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International Journal of Photoenergy
Volume 2009, Article ID 786429, 15 pages
http://dx.doi.org/10.1155/2009/786429
Research Article

Investigation of Temperature and Aging Effects in Nanostructured Dye Solar Cells Studied by Electrochemical Impedance Spectroscopy

Department of Applied Physics, Advanced Energy Systems, Helsinki University of Technology, P.O. Box 5100, 02015 TKK, Finland

Received 17 November 2008; Revised 28 May 2009; Accepted 6 August 2009

Academic Editor: A. Hagfeldt

Copyright © 2009 Minna Toivola et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. B. O'Regan and M. Grätzel, “A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films,” Nature, vol. 353, no. 6346, pp. 737–740, 1991. View at Google Scholar · View at Scopus
  2. M. Grätzel, “The magic world of nanocrystals, from batteries to solar cells,” Current Applied Physics, vol. 6, supplement 1, pp. e2–e7, 2006. View at Publisher · View at Google Scholar · View at Scopus
  3. M. K. Nazeeruddin, P. Péchy, S. M. Renouard et al., “Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells,” Journal of the American Chemical Society, vol. 123, no. 8, pp. 1613–1624, 2001. View at Publisher · View at Google Scholar · View at Scopus
  4. M. K. Nazeeruddin, T. Bessho, L. Cevey et al., “A high molar extinction coefficient charge transfer sensitizer and its application in dye-sensitized solar cell,” Journal of Photochemistry and Photobiology A, vol. 185, no. 2-3, pp. 331–337, 2007. View at Publisher · View at Google Scholar · View at Scopus
  5. H. Pettersson and T. Gruszecki, “Long-term stability of low-power dye-sensitised solar cells prepared by industrial methods,” Solar Energy Materials and Solar Cells, vol. 70, no. 2, pp. 203–212, 2001. View at Publisher · View at Google Scholar · View at Scopus
  6. H. Pettersson, T. Gruszecki, L.-H. Johansson, and P. Johander, “Manufacturing method for monolithic dye-sensitised solar cells permitting long-term stable low-power modules,” Solar Energy Materials and Solar Cells, vol. 77, no. 4, pp. 405–413, 2003. View at Publisher · View at Google Scholar · View at Scopus
  7. P. M. Sommeling, M. Späth, H. J. P. Smit, N. J. Bakker, and J. M. Kroon, “Long-term stability testing of dye-sensitized solar cells,” Journal of Photochemistry and Photobiology A, vol. 164, no. 1–3, pp. 137–144, 2004. View at Publisher · View at Google Scholar · View at Scopus
  8. R. Sastrawan, J. Beier, U. Belledin et al., “New interdigital design for large area dye solar modules using a lead-free glass frit sealing,” Progress in Photovoltaics: Research and Applications, vol. 14, no. 8, pp. 697–709, 2006. View at Publisher · View at Google Scholar · View at Scopus
  9. A. Hinsch, J. M. Kroon, R. Kern et al., “Long-term stability of dye-sensitised solar cells,” Progress in Photovoltaics: Research and Applications, vol. 9, no. 6, pp. 425–438, 2001. View at Publisher · View at Google Scholar · View at Scopus
  10. B. Macht, M. Turrión, A. Barkschat, P. Salvador, K. Ellmer, and H. Tributsch, “Patterns of efficiency and degradation in dye sensitization solar cells measured with imaging techniques,” Solar Energy Materials and Solar Cells, vol. 73, no. 2, pp. 163–173, 2002. View at Publisher · View at Google Scholar · View at Scopus
  11. T. Toyoda, T. Sano, J. Nakajima et al., “Outdoor performance of large scale DSC modules,” Journal of Photochemistry and Photobiology A, vol. 164, no. 1–3, pp. 203–207, 2004. View at Publisher · View at Google Scholar · View at Scopus
  12. P. Wang, S. M. Zakeeruddin, J. E. Moser, M. K. Nazeeruddin, T. Sekiguchi, and M. Grätzel, “A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte,” Nature Materials, vol. 2, no. 6, pp. 402–407, 2003. View at Publisher · View at Google Scholar · View at Scopus
  13. H. G. Agrell, J. Lindgren, and A. Hagfeldt, “Degradation mechanisms in a dye-sensitized solar cell studied by UV-VIS and IR spectroscopy,” Solar Energy, vol. 75, no. 2, pp. 169–180, 2003. View at Publisher · View at Google Scholar · View at Scopus
