International Journal of Photoenergy

International Journal of Photoenergy / 2013 / Article

Research Article | Open Access

Volume 2013 |Article ID 439079 |

Chung-Hsin Wu, Chao-Yin Kuo, Chin-Jung Lin, Peng-Ke Chiu, "Preparation of N- Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation", International Journal of Photoenergy, vol. 2013, Article ID 439079, 9 pages, 2013.

Preparation of N- Using a Microwave/Sol-Gel Method and Its Photocatalytic Activity for Bisphenol A under Visible-Light and Sunlight Irradiation

Academic Editor: Mahmoud M. El-Nahass
Received20 Nov 2012
Revised04 Jan 2013
Accepted13 Jan 2013
Published24 Feb 2013


This study applied the microwave/sol-gel method to prepare nitrogen-doped TiO2 (N-TiO2). The N-TiO2 was immobilized in glass balls to form N-TiO2/glass beads and applied to degrade Bisphenol A (BPA) under visible-light and sunlight irradiation. The characteristics of the prepared photocatalysts were analyzed by X-ray diffraction (XRD), UV-Vis spectroscopy, Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Experimental results demonstrate that the percentage of anatase increased as the amount of N in N-TiO2 increased. Compared with the undoped TiO2 (420 nm), spectra show that the absorption edge shifted to a longer wavelength (445 nm) after N doping. The XPS characterization confirms the substitution of crystal lattice O to N species in N-TiO2, forming Ti–O–N and N–Ti–O. With an increased N/Ti ratio, photodegradation efficiency increased and then decreased; moreover, the optimal amount for N doping was determined as an N/Ti mole ratio of 0.08 (0.1 NT). The efficiency of 0.1 NT in doing BPA photodegradation was greater than that of Degussa P25. After reaction for 61 min, the mineralization percentage of 0.1 NT under visible-light irradiation reached 41%. Photocatalyst efficiency decreased as the number of repeats increased in the visible-light/N-TiO2 system; however, these systems were stable during reaction.

1. Introduction

Bisphenol A (BPA), a monomer of various polymeric materials, is utilized primarily to produce epoxy resins and polycarbonate products [1]. Recent studies have shown that BPA can leach out of the plastic lining of food cans [2]. Due to its continued use in household and commercial products, large amounts of BPA have been released into aquatic environments. Based on its ability to disrupt endocrine function, the presence of BPA in aquatic environments and its potential adverse impacts on ecological and public health have garnered increased attention. Hence, researchers must develop effective remediation techniques that degrade BPA in wastewater.

Advanced oxidation processes (AOPs) are effective approaches for degrading and reducing recalcitrant wastewater loads from industrial processes. Significant progress has been made in developing AOPs for BPA degradation in recent years. Notably, AOPs involve primarily the generation of a very powerful nonselective oxidizing agent, the hydroxyl radical, which destroys pollutants. Because of its nontoxicity, photochemical stability, and reasonable cost, TiO2-based photocatalysis has been studied extensively for wastewater treatment. In ultraviolet light (UV)/TiO2-based systems, TiO2 particles absorb UV energy that is greater than the TiO2 band gap and form an electron and hole pair in the conduction band and valence band, respectively. The positive holes oxidize water molecules into hydroxyl radicals, and negative electrons reduce molecular oxygen to yield superoxide radical anions. These positive holes, hydroxyl radicals, and superoxide radical anions are the dominant oxidizing species in UV/TiO2 systems. However, rapid unfavorable recombination of photo-produced electrons and holes in TiO2 markedly reduces the photocatalytic efficiency. Additionally, TiO2 can only be photoexcited by UV; hence, developing photocatalysts that make full use of solar energy is necessary. Several investigations have synthesized sulfur-doped TiO2 (S-TiO2) [3, 4] and nitrogen-doped TiO2 (N-TiO2) [57], which extend the spectral response of TiO2 into the visible light region, thereby enhancing the photocatalytic activity of TiO2.

Various studies have used different AOPs to treat BPA, including ozone [8, 9], UV/ozone [8], UV/TiO2 [1014], visible-light/TiO2 [1517], sunlight/TiO2 [18], UV/Zr-TiO2 [19], UV/Pt-TiO2 [12], UV/Au-TiO2 [13], Fenton [14, 20, 21], UV/Fenton [20], ultrasound (US) [22, 23], US/Fenton [21], US/TiO2/Fe2+ [14], visible-light/N-TiO2 [17], and visible-light/C-N-TiO2 [24, 25] systems. Notably, BPA can be readily eliminated by the US process (~90 min); however, over 80% of the total organic carbon (TOC) remained in the solution after US irradiation for 9 h [23]. Additionally, the US/Fenton system increased the BPA degradation rate as compared to the Fenton system only [21]. The Zr-doped [19], Au-doped [13], and Pt-doped [12] TiO2 photocatalysts had better photocatalytic efficiency than pure TiO2 during the degradation of BPA under UV irradiation. Wang and Lim [24], who applied visible-light to photoexcite N-TiO2 and Degussa P25 for BPA degradation, demonstrated that the BPA removal percentage after reaction for 2 h was 29% and 5%, respectively. The BPA photodegradation rate under visible-light irradiation was as follows: N-TiO2 > Degussa P25 > undoped TiO2 [17]. Since Sojic et al. [26] suggested that nonmetals are more efficient dopants than metals for TiO2, TiO2 and N-TiO2 were selected as photocatalysts for BPA degradation in this study.

