International Journal of Photoenergy

International Journal of Photoenergy / 2009 / Article

Research Article | Open Access

Volume 2009 |Article ID 905987 | 6 pages | https://doi.org/10.1155/2009/905987

Photocatalytic Activity in CN Related to the Surface Properties of Powders Prepared by Sol-Gel Method

Academic Editor: Leonardo Palmisano
Received11 May 2009
Revised09 Jul 2009
Accepted06 Aug 2009
Published04 Nov 2009

Abstract

Some powders, prepared from titanium(IV)tetraisopropoxide by the sol-gel method and thermally treated between 100 and C, have been characterized by X-ray powder diffraction and by nitrogen adsorption and desorption at 77 K to calculate the BET-specific surface area, from which the micropore volume and the external surface area can be derived. The photocatalytic activity () of the above powders has been evaluated considering the -sensitized photo-oxidation of 4-methoxybenzyl alcohol in CN as the test reaction. The decrease of have been related to the decrease of the BET surface area, the micropore volume, and the external surface area of the powders, but a satisfactory linear correlation is observed only for the last superficial parameter.

1. Introduction

Heterogeneous photochemical processes sensitized by semiconductors, such as TiO2, have gained wide popularity because of their application, mainly to water or atmosphere detoxification, to conversion or storage of solar light energy, and to synthetic or mechanistic organic chemistry [1, 2].

Photo-oxidation reactions of organic compounds sensitized by TiO2 in CH3CN have been studied also from the point of view of their reaction mechanism because this reaction medium is suitable to dissolve the organic substrates and is not competitively oxidizable. Moreover, the primary oxidation products usually are not furtherly degraded, allowing material recovery (unreacted substrate formed product) and stoichiometry to be evaluated. The primary oxidation products are generally obtained through an electron transfer mechanism between the photo-generated hole, , and the substrate, giving a radical cation as intermediate [3].

In recent years, many mechanistic details have been collected about this TiO2-sensitized oxidative process on benzylic derivatives (arenes [4], alcohols [57], ethers [8], silanes [7], sulfides [911], diols [6, 12] etc.) in CH3CN. In these works only TiO2 commercial powders have been considered (anatase, Aldrich, or P25, Degussa).

In this paper we report the results of a study that allow a correlation of the photochemical activity in CH3CN to the superficial texture and the crystal form of different synthetic TiO2 powders. These photocatalysts were prepared by a sol-gel method starting from titanium isopropoxide, calcined at different temperatures ( for one hour) and characterized by X-ray diffraction (XRD) and by nitrogen adsorption and desorption at 77 K.

In this context, it has been previously reported that powders, prepared though the sol-gel method in the absence of any kind of additives and calcined at different temperatures, show different photochemical efficiencies in the photo-oxidations of appropriate test samples, either in water and in gas phase [1316].

In this work, the photocatalytic activity of the powders have been evaluated through the photo-oxidation in CH3CN of 4-methoxybenzyl alcohol to 4-methoxybenzaldehyde, a reaction of known stoichiometry and mechanism [7, 17, 18].

2. Experiments

2.1. Materials

Titanium(IV)tetraisopropoxide (TTIP, Aldrich, 97%), TiO2 (P25, Degussa), isopropanol (IP, Carlo Erba, 99.7%), CH3CN (99.9%, HPLC grade, containing 0.02% of water from Karl Fisher analysis), and 4-methoxybenzyl alcohol (Aldrich, 98%) were commercial samples.

2.2. Preparation of TiO2 Powder

For the synthesis of the TiO2 powder, TTIP (12 mL) was added to 500 mL of IP with constant magnetic stirring at room temperature. Milli-Q water (2500 mL) was then added slowly to the solution. The obtained mixture ( molar ) was vigorously stirred for 24 hours in a closed flask. The fine white precipitate dispersed in the solvent was filtered and washed with Milli-Q water. The white residue was dried in oven at for 24 hours and then it was grinded by a ceramic mortar. The derived particles were thermally treated for 1 hour at 200, 300, 350, 400, 500, 700, 850, and .

