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International Journal of Photoenergy
Volume 2013, Article ID 245646, 8 pages
http://dx.doi.org/10.1155/2013/245646
Research Article

Multifunctional Chitosan-Copper Oxide Hybrid Material: Photocatalytic and Antibacterial Activities

School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk 712-749, Republic of Korea

Received 28 May 2013; Accepted 18 August 2013

Academic Editor: Meenakshisundaram Swaminathan

Copyright © 2013 Yuvaraj Haldorai and Jae-Jin Shim. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. C. Burda, X. B. Chen, R. Narayanan, and M. A. El-Sayed, “Chemistry and properties of nanocrystals of different shapes,” Chemical Reviews, vol. 105, no. 4, pp. 1025–1102, 2005. View at Publisher · View at Google Scholar · View at Scopus
  2. S. J. Guo and E. K. Wang, “Functional micro/nanostructures: simple synthesis and application in sensors, fuel cells, and gene delivery,” Accounts of Chemical Research, vol. 44, no. 7, pp. 491–500, 2011. View at Publisher · View at Google Scholar · View at Scopus
  3. X. Zhao, L. Lv, B. Pan, W. Zhang, S. Zhang, and Q. Zhang, “Polymer-supported nanocomposites for environmental application: a review,” Chemical Engineering Journal, vol. 170, no. 2-3, pp. 381–394, 2011. View at Publisher · View at Google Scholar · View at Scopus
  4. S. Sarkar, E. Guibal, F. Quignard, and A. K. SenGupta, “Polymer-supported metals and metal oxide nanoparticles: synthesis, characterization, and applications,” Journal of Nanoparticle Research, vol. 14, no. 2, article 715, 2012. View at Publisher · View at Google Scholar · View at Scopus
  5. J. D. Torres, E. A. Faria, J. R. SouzaDe, and A. G. S. Prado, “Preparation of photoactive chitosan-niobium (V) oxide composites for dye degradation,” Journal of Photochemistry and Photobiology A, vol. 182, no. 2, pp. 202–206, 2006. View at Publisher · View at Google Scholar · View at Scopus
  6. E. I. Rabea, M. E.-T. Badawy, C. V. Stevens, G. Smagghe, and W. Steurbaut, “Chitosan as antimicrobial agent: applications and mode of action,” Biomacromolecules, vol. 4, no. 6, pp. 1457–1465, 2003. View at Publisher · View at Google Scholar · View at Scopus
  7. Z. Liu, H. Bai, and D. D. Sun, “Facile fabrication of porous chitosan/TiO2/Fe3O3 microspheres with multifunction for water purifications,” New Journal of Chemistry, vol. 35, no. 1, pp. 137–140, 2011. View at Publisher · View at Google Scholar · View at Scopus
  8. V. Singh, A. K. Sharma, and R. Sanghi, “Poly(acrylamide) functionalized chitosan: an efficient adsorbent for azo dyes from aqueous solutions,” Journal of Hazardous Materials, vol. 166, no. 1, pp. 327–335, 2009. View at Publisher · View at Google Scholar · View at Scopus
  9. V. Singh, A. K. Sharma, D. N. Tripathi, and R. Sanghi, “Poly(methylmethacrylate) grafted chitosan: an efficient adsorbent for anionic azo dyes,” Journal of Hazardous Materials, vol. 161, no. 2-3, pp. 955–966, 2009. View at Publisher · View at Google Scholar · View at Scopus
  10. G. Applerot, J. Lellouche, A. Lipovsky et al., “Understanding the antibacterial mechanism of CuO nanoparticles: revealing the route of induced oxidative stress,” Small, vol. 8, no. 21, pp. 3326–3337, 2012. View at Google Scholar
  11. G. Ren, D. Hu, E. W. C. Cheng, M. A. Vargas-Reus, P. Reip, and R. P. Allaker, “Characterisation of copper oxide nanoparticles for antimicrobial applications,” International Journal of Antimicrobial Agents, vol. 33, no. 6, pp. 587–590, 2009. View at Publisher · View at Google Scholar · View at Scopus
  12. X. C. Jiang, T. Herricks, and Y. N. Xia, “CuO nanowires can be synthesized by heating copper substrates in air,” Nano Letters, vol. 2, no. 12, pp. 1333–1338, 2002. View at Google Scholar · View at Scopus