A slurry reactor system was used in most experiments, in which TiO2 particles were suspended in the form of a colloid and utilized as a photocatalyst. However, the required separation of the ultrafine photocatalyst particles from the treated liquid hindered the wide application of slurry photocatalytic reaction systems. Only Nakashima et al. [10] and Wang et al. [15] have used a UV/immobilized TiO2 system to degrade BPA. No study has investigated the BPA photodegradation by visible-light/immobilized TiO2 and sunlight/immobilized TiO2 systems. This study synthesizes TiO2 and N-TiO2 using the microwave/sol-gel method and immobilizes photocatalysts on glass balls to form fixed beads. The objectives of this study are to (i) identify the characteristics of prepared TiO2 and N-TiO2 particles, (ii) compare the photocatalytic activity of TiO2 and N-TiO2 for BPA degradation under visible-light and sunlight irradiation under an immobilized condition, (iii) determine the effects of photocatalyst dosage and amount of N doping, and (iv) investigate repeated usability of the visible-light/immobilized N-TiO2 system for BPA degradation.

2. Materials and Methods

2.1. Materials

The Ti and N source was ethyl titanate (C8H20O4Ti) and urea, respectively (Merck). Ethanol was applied as a modulator when preparing TiO2. The parent compound, BPA, was obtained from Sigma-Aldrich (purity > 99%). Solution pH was adjusted using HNO3 and NaOH. Degussa P25 was utilized as the standard material to compare photocatalytic activity of prepared TiO2 and N-TiO2 for BPA photodegradation. All chemicals were analytical reagent grade and used as received.

2.2. Preparation of the Immobilized TiO2/Glass Bead and N-TiO2/Glass Bead

Figure 1 presents a flowchart of the procedure used to prepare immobilized N-TiO2/glass beads. In preparing N-TiO2, 44 mL C8H20O4Ti was mixed with 60 mL ethanol and then mixed further with 180 mL deionized water. An appropriate amount of urea (0.3, 0.5, 1, 3, and 9 g) was added. Then, 8 mL HNO3 was added, and the entire mixture was stirred at 250 rpm for 24 h. After gel formation, the batch was dehydrated at 120°C. Dehydrated gels were first ground, and 5 mL deionized water was then added. The resulting gels were irradiated in a 700 W microwave (2425–2475 MHz) for 30 min to generate N-TiO2 powder. Glass balls (5 mm in diameter) were etched to generate a rugged surface in 5 M NaOH (100°C) for 5 h. The N-TiO2 and pretreated glass balls were washed 5 times with deionized water. The clean and etched glass balls were immersed in a 5% (w/v) N-TiO2 solution. The glass balls were conditioned at 120°C for 12 h to form immobilized N-TiO2/glass beads. The mole ratio of N/Ti for the obtained N-TiO2/glass beads under addition of 0.3, 0.5, 1, 3, and 9 g urea was 0.05, 0.08, 0.17, 0.5, and 1.5, respectively, and these N-TiO2/glass beads are denoted as 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT, and 1.5 NT herein, respectively. If no urea was added, the TiO2/glass beads (T) were produced. The 5% (w/v) Degussa P25 solution was also calcined with pretreated glass balls at 120°C for 12 h to form a Degussa P25/glass beads (P).

