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International Journal of Photoenergy
Volume 2006 (2006), Article ID 26870, 8 pages
http://dx.doi.org/10.1155/IJP/2006/26870

Modelling of quantum yields in photocatalytic membrane reactors immobilising titanium dioxide

1Environmental Research Centre, University of Milan, Via C. Golgi 19, Milan 20133, Italy
2Research and Development Group, BIT srl, Milan 20121, Italy
3Department of Materials Science, University of Milano Bicocca, Milan 20126, Italy
4CNR, ISTM, Milan 20133, Italy

Received 19 February 2006; Revised 25 April 2006; Accepted 4 May 2006

Copyright © 2006 Ignazio Renato Bellobono et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. L. Pruden and D. F. Ollis, “Photoassisted heterogeneous catalysis: the degradation of trichloroethylene in water,” Journal of Catalysis, vol. 82, no. 2, pp. 404–417, 1983. View at Publisher · View at Google Scholar
  2. H. Y. Hsiao, C. L. Lee, and D. F. Ollis, “Heterogeneous photocatalysis: degradation of dilute solutions of dichloromethane (CH2Cl2), chloroform (CHCl3), and carbon tetrachloride (CCl4) with illuminated TiO2 photocatalyst,” Journal of Catalysis, vol. 82, no. 2, pp. 418–423, 1983. View at Publisher · View at Google Scholar
  3. T. Nguyen and D. F. Ollis, “Complete heterogeneously photocatalyzed transformation of 1,1- and 1,2-dibromoethane to carbon dioxide and hydrogen bromide,” Journal of Physical Chemistry, vol. 88, no. 16, pp. 3386–3388, 1984. View at Publisher · View at Google Scholar
  4. R. W. Matthew, “Hydroxylation reactions induced by near-ultraviolet photolysis of aqueous titanium dioxide suspensions,” Journal of the Chemical Society, Faraday Transactions 1, vol. 80, pp. 457–471, 1984. View at Publisher · View at Google Scholar
  5. R. W. Matthew, “Photo-oxidation of organic material in aqueous suspensions of titanium dioxide,” Water Research, vol. 20, no. 5, pp. 569–578, 1986. View at Publisher · View at Google Scholar
  6. K. Okamoto, Y. Yamamoto, H. Tanaka, M. Tanaka, and A. Itaya, “Heterogeneous photocatalytic decomposition of phenol over TiO2 powder,” Bulletin of the Chemical Society of Japan, vol. 58, pp. 2015–2022, 1985. View at Publisher · View at Google Scholar
  7. M. Barbeni, E. Pramauro, E. Pelizzetti, E. Borgarello, M. Grätzel, and N. Serpone, “Photodegradation of 4-chlorophenol catalyzed by titanium dioxide particles,” Nouveau Journal De Chimie, vol. 8, pp. 547–550, 1984. View at Google Scholar
  8. H. Al-Ekabi and N. Serpone, “Kinetic studies in heterogeneous photocatalysis. 1. Photocatalytic degradation of chlorinated phenols in aerated aqueous solutions over TiO2 supported on a glass matrix,” Journal of Physical Chemistry, vol. 92, no. 20, pp. 5726–5731, 1988. View at Publisher · View at Google Scholar
  9. A. Fujishima and K. Honda, “Electrochemical photolysis of water at a semiconductor electrode,” Nature, vol. 238, pp. 37–38, 1972. View at Publisher · View at Google Scholar
  10. A. Fujishima, K. Kohayakawa, and K. Honda, “Hydrogen production under sunlight with electrochemical photo-cell,” Journal of the Electrochemical Society, vol. 122, p. 1487, 1975. View at Publisher · View at Google Scholar
  11. A. J. Nozik, “Photoelectrolysis of water using semiconducting TiO2 crystals,” Nature, vol. 257, pp. 383–386, 1975. View at Publisher · View at Google Scholar
  12. M. S. Wrighton, D. S. Ginley, P. T. Wolczanski, A. B. Ellis, D. L. Morse, and A. Linz, “Photoassisted electrolysis of water by irradiation of a titanium dioxide electrode,” Proceedings of the National Academy of Sciences of the United States of America, vol. 72, no. 4, pp. 1518–1522, 1975. View at Publisher · View at Google Scholar
  13. J. Manassen, D. Cahen, G. Hodes, and A. Sofer, “Electrochemical, solid state, photochemical and technological aspects of photoelectrochemical energy converters,” Nature, vol. 263, pp. 97–100, 1976. View at Publisher · View at Google Scholar
  14. W. Gissler, P. L. Lensi, and S. Pizzini, “Electrochemical investigation of an illuminated TiO2-electrode,” Journal of Applied Electrochemistry, vol. 6, no. 1, pp. 9–13, 1976. View at Publisher · View at Google Scholar
  15. B. Marcandalli and I. R. Bellobono, “Influence of wavelength on the photoeffects at polycrystalline semiconductors. Energy conversion efficiencies of photoelectrochemical cells employing a titanium dioxide film anode and a hydrogen or oxygen cathode,” Atti della Accademia Nazionale dei Lincei, Rendiconti, Classe di Scienze Fisiche, Matematiche e Naturali, vol. 65, pp. 87–92, 1978. View at Google Scholar