  14. P. J. Sebastián, A. Olea, J. Campos, J. A. Toledo, and S. A. Gamboa, “Temperature dependence and the oscillatory behavior of the opto-electronic properties of a dye-sensitized nanocrystalline TiO2 solar cell,” Solar Energy Materials and Solar Cells, vol. 81, no. 3, pp. 349–361, 2004. View at Publisher · View at Google Scholar · View at Scopus
  15. K. Lobato and L. M. Peter, “Direct measurement of the temperature coefficient of the electron quasi-Fermi level in dye-sensitized nanocrystalline solar cells using a titanium sensor electrode,” The Journal of Physical Chemistry B, vol. 110, no. 43, pp. 21920–21923, 2006. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Dürr, A. Yasuda, and G. Nelles, “On the origin of increased open circuit voltage of dye-sensitized solar cells using 4-tert-butyl pyridine as additive to the electrolyte,” Applied Physics Letters, vol. 89, no. 6, Article ID 061110, 3 pages, 2006. View at Publisher · View at Google Scholar · View at Scopus
  17. H. J. Snaith, L. Schmidt-Mende, M. Grätzel, and M. Chiesa, “Light intensity, temperature, and thickness dependence of the open-circuit voltage in solid-state dye-sensitized solar cells,” Physical Review B, vol. 74, no. 4, Article ID 045306, 6 pages, 2006. View at Publisher · View at Google Scholar · View at Scopus
  18. L. M. Peter, A. B. Walker, G. Boschloo, and A. Hagfeldt, “Interpretation of apparent activation energies for electron transport in dye-sensitized nanocrystalline solar cells,” The Journal of Physical Chemistry B, vol. 110, no. 28, pp. 13694–13699, 2006. View at Publisher · View at Google Scholar · View at Scopus
  19. H. G. Agrell, G. Boschloo, and A. Hagfeldt, “Conductivity studies of nanostructured TiO2 films permeated with electrolyte,” The Journal of Physical Chemistry B, vol. 108, no. 33, pp. 12388–12396, 2004. View at Publisher · View at Google Scholar · View at Scopus
  20. G. Boschloo and A. Hagfeldt, “Activation energy of electron transport in dye-sensitized TiO2 solar cells,” The Journal of Physical Chemistry B, vol. 109, no. 24, pp. 12093–12098, 2005. View at Publisher · View at Google Scholar · View at Scopus
  21. B. C. O'Regan and J. R. Durrant, “Calculation of activation energies for transport and recombination in mesoporous TiO2/dye/electrolyte films-taking into account surface charge shifts with temperature,” The Journal of Physical Chemistry B, vol. 110, no. 17, pp. 8544–8547, 2006. View at Publisher · View at Google Scholar · View at Scopus
  22. Q. Wang, J.-E. Moser, and M. Grätzel, “Electrochemical impedance spectroscopic analysis of dye-sensitized solar cells,” The Journal of Physical Chemistry B, vol. 109, no. 31, pp. 14945–14953, 2005. View at Publisher · View at Google Scholar · View at Scopus
  23. R. Kern, R. Sastrawan, J. Ferber, R. Stangl, and J. Luther, “Modeling and interpretation of electrical impedance spectra of dye solar cells operated under open-circuit conditions,” Electrochimica Acta, vol. 47, no. 26, pp. 4213–4225, 2002. View at Publisher · View at Google Scholar · View at Scopus
  24. F. Fabregat-Santiago, J. Bisquert, G. Garcia-Belmonte, G. Boschloo, and A. Hagfeldt, “Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy,” Solar Energy Materials and Solar Cells, vol. 87, no. 1–4, pp. 117–131, 2005. View at Publisher · View at Google Scholar · View at Scopus
  25. J. Bisquert, G. Garcia-Belmonte, F. Fabregat-Santiago, N. S. Ferriols, P. Bogdanoff, and E. C. Pereira, “Doubling exponent models for the analysis of porous film electrodes by impedance. relaxation of TiO2 nanoporous in aqueous solution,” The Journal of Physical Chemistry B, vol. 104, no. 10, pp. 2287–2298, 2000. View at Google Scholar · View at Scopus
  26. J. Bisquert, G. Garcia-Belmonte, F. Fabregat-Santiago, and A. Compte, “Anomalous transport effects in the impedance of porous film electrodes,” Electrochemistry Communications, vol. 1, no. 9, pp. 429–435, 1999. View at Google Scholar · View at Scopus