2.3. Characterization

The crystallinity of photocatalysts was analyzed by X-ray diffraction (XRD) using CuKα radiation (Bruker AXS). Accelerating voltage and applied current were 40 kV and 30 mA, respectively. The XRD patterns were recorded as 2θ values at 10–80° and a scanning speed of 3°/min. The UV-Vis spectroscopy (Jasco V-670) method was applied to profile the absorbance spectrum of photocatalysts at wavelengths of 200–800 nm. The UV-Vis diffuse reflectance spectra were used to calculate photocatalyst band gap energy. Functional groups of photocatalysts were identified by Fourier transform infrared spectroscopy (FTIR) using a Spectrum One and AutoIMAGE system (Perkin Elmer) via the KBr pressed disc method. An inductively coupled plasma-optical emission spectrometer (ICP-OES, Optima 2100DV) was utilized to measure the TiO2 concentration in effluent. The X-ray photoelectron spectroscopy (XPS) measurements were performed using a Vacuum Generator ESCALAB MKΠ photoelectron spectrometer (East Grinsted) with an ALKR 1, 2 (1486.6 eV) X-ray source. Binding energies of photoelectrons were determined based on the assumption that carbon 1s electrons were at 284.5 eV. The BPA concentration was measured using a high-performance liquid chromatograph (HPLC) with a UV detector (Agilent Technologies). The UV detector was set to a wavelength of 197 nm. Separations were performed using a Supelcosil C18 column (Supelco). The mobile phase was Milli-Q water and CH3CN (40 : 60 v/v) at a flow rate of 0.5 mL/min. Injection volume was 20 μL. The decrease in TOC, measured using an O.I. 1010 TOC analyzer, indicated a BPA mineralization.

2.4. Photodegradation of BPA

The photocatalytic reactor (Figure 2) consisted of 4 30 cm long quartz tubes and 5 visible-light lamps. The external diameter of each tube was 1.2 cm, and the internal diameter was 1 cm. In total, 10–40 photocatalyst/glass balls were filled into each quartz tube before 10 mg/L of BPA solution was introduced into the system using a peristaltic pump. The photocatalyst dosage in the photocatalytic reactor was 1.7–6.7 g/L. The optimal experimental pH for BPA degradation in the sunlight/TiO2 system was 6, because a chemical treatment was not needed, including a neutralization process [18]. Hence, the initial solution pH was adjusted to 6 herein. The flow rate of the BPA solution was maintained at 1.5 mL/min. The column photoreactor was irradiated with 410 nm visible light (8 W, Philips) at room temperature. The quartz tubes were arranged at equal distances around the 5 lamps. Moreover, the system was analyzed under sunlight in selected experiments for comparison purposes. The intensity of visible light and sunlight was 2.88 and 23.46–24.06 mW/cm2, respectively. Some experiments were performed in triplicate, and average values are reported.

3. Results and Discussion

3.1. Physical Characterization of Photocatalysts

Figure 3 shows XRD patterns of N-TiO2 samples with differing N content. The 2θ peaks at 25.5°, 37.8°, and 48.1° indicate anatase-type TiO2, and those at 27.5° and 36.1° indicate rutile-type TiO2. No N-derived peak was detected in any pattern. Anatase is considered the photoactive form, whereas rutile exhibits low photocatalytic activity. However, the source of the activity difference remains unknown. The ratio of anatase to rutile in photocatalysts was calculated using the following well-known formula [27]: where is the fraction of anatase in the photocatalyst, is the (101) peak intensity of anatase at 25.5°, is the (110) peak intensity of rutile at 27.5°, and 1.265 is the scattering coefficient. Degussa P25, which is a standard material in photocatalytic reactions, contains anatase and rutile phases at a ratio of roughly 3 : 1 (Table 1). The synthesized TiO2 particles have less anatase than Degussa P25. As the amount of N in N-TiO2 increases, the ratio of anatase to rutile increases (Table 1). The XRD diagrams indicate that N doping retards the transformation of TiO2 phase from anatase to rutile. This retardation of phase transformation may be due to stabilization of the anatase phase by surrounding N ions via the formation of Ti–O–N bonds. Ma et al. [7] obtained similar analytical results for samarium doping.

PhotocatalystsCrystalline phaseAbsorbed wavelength (nm)Band gap (eV)
Anatase (%)Rutile (%)

0.05 NT33.266.84292.89
0.1 NT34.565.54382.83
0.2 NT41.958.14452.79
0.5 NT63.037.04452.79
1.5 NT73.626.44452.79

The electronic structure of a photocatalyst affects its optical absorption and migration of light-induced electrons and holes. The band gap of the photocatalyst was calculated using the formula , where is the wavelength value corresponding to the intersection point of the vertical and horizontal section of spectra. The impact of N doping on the band gap of N-TiO2 is investigated (Table 1). Compared with undoped TiO2 (420 nm), the spectra show the absorption edge shifting to a longer wavelength (445 nm) after N doping. All N-TiO2 had high photoabsorption capacity in the range of UV light to visible light, and the number of photo-generated electrons and holes to participate in the photocatalytic reaction was increased; additionally, the significant narrowing of the band gap is of great importance for practical applications of N-TiO2 since N-TiO2 can be activated by sunlight (Table 1).