  13. M. H. Cao, C. W. Hu, Y. H. Wang et al., “A controllable synthetic route to Cu, Cu2O, and CuO nanotubes and nanorods,” Chemical Communications, vol. 9, no. 15, pp. 1884–1885, 2003. View at Google Scholar · View at Scopus
  14. Z. L. Wang, X. Y. Kong, X. Wen, and S. Yang, “In situ structure evolution from Cu(OH)2 nanobelts to copper nanowires,” Journal of Physical Chemistry B, vol. 107, no. 33, pp. 8275–8280, 2003. View at Google Scholar · View at Scopus
  15. C. K. Xu, Y. K. Liu, G. D. Xu, and G. H. Wang, “Preparation and characterization of CuO nanorods by thermal decomposition of CuC2O4 precursor,” Materials Research Bulletin, vol. 37, no. 14, pp. 2365–2372, 2002. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Gouda and A. Hebeish, “Preparation and evaluation of CuO/chitosan nanocomposite for antibacterial finishing cotton fabric,” Journal of Industrial Textiles, vol. 39, no. 3, pp. 203–214, 2010. View at Publisher · View at Google Scholar · View at Scopus
  17. Y. Haldorai and J.-J. Shim, “Chitosan-zinc oxide hybrid composite for enhanced dye degradation and antibacterial activity,” Composite Interfaces, vol. 20, no. 5, pp. 365–377, 2013. View at Google Scholar
  18. A. Higazy, M. Hashem, A. ElShafei, N. Shaker, and M. A. Hady, “Development of antimicrobial jute packaging using chitosan and chitosan-metal complex,” Carbohydrate Polymers, vol. 79, no. 4, pp. 867–874, 2010. View at Publisher · View at Google Scholar · View at Scopus
  19. L.-H. Li, J.-C. Deng, H.-R. Deng, Z.-L. Liu, and X.-L. Li, “Preparation, characterization and antimicrobial activities of chitosan/Ag/ZnO blend films,” Chemical Engineering Journal, vol. 160, no. 1, pp. 378–382, 2010. View at Publisher · View at Google Scholar · View at Scopus
  20. S. Sepulveda-Guzman, B. Reeja-Jayan, E. de la Rosa, A. Torres-Castro, V. Gonzalez-Gonzalez, and M. Jose-Yacaman, “Synthesis of assembled ZnO structures by precipitation method in aqueous media,” Materials Chemistry and Physics, vol. 115, no. 1, pp. 172–178, 2009. View at Publisher · View at Google Scholar · View at Scopus
  21. F. Tian, Y. Liu, K. Hu, and B. Zhao, “The depolymerization mechanism of chitosan by hydrogen peroxide,” Journal of Materials Science, vol. 38, no. 23, pp. 4709–4712, 2003. View at Publisher · View at Google Scholar · View at Scopus
  22. A. Rahnama and M. Gharagozlou, “Preparation and properties of semiconductor CuO nanoparticles via a simple precipitation method at different reaction temperatures,” Optical and Quantum Electronics, vol. 44, no. 6-7, pp. 313–322, 2012. View at Publisher · View at Google Scholar · View at Scopus
  23. L.-H. Li, J.-C. Deng, H.-R. Deng, Z.-L. Liu, and L. Xin, “Synthesis and characterization of chitosan/ZnO nanoparticle composite membranes,” Carbohydrate Research, vol. 345, no. 8, pp. 994–998, 2010. View at Publisher · View at Google Scholar · View at Scopus
  24. Y. Li, Y. Wei, G. Shi, Y. Xian, and L. Jin, “Facile synthesis of leaf-like CuO nanoparticles and their application on glucose biosensor,” Electroanalysis, vol. 23, no. 2, pp. 497–502, 2011. View at Publisher · View at Google Scholar · View at Scopus
  25. C. Peniche-Covas, W. Argüelles-Monal, and J. San Román, “A kinetic study of the thermal degradation of chitosan and a mercaptan derivative of chitosan,” Polymer Degradation and Stability, vol. 39, no. 1, pp. 21–28, 1993. View at Google Scholar · View at Scopus
  26. H. Yu, J. Yu, S. Liu, and S. Mann, “Template-free hydrothermal synthesis of CuO/Cu2O composite hollow microspheres,” Chemistry of Materials, vol. 19, no. 17, pp. 4327–4334, 2007. View at Publisher · View at Google Scholar · View at Scopus
  27. A. Aguiar and A. Ferraz, “Fe3+- and Cu2+-reduction by phenol derivatives associated with Azure B degradation in Fenton-like reactions,” Chemosphere, vol. 66, no. 5, pp. 947–954, 2007. View at Publisher · View at Google Scholar · View at Scopus