2.3. Characterization of TiO2 Powders

X-ray powder diffraction (XRD) analyses were performed on a computerized Philips PW1710 diffractometer using Cu radiation, operating at 40 kV and 20 mA with a step scan of /min.

Nitrogen adsorption/desorption isotherms at 77 K were measured using a computer-controlled Micrometrics ASAP 2010 adsorption analyzer. The preparation of samples was made by degassing the materials at , overnight. The specific surface area was calculated by the Brunauer, Emmett and Teller (BET) theory. Micropore volume and external surface area of the catalysts were obtained by application of the -plot method [19]. The Harkins-Jura equation was used as reference for the thickness of the adsorbed layer [19].

The thermogravimetric analysis of the sample dried at , stored at room temperature, 75% r.h., was performed with a Netzsch STA 449C thermobalance with a temperature gradient of /min.

2.4. Photochemical Oxidation

A solution of the substrate ( M) in 10 mL of CH3CN, containing 10 mg of TiO2, was externally irradiated using a Helios Italquartz 500 W high pressure mercury lamp (through Pyrex filter), under stirring at room temperature. In the present work, we are mainly interested to the relative photocatalytic activity of powders and therefore we did not measure the irradiation intensity. However, for such a lamp, one typically expects a photon flux emission between 15 and 20 mW cm−2. After irradiation, the reaction mixture was filtered through double paper and analyzed by gas-chromatography (GC, in the presence of bibenzyl as internal standard). The GC analyses were carried out on a HP 5890 gas-chromatograph using a HP-Innovax capillary column, 15 m.

3. Results and Discussion

3.1. Powders Synthesis

The TiO2 powders were prepared by hydrolysis of TTIP in IP and subsequent calcination at 100 (denoted as S100), 200 (S200), 300 (S300), 350 (S350), 400 (S400), 500 (S500), 700 (S700), 850 (S850) and (S1000).

3.2. X-Ray Diffraction

XRD patterns of the samples S100-S1000 are shown in Figure 1. Diffraction maxima due to the anatase form of TiO2 were evident after thermal treatments from 400 to (S400, S500, and S700 samples). A further increase of calcination temperature brings to the appearance of the rutile crystalline form besides that of anatase (S850). In the case of S1000 sample, only maxima ascribed to the rutile crystalline form are observed. From XRD results the S100-S350 samples do not present any evident christallinity, but TEM measurements [14, 15] on samples prepared by a similar procedure and calcined at temperatures from 100 to evidentiate aggregates of fine particles.

3.3. Nitrogen Adsorption-Desorption Isotherms

Surface area and porosity of obtained solids were calculated by nitrogen adsorption and desorption at 77 K. Some of these isotherms are shown in Figure 2.

The adsorption-desorption isotherm of S350 is similar and superimposed to all the samples below (S100, S200, and S300) and can be classified as type II isotherm.

Increasing the temperature of the thermal treatment from 350 to , the adsorption isotherm gradually changes from type II to type III.

The little hysteresis present between the desorption and adsorption isotherms of some samples, in the range , indicates that a little volume of mesopores is present.

The BET adsorption analysis data allows to calculate, for the various samples, the specific BET surface area. This area depends on the temperature of the thermal treatment: higher values of surface area are measured for the samples treated at temperatures lower than (see Figure 3).

Increasing the thermal treatment temperatures above , BET surface area diminishes until a very low value at (S1000 sample). The decrease of BET area (with the enhancement of the calcination temperature) could be related to the increase of crystallinity of the samples [20].

The -plot analysis of samples adsorption data permits to evaluate the micropore volumes and the external surface area of the samples [19].

The calculated micropore volumes and the external surface area for the prepared samples are plotted against thermal treatment temperature in Figures 4 and 5.

Samples with a micropore volume higher than 0.18 cm3/g were obtained when the temperature of the thermal treatment do not exceed . The increase of the temperature above induces a decrease in the micropore volume and in the external surface area. This is consistent with the increase of the crystallinity of the samples.

The micropore size distribution calculated by the MP method [19] is narrow; for example, the hydraulic radius relative to the powder S350 is in the range 5–8 angstrom.