The band gap energy of Degussa P25 was 3.00 eV (Table 1), and this value was the same as that determined by Silveyra et al. [6] and Liu et al. [28]. The band gap energy of TiO2 decreased from 2.95 eV to 2.79 eV via N doping (Table 1). In previous studies, the band gap energy of TiO2 decreased from 3.01 eV to 2.88 eV via N doping [6]; moreover, the same trend (band gap energy of TiO2 decreasing from 3.09 eV to 2.84 eV) was also obtained by Ma et al. [7]. Hussain et al. [29] and Wang et al. [30] indicated that the band gap value of a photocatalyst decreases as the amount of dopant increases. Notably, N-doping was effective in decreasing the band gap of TiO2 by generating an isolated N 2p narrow band above the O 2p valence, which formed by incorporating N atoms into the TiO2 lattice [5].

Figure 4 shows the FTIR spectra of different photocatalysts obtained with different urea concentrations. Three major absorbance peaks were observed at 1384, 1625, and 3130 cm−1. The absorption peak at 1625 cm−1 belongs to the Ti-O structure [29, 31, 32]. The board absorption band at 3100–3300 cm−1 was characteristic of OH stretching vibrations on the photocatalyst surface [31]. The peak at 1384 cm−1 corresponds to the surface adsorbed molecules [33]. Adsorption of molecules onto prepared photocatalysts can be attributed to adding HNO3 during photocatalyst preparation. Hu et al. [34] demonstrated that hydrolysis of TiCl4 in a urea solution led to chemisorption of NH3 molecules on the TiO2 surface and to the formation of nitride species in the TiO2 lattice. However, N atoms incorporated into the TiO2 crystal lattice were not identified by FTIR analysis in this study.

The XPS characterization further confirms the substitution of crystal lattice O for N species in N-TiO2. Figure 5 shows XPS spectra for the N 1s region of N-doped TiO2 for 0.05 NT, 0.1 NT, 0.2 NT, and 0.5 NT, respectively, and their fitting curves. After curve fitting, two peaks with binding energies of 399 and 401 eV were identified. The peak at 399 eV has been attributed to anionic N in N–Ti–O linkages by many researchers [5, 35]. Another peak at a higher binding energy of 401 eV for the N 1s region of N-TiO2 was attributed to oxidized N in Ti–O–N. Xing et al. [36] indicated that this oxidized N in Ti–O–N is chemically adsorbed onto the catalyst surface and appears at a high binding energy of 401 eV in N 1s XPS spectra. The Ti 2p region of 0.2 NT shows that the Ti 2p3/2 and Ti 2p1/2 core levels in N-TiO2 appear at 458.5 and 464.3 eV, respectively (Figure 6). The binding energies of Ti 2p3/2 and Ti 2p1/2 after N doping decreased when compared with that of pure TiO2 (Ti 2p3/2 appears at 459.1 eV, and Ti 2p1/2 appears at 465.0 eV). The possible reason is that N is incorporated into the lattice and substitutes for O, and the lower electronegativity of N compared with that of O leads to electron transformation from N to Ti to increase electron density on Ti [31, 37]. The XPS spectra of the O 1s region of 0.2 NT have two peaks after curve fitting (Figure 7). The peak at 529.8 eV is attributed to O 1s in Ti–O linkages of TiO2. Another peak at 531.5 eV is attributed to the presence of Ti–O–N bonds [38, 39]. The peaks at about 529.8 and 531.5 eV indicate the presence of two oxygen states, Ti–O–Ti and Ti–O–N, respectively. Based on these observations, we conclude that the chemical states of N-doped TiO2 may coexist as N–Ti–O (N1) and Ti–O–N (N2). According to the XPS spectra, different fitting peak nitrogen percentages in the TiO2 were calculated in relation to titanium (Table 2). The highest N1/N2 ratio was 0.2 NT; additionally, the highest N-doping concentration was 0.5 NT (Table 2). Xing et al. [36] indicated that when the N/Ti value increases, the ratio of N1/N2 increases first and then decreases; this study obtained a similar trend.

0.05 NT0.1 NT0.2 NT0.5 NT

Total doping N0.15%0.16%0.33%0.35%

N1 refers to N in N–Ti–O linkages. N2 refers to N in Ti–O–N.
3.2. Effects of Photocatalyst Dosage and Amount of N Doping in TiO2