  27. J. Bisquert, “Influence of the boundaries in the impedance of porous film electrodes,” Physical Chemistry Chemical Physics, vol. 2, no. 18, pp. 4185–4192, 2000. View at Publisher · View at Google Scholar · View at Scopus
  28. T. Hoshikawa, T. Ikebe, R. Kikuchi, and K. Eguchi, “Effects of electrolyte in dye-sensitized solar cells and evaluation by impedance spectroscopy,” Electrochimica Acta, vol. 51, no. 25, pp. 5286–5294, 2006. View at Publisher · View at Google Scholar · View at Scopus
  29. M. Adachi, M. Sakamoto, J. Jiu, Y. Ogata, and S. Isoda, “Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy,” The Journal of Physical Chemistry B, vol. 110, no. 28, pp. 13872–13880, 2006. View at Publisher · View at Google Scholar · View at Scopus
  30. T. Hoshikawa, R. Kikuchi, and K. Eguchi, “Impedance analysis for dye-sensitized solar cells with a reference electrode,” The Journal of Electroanalytical Chemistry, vol. 588, no. 1, pp. 59–67, 2006. View at Publisher · View at Google Scholar · View at Scopus
  31. T. Hoshikawa, M. Yamada, R. Kikuchi, and K. Eguchi, “Impedance analysis of internal resistance affecting the photoelectrochemical performance of dye-sensitized solar cells,” Journal of the Electrochemical Society, vol. 152, no. 2, pp. E68–E73, 2005. View at Publisher · View at Google Scholar · View at Scopus
  32. C. Longo, A. F. Nogueira, M.-A. De Paoli, and H. Cachet, “Solid-state and flexible dye-sensitized TiO2 solar cells: a study by electrochemical impedance spectroscopy,” The Journal of Physical Chemistry B, vol. 106, no. 23, pp. 5925–5930, 2002. View at Publisher · View at Google Scholar · View at Scopus
  33. L. Han, N. Koide, Y. Chiba, A. Islam, and T. Mitate, “Modeling of an equivalent circuit for dye-sensitized solar cells: improvement of efficiency of dye-sensitized solar cells by reducing internal resistance,” Comptes Rendus Chimie, vol. 9, no. 5-6, pp. 645–651, 2006. View at Publisher · View at Google Scholar · View at Scopus
  34. C. Shi, S. Dai, K. Wang et al., “Influence of various cations on redox behavior of I- and I3- and comparison between KI complex with 18-crown-6 and 1,2-dimethyl-3-propylimidazolium iodide in dye-sensitized solar cells,” Electrochimica Acta, vol. 50, no. 13, pp. 2597–2602, 2005. View at Publisher · View at Google Scholar · View at Scopus
  35. Q. Wang, S. Ito, M. Grätzel et al., “Characteristics of high efficiency dye-sensitized solar cells,” The Journal of Physical Chemistry B, vol. 110, no. 50, pp. 25210–25221, 2006. View at Publisher · View at Google Scholar · View at Scopus
  36. F. Fabregat-Santiago, J. Bisquert, E. Palomares et al., “Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids,” The Journal of Physical Chemistry C, vol. 111, no. 17, pp. 6550–6560, 2007. View at Publisher · View at Google Scholar · View at Scopus
  37. K. Miettunen, J. Halme, M. Toivola, and P. Lund, “Initial performance of dye solar cells on stainless steel substrates,” The Journal of Physical Chemistry C, vol. 112, no. 10, pp. 4011–4017, 2008. View at Publisher · View at Google Scholar · View at Scopus
  38. M. Toivola, L. Peltokorpi, J. Halme, and P. Lund, “Regenerative effects by temperature variations in dye-sensitized solar cells,” Solar Energy Materials and Solar Cells, vol. 91, no. 18, pp. 1733–1742, 2007. View at Publisher · View at Google Scholar · View at Scopus
  39. M. Toivola, F. Ahlskog, and P. Lund, “Industrial sheet metals for nanocrystalline dye-sensitized solar cell structures,” Solar Energy Materials and Solar Cells, vol. 90, no. 17, pp. 2881–2893, 2006. View at Publisher · View at Google Scholar · View at Scopus
  40. P. Wang, S. M. Zakeeruddin, and M. Grätzel, “Solidifying liquid electrolytes with fluorine polymer and silica nanoparticles for quasi-solid dye-sensitized solar cells,” Journal of Fluorine Chemistry, vol. 125, no. 8, pp. 1241–1245, 2004. View at Publisher · View at Google Scholar · View at Scopus
  41. J. R. Macdonald, Impedance Spectroscopy, Wiley, New York, NY, USA, 1987.