International Journal of Photoenergy

International Journal of Photoenergy / 1999 / Article

Open Access

Volume 1 |Article ID 435413 | https://doi.org/10.1155/S1110662X99000240

K. Hansongnern, P. Chooto, P. Amornpitoksuk, "Electrogenerated chemiluminescence of violanthrone in dimethyl sulfoxide", International Journal of Photoenergy, vol. 1, Article ID 435413, 3 pages, 1999. https://doi.org/10.1155/S1110662X99000240

Electrogenerated chemiluminescence of violanthrone in dimethyl sulfoxide

Abstract

Violanthrone is an anthraquinone vat dye, which is resistant to photochemical damage. Most previous work has concentrated on its chemiluminescence properties. In this report, electrogenerated chemiluminescence (ECL) of violanthrone has been investigated in dimethyl sulfoxide with 0.1M of tetraethylammonium bromide as electrolyte. Violanthrone luminesces in the potential range between 0.0V and -4:0 V. At the sweep rate 1000 mV/s, the intensity of the violanthrone ECL is about 2% of that of tris(2,2-bipyridine) ruthenium(II) ion under the same conditions. It was found that bromine was also produced during the ex- periment, leading to the conclusion that the luminescence arises from the reaction between radical anion of violanthrone and molecular bromine. The mechanism is discussed in detail.

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


More related articles

 PDF Download Citation Citation
 Order printed copiesOrder
Views90
Downloads326
Citations

We are committed to sharing findings related to COVID-19 as quickly as possible. We will be providing unlimited waivers of publication charges for accepted research articles as well as case reports and case series related to COVID-19. Review articles are excluded from this waiver policy. Sign up here as a reviewer to help fast-track new submissions.