Under the addition of 6.7 g/L photocatalyst, the adsorption of BPA by T, P, 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT, and 1.5 NT after reaction for 61 min was 25%, 5%, 15%, 12%, 10%, 11%, and 12%, respectively. After reaction for 61 min, the photolysis of BPA by 410 nm visible light, and sunlight irradiation was 4% and 29%, respectively. The BPA removal was ineffective by photocatalyst adsorption and photolysis. Figure 8 shows the BPA removal percentages under different photocatalyst dosages. Under 410 nm visible-light irradiation on 0.2 NT, BPA removal at 1.7, 3.3, 5.0, and 6.7 g/L was 29%, 49%, 59%, and 64%, respectively; additionally, for 0.2 NT under sunlight irradiation, BPA removal was 49%, 60%, 74%, and 75%, respectively. The BPA degradation efficiency increased as the amount of photocatalyst increased. This increase in efficiency is due to an increased total surface area, namely, the number of active sites, available for the photocatalytic reaction as the photocatalyst dosage increased [18]. Under the same photocatalyst dose, BPA removal percentage for 0.2 NT was higher than that for T and P. This study demonstrates that photocatalytic activity of TiO2 was enhanced by N doping.

Figure 9 shows the effects of the N doping dosage in TiO2 for BPA removal. Under 410 nm visible-light irradiation, BPA removal of 0.05 NT, 0.1 NT, 0.2 NT, 0.5 NT, and 1.5 NT was 66%, 68%, 64%, 62%, and 56%, respectively; moreover, under sunlight irradiation, BPA removal was 84%, 91%, 75%, 88%, and 53%, respectively. With the increase in the N/Ti ratio (ratio of urea to TiO2), photodegradation efficiency first increases and then decreases (Figure 9). The effects of the N doping dosage in catalyst for photodegradation efficiency were similar to those observed by Xing et al. [36]. A high doping concentration of N increases the energy shift due to a significant overlap of N and O states, leading to a narrow band gap in N-TiO2 (Table 1). An optimal amount of C, N, and/or S dopant exists at which they can synergistically serve as electron traps that inhibit recombination of photogenerated electron-hole pairs [5, 40]. However, an excessive amount of dopant can act as charge recombination centers. The optimal N doping amount in TiO2 in this study was identified as the N/Ti mole ratio of 0.08 (0.1 NT).

3.3. Comparisons of Different Photocatalysts for BPA Degradation

Figures 10 and 11 show the effects of different photocatalysts on BPA removal rate under 410 nm visible-light and sunlight irradiation, respectively. The BPA photodegradation rate satisfies pseudo-first-order kinetics, and various studies have demonstrated that photodegradation rates for organics can be approximated using pseudo-first-order kinetics [7, 16, 17]. The BPA photodegradation rate was 0.1 NT > P > T > photolysis for 410 nm visible-light and sunlight irradiation. The BPA photodegradation rate by sunlight irradiation was higher than that by 410 nm visible-light irradiation because the intensity of sunlight is greater than that of 410 nm visible light. Table 3 lists the pseudo-first-order rate constants (k) of BPA for different photocatalysts. Under 410 nm visible-light irradiation, k values were in the order of 0.1 NT > 0.05 NT > 0.2 NT > P > 0.5 NT > 1.5 NT > T. Photocatalytic activity was improved significantly by N doping. Yang et al. [17] demonstrated that BPA removal percentage of undoped TiO2, Degussa P25, and N-TiO2 under visible-light irradiation in a suspended system was 5%, 15%, and 30%, respectively, and the trend was similar to that in this study. Obviously, 0.1 NT had the fastest photodegradation rate and the highest removal percentage for BPA under both 410 nm visible-light and sunlight irradiation. Therefore, 0.1 NT was utilized to evaluate BPA mineralization. The BPA removal percentage for P and 0.1 NT was 58% and 68%, respectively; additionally, the TOC removal percentage for P and 0.1 NT was 4% and 41%, respectively. Experimental results indicate that 0.1 NT was the best photocatalyst for BPA and TOC degradation.

410 nm visible lightSunlight
(hr−1) (hr−1)

0.05 NT1.130.9481.890.960
0.1 NT1.210.9222.590.961
0.2 NT1.060.9931.430.929
0.5 NT0.890.9822.000.977
1.5 NT0.730.9830.830.936

Figure 12 lists the photocatalytic efficiency of repeated tests for P and 0.1 NT under 410 nm visible-light irradiation. The BPA removal of P in runs 1, 2, 3, 4, and 5 was 60%, 58%, 50%, 42%, and 39%, respectively; moreover, that of 0.1 NT was 68%, 66%, 59%, 52%, and 49%, respectively. Photocatalyst efficiency decreased as the number of repeats increased. The factor of (efficiency in run 5)/(efficiency in run 1) for P and 0.1 NT was 0.65 and 0.72, respectively. The performance of cyclic usability for 0.1 NT was greater than that for P. The concentration of released TiO2 in effluent for 0.1 NT was 1.13 mg/L in run 1; additionally, no TiO2 was released in effluent during runs 2–5. Experimental results demonstrate that 0.1 NT was the best photocatalyst, and visible-light-immobilized N-TiO2 and sunlight-immobilized N-TiO2 systems are suitable for BPA degradation. Additionally, visible-light-immobilized N-TiO2 system was stable during photocatalytic degradation.