3.4. Photocatalytic Activity

As it has been mentioned in the Introduction, in order to evaluate the photocatalytic activity of the different TiO2 powders, we have considered a photo-oxidation test reaction in liquid phase previously extensively studied by us, that is, the TiO2 photosensitized oxidation of 4-methoxybenzyl alcohol in CH3CN (1):

905987.eq.001(1)

The recognized reaction mechanism and, consequently, the reaction stoichiometry, are reported in Scheme 1.

905987.sch.001

The aldehyde conversions, obtained at different times in the presence of TiO2 powders thermally treated from 100 to , are reported in Table 1. In the same table are also reported the data relative to the commercial TiO2 P25 powder.


SampleAldehyde yield (%)103 (min−1)
minutes minutes minutes minutes minutes

S10012223552676.3
S20011224065819.0
S300203352778010.2
S35018284369819.4
S40015263659696.9
S50014233757747.4
S70011162744594.9
S85012172635574.0
S100012260.3
P2514202433383.1

The photocatalytic activity of the different powders can be quantitatively evaluated by the apparent rate constants () calculated by the following Langmuir-Hinshelwood rate expression:

where is the aldehyde percent at the various times (), k is the true rate constant and K is the substrate adsorption constant on TiO2. As an example, the linear plot ln[100/()] versus , relative to the photo-oxidation in the presence of the sample S200, is reported in Figure 6.

All values are reported in Table 1. From these kinetic data it can be observed that the samples S200, S300, and S350 are the most photochemically efficient ( in the range  min−1). Samples S100, S400, S500, S700, and S850 are less efficient ( min−1). Finally, the sample S1000 is the least reactive one ( min−1), mostly due to its crystal form (rutile, less efficient than anatase) [21].

A further point to be considered is that all prepared photocatalytic powders (exept S1000) are more efficient than the commercial photocatalyst P25 (see Table 1).

Moreover, no reaction takes place in the absence of light or in the absence of catalyst until the considered reaction time (3 hours).

It must be observed that the sample S100 presents a great water amount ( 13% w/w, from thermogravimetric analysis) that could reduce the sites available to the substrate adsorption and then the value; therefore, we have not thought it convenient to consider this sample in the following discussion.

Therefore, considering only the values relative to S200-S1000 samples in Table 1 and their calcination temperature, a rate decrease when the temperature increases is qualitatively observed.

As the test reaction occurs at the interface between the solid photocatalyst and the organic solution, it is expected that the observed relationship should be connected with the solid-solution interface characteristics and, in particular, to the superficial properties of TiO2. The above reported characterization of the photocatalyst surface indicates that the BET surface area, the micropore volume and the external surface area depend on the temperature of the thermal treatment: they decrease together according to the trends reported in Figures 3, 4, and 5. Therefore, it seems to be of interest to directly evaluate the relationship between these parameters and .

From the N2 adsorption data, the calculation of the nitrogen volume which forms a monolayer of adsorbed molecules, and thus the BET surface area value, involves the volume of the nitrogen molecules adsorbed in the micropores and on the external surface area [19]; therefore, the micropore volume and the external surface area are separately taken into account to find a dependence from the measured value.

Plotting versus external surface area, a satisfactory linear correlation () was obtained (Figure 7) while a lower correlation factor () for versus micropore volume was calculated. Thus, the photochemical activity directly depends from external surface area of the sample, while the micropore volume is less important.

The fact that the photocatalytic activity becomes weaker when the external surface area decreases, could be related to the decrease of the number of OH groups, necessary for the adsorption of substrate at the semiconductor surface, interfaced to CH3CN [22, 23].

4. Conclusion

The photochemical activity of TiO2 powders, obtained by a sol-gel method and calcined at different temperatures, has been evaluated through a test reaction (4-methoxybenzyl alcohol 4-methoxybenzaldehyde) in CH3CN. In this medium, the increase of calcination temperature induces, on one side, a decrease of BET surface area, of micropore volume and of external surface area and, on the other side, a decrease of the photo-oxidation rate of test reaction. Among the above surface parameters, the one that shows the best linear correlation with the reaction rate is the external surface area.

Acknowledgment

This work was carried out with the financial support of the Ministero dell’Istruzione, dell’Università e della Ricerca.

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Copyright © 2009 Marta Bettoni et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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