International Journal of Photoenergy

International Journal of Photoenergy / 2003 / Article

Open Access

Volume 5 |Article ID 870586 | https://doi.org/10.1155/S1110662X03000059

Kyoichi Oki, Sachiko Tsuchida, Hiromasa Nishikiori, Nobuaki Tanaka, Tsuneo Fujii, "Photocatalytic degradation of chlorinated ethenes", International Journal of Photoenergy, vol. 5, Article ID 870586, 5 pages, 2003. https://doi.org/10.1155/S1110662X03000059

Photocatalytic degradation of chlorinated ethenes

Abstract

Degradation of three chlorinated ethenes, trichloroethylene, trans-1,2-dichloroethylene and cis-1,2-dichloroethylene, by UV-light irradiated TiO2 catalyst prepared by the sol-gel method in dry air at ambient temperature have been examined by using FTIR measurement. The chlorinated ethenes rapidly decomposed to produce dichloroacethyl chloride, CO, HCl, and COCL2. For trans- and cis-1,2-DCE systems isomerization to each other is found to be the first step of the degradation. The C = C bond of the chlorinated ethenes interacts directly with TiO2 site and, consequently, the degradation results in several products on the catalyst surface in these systems.

Copyright © 2003 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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