4. Conclusions

This investigation utilized N-TiO2/glass immobilized beads to degrade BPA. The ratio of anatase in prepared N-TiO2 increased as the N/Ti ratio increased; conversely, band gap energy decreased as the N/Ti ratio increased. Two forms of N-TiO2, Ti–O–N and N–Ti–O, were identified by XPS analysis. The optimal N/Ti mole ratio was 0.08, and N doping synergistically served as electron traps that inhibited recombination of photogenerated electron-hole pairs. The BPA degradation efficiency increased as the photocatalyst dose increased; moreover, the photocatalytic activity of N-TiO2 was higher under sunlight irradiation than under visible-light irradiation. The TOC removal percentage during BPA photodegradation was 0.1 NT > P. This study suggested that visible-light-immobilized N-TiO2 and sunlight-immobilized N-TiO2 systems are effective for BPA degradation. Moreover, the visible-light-immobilized N-TiO2 system had a high cyclic efficacy for BPA photodegradation.


The authors would like to thank the National Science Council Taiwan, for financially supporting this research under Contract no. NSC 101–2221-E-151-038-MY3.


  1. C. A. Staples, P. B. Dorn, G. M. Klecka, S. T. O'Block, and L. R. Harris, “A review of the environmental fate, effects, and exposures of bisphenol A,” Chemosphere, vol. 36, no. 10, pp. 2149–2173, 1998. View at: Publisher Site | Google Scholar
  2. J. A. Brotons, M. F. Olea-Serrano, M. Villalobos, V. Pedraza, and N. Olea, “Xenoestrogens released from lacquer coatings in food cans,” Environmental Health Perspectives, vol. 103, no. 6, pp. 608–612, 1995. View at: Google Scholar
  3. W. Ho, J. C. Yu, and S. Lee, “Low-temperature hydrothermal synthesis of S-doped TiO2 with visible light photocatalytic activity,” Journal of Solid State Chemistry, vol. 179, no. 4, pp. 1171–1176, 2006. View at: Publisher Site | Google Scholar
  4. L. Szatmáry, S. Bakardjieva, J. Subrt et al., “Sulphur doped nanoparticles of TiO2,” Catalysis Today, vol. 161, no. 1, pp. 23–28, 2011. View at: Publisher Site | Google Scholar
  5. R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science, vol. 293, no. 5528, pp. 269–271, 2001. View at: Publisher Site | Google Scholar
  6. R. Silveyra, L. T. Saenz, W. A. Flores, V. C. Martınez, and A. A. Elguezabal, “Doping of TiO2 with nitrogen to modify the interval of photocatalytic activation towards visible radiation,” Catalysis Today, vol. 107, pp. 602–605, 2005. View at: Publisher Site | Google Scholar
  7. Y. Ma, J. Zhang, B. Tian, F. Chen, and L. Wang, “Synthesis and characterization of thermally stable Sm,N co-doped TiO2 with highly visible light activity,” Journal of Hazardous Materials, vol. 182, no. 1–3, pp. 386–393, 2010. View at: Publisher Site | Google Scholar
  8. S. Irmak, O. Erbatur, and A. Akgerman, “Degradation of 17β-estradiol and bisphenol A in aqueous medium by using ozone and ozone/UV techniques,” Journal of Hazardous Materials, vol. 126, no. 1–3, pp. 54–62, 2005. View at: Publisher Site | Google Scholar
  9. M. Debordea, S. Rabouana, P. Mazelliera, J. P. Duguetc, and B. Legubea, “Oxidation of bisphenol A by ozone in aqueous solution,” Water Research, vol. 42, no. 16, pp. 4299–4308, 2008. View at: Publisher Site | Google Scholar
  10. T. Nakashima, Y. Ohko, D. A. Tryk, and A. Fujishima, “Decomposition of endocrine-disrupting chemicals in water by use of TiO2 photocatalysts immobilized on polytetrafluoroethylene mesh sheets,” Journal of Photochemistry and Photobiology A, vol. 151, no. 1–3, pp. 207–212, 2002. View at: Publisher Site | Google Scholar
  11. N. Watanabe, S. Horikoshi, H. Kawabe, Y. Sugie, J. Zhao, and H. Hidaka, “Photodegradation mechanism for bisphenol A at the TiO2/H2O interfaces,” Chemosphere, vol. 52, no. 5, pp. 851–859, 2003. View at: Publisher Site | Google Scholar