  16. F. Gianturco, C. M. Chiodaroli, I. R. Bellobono, M. L. Raimondi, A. Moroni, and B. Gawlik, “Pilot-plant photomineralization of atrazine in aqueous solution, by photocatalytic membranes immobilising titanium dioxide and promoting photocatalysts,” Fresenius Environmental Bulletin, vol. 6, no. 7-8, pp. 461–468, 1997. View at Google Scholar
  17. L. Rivas, I. R. Bellobono, and F. Ascari, “Photomineralization of n-alkanoic acids in aqueous solution by photocatalytic membranes. Influence of trialkyl vanadates as catalytic promoters of immobilized titanium dioxide,” Chemosphere, vol. 35, no. 12, pp. 2889–2908, 1997. View at Publisher · View at Google Scholar
  18. I. R. Bellobono, F. Ascari, C. Lagrasta et al., “Kinetic modelling of photomineralization of phenol, as model molecule of aromatic micropollutants, and validation of a photochemical reactor based on photocatalytic membranes immobilizing titanium dioxide and promoting photocatalysts,” Fresenius Environmental Bulletin, vol. 12, no. 12, pp. 1536–1544, 2003. View at Google Scholar
  19. H. Gerischer and A. Heller, “Photocatalytic oxidation of organic molecules at TiO2 particles by sunlight in aerated water,” Journal of the Electrochemical Society, vol. 139, no. 1, pp. 113–118, 1992. View at Publisher · View at Google Scholar
  20. C. M. Wang, A. Heller, and H. Gerischer, “Palladium catalysis of O2 reduction by electrons accumulated on TiO2 particles during photoassisted oxidation of organic compounds,” Journal of the American Chemical Society, vol. 114, no. 13, pp. 5230–5234, 1992. View at Publisher · View at Google Scholar
  21. J. Chen, D. F. Ollis, W. H. Rulkens, and H. Bruning, “Photocatalyzed oxidation of alcohols and organochlorides in the presence of native TiO2 and metallized TiO2 suspensions. Part (I): photocatalytic activity and pH influence,” Water Research, vol. 33, no. 3, pp. 661–668, 1999, 1173. View at Publisher · View at Google Scholar
  22. A. Dobosz and A. Sobczyński, “Water detoxification: photocatalytic decomposition of phenol on Au/TiO2,” Monatshefte für Chemie, vol. 132, no. 9, pp. 1037–1045, 2001. View at Google Scholar
  23. M. F. J. Dijkstra, E. C. B. Koerts, A. A. C. M. Beenackers, and J. A. Wesselingh, “Performance of immobilized photocatalytic reactors in continuous mode,” American Institute of Chemical Engineers Journal, vol. 49, no. 3, pp. 734–744, 2003. View at Google Scholar
  24. F. Ascari, I. R. Bellobono, and P. M. Tozzi, “Kinetic modelling of pilot plant photomineralization of aqueous cibacron CR as model molecule of industrial azo dyes on titanium dioxide-immobilizing membranes,” Fresenius Environmental Bulletin, vol. 12, no. 10, pp. 1195–1201, 2003. View at Google Scholar
  25. I. R. Bellobono, F. Morazzoni, R. Bianchi et al., “Laboratory-scale photomineralisation of n-alkanes in aqueous solution, by photocatalytic membranes immobilising titanium dioxide,” International Journal of Photoenergy, vol. 7, no. 2, pp. 79–85, 2005. View at Publisher · View at Google Scholar
  26. L. Rivas, I. R. Bellobono, and F. Ascari, “Photomineralization of n-alkanoic acids in aqueous solution by photocatalytic membranes. Influence of radiation power,” Chemosphere, vol. 37, no. 6, pp. 1033–1044, 1998. View at Publisher · View at Google Scholar
  27. I. R. Bellobono, R. Tacchi, E. Selli, and F. Muffato, “Photosynthetic membranes for pure and ultrapure water production,” in Membrane Separation Processes, A. Green, Ed., p. 187, BHRA, Cranfield, UK, 1989. View at Google Scholar
  28. B. Barni, A. Cavicchioli, E. Riva et al., “Laboratory-scale photodegradation of phenol in aqueous solution by photocatalytic membranes immobilizing titanium dioxide,” Chemosphere, vol. 30, no. 10, pp. 1847–1860, 1995. View at Publisher · View at Google Scholar
  29. A. J. Elliot and D. C. Ouellete, “Temperature dependence of the rate constant for the reaction e-aq+ OH in water up to 150 °C,” Journal of the Chemical Society, Faraday Transactions, vol. 90, pp. 837–841, 1994. View at Publisher · View at Google Scholar
  30. R. Morelli, I. R. Bellobono, C. M. Chiodaroli, and S. Alborghetti, “EPR spin-trapping of hydroxyl radicals onto photocatalytic membranes immobilizing titanium dioxide, and spin adduct competition, as a probe of reactivity with aqueous organic micropollutants,” Journal of Photochemistry and Photobiology A: Chemistry, vol. 112, no. 2, pp. 271–276, 1998. View at Publisher · View at Google Scholar