  12. K. Chiang, T. M. Lim, L. Tsen, and C. C. Lee, “Photocatalytic degradation and mineralization of bisphenol A by TiO2 and platinized TiO2,” Applied Catalysis A, vol. 261, no. 2, pp. 225–237, 2004. View at: Publisher Site | Google Scholar
  13. Y. B. Xie and X. Z. Li, “Degradation of bisphenol A in aqueous solution by H2O2-assisted photoelectrocatalytic oxidation,” Journal of Hazardous Materials, vol. 138, no. 3, pp. 526–533, 2006. View at: Publisher Site | Google Scholar
  14. R. A. Torres-Palma, J. I. Nieto, E. Combet, C. Pétrier, and C. Pulgarin, “An innovative ultrasound, Fe2+ and TiO2 photoassisted process for bisphenol a mineralization,” Water Research, vol. 44, no. 7, pp. 2245–2252, 2010. View at: Publisher Site | Google Scholar
  15. R. Wang, D. Ren, S. Xia, Y. Zhang, and J. Zhao, “Photocatalytic degradation of Bisphenol A (BPA) using immobilized TiO2 and UV illumination in a horizontal circulating bed photocatalytic reactor (HCBPR),” Journal of Hazardous Materials, vol. 169, no. 1–3, pp. 926–932, 2009. View at: Publisher Site | Google Scholar
  16. C. Y. Kuo, C. H. Wu, and H. Y. Lin, “Photocatalytic degradation of bisphenol A in a visible light/TiO2 system,” Desalination, vol. 256, no. 1–3, pp. 37–42, 2010. View at: Publisher Site | Google Scholar
  17. J. Yang, J. Dai, and J. Li, “Synthesis, characterization and degradation of Bisphenol A using Pr, N co-doped TiO2 with highly visible light activity,” Applied Surface Science, vol. 257, no. 21, pp. 8965–8973, 2011. View at: Publisher Site | Google Scholar
  18. S. Kaneco, M. A. Rahman, T. Suzuki, H. Katsumata, and K. Ohta, “Optimization of solar photocatalytic degradation conditions of bisphenol A in water using titanium dioxide,” Journal of Photochemistry and Photobiology A, vol. 163, no. 3, pp. 419–424, 2004. View at: Publisher Site | Google Scholar
  19. B. Gao, T. M. Lim, D. P. Subagio, and T. T. Lim, “Zr-doped TiO2 for enhanced photocatalytic degradation of bisphenol A,” Applied Catalysis A, vol. 375, no. 1, pp. 107–115, 2010. View at: Publisher Site | Google Scholar
  20. H. Katsumata, S. Kawabe, S. Kaneco, T. Suzuki, and K. Ohta, “Degradation of bisphenol A in water by the photo-Fenton reaction,” Journal of Photochemistry and Photobiology A, vol. 162, no. 2-3, pp. 297–305, 2004. View at: Publisher Site | Google Scholar
  21. I. Ioan, S. Wilson, E. Lundanes, and A. Neculai, “Comparison of Fenton and sono-Fenton bisphenol a degradation,” Journal of Hazardous Materials, vol. 142, no. 1-2, pp. 555–558, 2007. View at: Publisher Site | Google Scholar
  22. M. Inoue, Y. Masuda, F. Okada, A. Sakurai, I. Takahashi, and M. Sakakibara, “Degradation of bisphenol A using sonochemical reactions,” Water Research, vol. 42, no. 6-7, pp. 1379–1386, 2008. View at: Publisher Site | Google Scholar
  23. R. A. Torres, C. Pétrier, E. Combet, M. Carrier, and C. Pulgarin, “Ultrasonic cavitation applied to the treatment of bisphenol A. Effect of sonochemical parameters and analysis of BPA by-products,” Ultrasonics Sonochemistry, vol. 15, no. 4, pp. 605–611, 2008. View at: Publisher Site | Google Scholar
  24. X. Wang and T. T. Lim, “Solvothermal synthesis of C-N codoped TiO2 and photocatalytic evaluation for bisphenol A degradation using a visible-light irradiated LED photoreactor,” Applied Catalysis B, vol. 100, no. 1-2, pp. 355–364, 2010. View at: Publisher Site | Google Scholar
  25. X. Wang and T. T. Lim, “Effect of hexamethylenetetramine on the visible-light photocatalytic activity of C-N codoped TiO2 for bisphenol A degradation: evaluation of photocatalytic mechanism and solution toxicity,” Applied Catalysis A, vol. 399, no. 1-2, pp. 233–241, 2011. View at: Publisher Site | Google Scholar
  26. D. V. Sojic, V. N. Despotovic, N. D. Abazovic, M. I. Comor, and B. F. Abramovic, “Photocatalytic degradation of selected herbicides in aqueous suspensions of doped titania under visible light irradiation,” Journal of Hazardous Materials, vol. 179, no. 1–3, pp. 49–56, 2010. View at: Publisher Site | Google Scholar
  27. R. A. Spurr and H. Myers, “Quantitative analysis of anatase-rutile mixtures with an X-ray diffractometer,” Analytical Chemistry, vol. 29, no. 5, pp. 760–762, 1957. View at: Google Scholar
  28. S. Y. Liu, Q. L. Tang, and Q. G. Feng, “Synthesis of S/Cr doped mesoporous TiO2 with high-active visible light degradation property via solid state reaction route,” Applied Surface Science, vol. 257, no. 13, pp. 5544–5551, 2011. View at: Publisher Site | Google Scholar
  29. S. T. Hussain, K. Khan, and R. Hussain, “Size control synthesis of sulfur doped titanium dioxide (anatase) nanoparticles, its optical property and its photo catalytic reactivity for CO2+H2O conversion and phenol degradation,” Journal of Natural Gas Chemistry, vol. 18, no. 4, pp. 383–391, 2009. View at: Publisher Site | Google Scholar
  30. Y. Wang, Y. Huang, W. Ho, L. Zhang, Z. Zou, and S. Lee, “Biomolecule-controlled hydrothermal synthesis of C-N-S-tridoped TiO2 nanocrystalline photocatalysts for NO removal under simulated solar light irradiation,” Journal of Hazardous Materials, vol. 169, no. 1–3, pp. 77–87, 2009. View at: Publisher Site | Google Scholar
  31. H. Li, J. Li, and Y. Huo, “Highly active TiO2N photocatalysts prepared by treating TiO2 precursors in NH3/ethanol fluid under supercritical conditions,” The Journal of Physical Chemistry B, vol. 110, no. 4, pp. 1559–1565, 2006. View at: Publisher Site | Google Scholar
  32. J. H. Xu, W. L. Dai, J. Li et al., “Simple fabrication of thermally stable apertured N-doped TiO2 microtubes as a highly efficient photocatalyst under visible light irradiation,” Catalysis Communications, vol. 9, no. 1, pp. 146–152, 2008. View at: Publisher Site | Google Scholar
  33. F. Cot, A. Larbot, G. Nabias, and L. Cot, “Preparation and characterization of colloidal solution derived crystallized titania powder,” Journal of the European Ceramic Society, vol. 18, no. 14, pp. 2175–2181, 1998. View at: Google Scholar
  34. S. Hu, A. Wang, X. Li, and H. Löwe, “Hydrothermal synthesis of well-dispersed ultrafine N-doped TiO2 nanoparticles with enhanced photocatalytic activity under visible light,” Journal of Physics and Chemistry of Solids, vol. 71, no. 3, pp. 156–162, 2010. View at: Publisher Site | Google Scholar
  35. C. Burda, Y. Lou, X. Chen, A. C. S. Samia, J. Stout, and J. L. Gole, “Enhanced nitrogen doping in TiO2 nanoparticles,” Nano Letters, vol. 3, no. 8, pp. 1049–1051, 2003. View at: Publisher Site | Google Scholar
  36. M. Xing, J. Zhang, and F. Chen, “New approaches to prepare nitrogen-doped TiO2 photocatalysts and study on their photocatalytic activities in visible light,” Applied Catalysis B, vol. 89, no. 3-4, pp. 563–569, 2009. View at: Publisher Site | Google Scholar
  37. M. Sathish, B. Viswanathan, R. P. Viswanath, and C. S. Gopinath, “Synthesis, characterization, electronic structure, and photocatalytic activity of nitrogen-doped TiO2 nanocatalyst,” Chemistry of Materials, vol. 17, no. 25, pp. 6349–6353, 2005. View at: Publisher Site | Google Scholar
  38. X. Chen and C. Burda, “Photoelectron spectroscopic investigation of nitrogen-doped titania nanoparticles,” The Journal of Physical Chemistry B, vol. 108, no. 40, pp. 15446–15449, 2004. View at: Publisher Site | Google Scholar
  39. J. L. Gole, J. D. Stout, C. Burda, Y. Lou, and X. Chen, “Highly efficient formation of visible light tunable TiO2-xNx photocatalysts and their transformation at the nanoscale,” The Journal of Physical Chemistry B, vol. 108, no. 4, pp. 1230–1240, 2004. View at: Google Scholar
  40. J. A. Rengifo-Herrera and C. Pulgarin, “Photocatalytic activity of N, S co-doped and N-doped commercial anatase TiO2 powders towards phenol oxidation and E. coli inactivation under simulated solar light irradiation,” Solar Energy, vol. 84, no. 1, pp. 37–43, 2010. View at: Publisher Site | Google Scholar

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