Table of Contents Author Guidelines Submit a Manuscript
International Journal of Photoenergy
Volume 2013 (2013), Article ID 658231, 6 pages
Research Article

Catalytic Activity of Porous Phosphate Heterostructures-Fe towards Reactive Black 5 Degradation

1Centro de Química de Vila Real, Universidade de Trás-os-Montes e Alto Douro, Apartado 1013, 5001-801 Vila Real, Portugal
2Centro de Geologia do Porto, Faculdade de Ciências, Universidade do Porto, Rua do Campo Alegre 687, 4169-007 Porto, Portugal
3Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga, Spain

Received 10 May 2013; Accepted 9 July 2013

Academic Editor: Mika Sillanpaa

Copyright © 2013 Marco S. Lucas et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Fenton’s reaction is often used to decompose stable substances in wastewater. In this study, experiments based on the effect of porous phosphate heterostructures as catalyst sorbent of Fe2+ synthesised by different procedures were planned. The examined PPH-Fe/H2O2 as oxidant in a heterogeneous process under mild conditions at pH 5 was found to be very efficient for discoloration of a simulated wastewater containing 50 mg L−1 of a commercial azo dye (Reactive Black 5) reaching 95% of decolourization. Under the described conditions total visual decolourization was achieved after 360 min. This study can provide a simple, effective, and economic system ideal for the treatment of toxic and nonbiodegradable azo dyes.

1. Introduction

Synthetic dyes are extensively used for textile dyeing, paper printing, color photography, and as additives in petroleum products [1]. In the textile manufacturing industry, up to 10–25% of the dyes are lost after the dyeing process and about 2–20% of them are directly discharged to the aqueous effluents in different environmental components [2]. Azo and triphenylmethane dyes are primarily produced and used in the textile industry and cause pollution if not properly treated before discharge to the environment [3, 4]. In this context, the textile industry is concerned with these xenobiotics compounds to improve the existing technologies to treat the dye containing wastewater, because they pose lethal, mutagenicity, genotoxicity, and carcinogenicity effects [5].

Conventional treatment processes have long been established such as chemical precipitation, coagulation, adsorption, and flocculation [6], but they have their own disadvantages, mainly used for insoluble dyestuff wastewater. Bioremediation techniques are considered unsatisfactorily because they need further processes. The chemical methods are based in the oxidation of the organic materials by oxidizing agents, such as O3 [79], H2O2 [10, 11], UV light [12], or combination of such oxidants [13, 14], known as advanced oxidation processes (AOPs).

Among these, the Fenton reaction, iron-based photocatalytic systems via hydroxyl radicals produced by H2O2 under UV, has attracted much attention for wastewater treatments because of their efficient, low cost, and benignity to environment [15, 16]. This catalytic system decolourizes completely and partially mineralized textile dyes in short reaction time [17]. Common Fenton processes involve the application of ferrous or ferric salts and hydrogen peroxide in order to produce hydroxyl radicals (HO). However, despite the high efficiency, the process generates a high amount of sludge in the coagulation step for the elimination of the iron added. For this reason, in the last years, an important effort has been done in the field of heterogeneous catalysis to facilitate the elimination and reuse of iron [18, 19].

Advanced oxidation processes (AOPs) have been developed in the last decades to environmental applications, mainly focused on the removing by mineralization of refractory organic compounds. For this, Fenton reaction catalysed by Fe2+ is used with hydrogen peroxide as oxidizing agent and for photo-Fenton process with the UV irradiation. Normally, Fenton and photo-Fenton are homogeneous processes where Fe2+ cations are in solution; however some limitations related with the eventually precipitation of insoluble ferric hydroxides, which require an acidification of solution and by their use the materials of reactor must be resistant to corrosion. Furthermore, in homogeneous processes, an additional step of separation must be made for recovering the catalyst. Because of these limitations heterogeneous catalyst can be an alternative, and several solid catalysts which incorporate Fe2+ are tested in Fenton or photo-Fenton reactions. Thus, has been tested as heterogeneous catalyst iron-containing zeolites [20], clay pillared by Fe hydroxo complexes or by Fe2+ cationic exchange, or wet impregnation with a Fe2+ solution of an adequate support.

On the other hand, porous phosphate heterostructures (PPH) are a new kind of versatile porous materials, which are application as catalyst and sorbent. The synthesis of this material combines the methodologies of pillared layered structures (PLS) and silica mesostructured with surfactant as MCM-41 type. Thus, into interlayer space of zirconium phosphate, silica galleries are formed using surfactant molecules as templates. After surfactant removing a mesoporous material is obtained with high specific area (600 m2 g−1) and a cationic exchange capacity (CEC) of surface 1.7 meq g−1 due to the presence of PO-H and SiO-H surface groups [21]. Because of these properties, this material has been tested as solid acid catalyst and as support of metallic species as Ru or Cu in the synthesis of catalysts [22, 23]. Also, hybrid PPH are also synthesized adding an organosilane derivate together with tetraethyl orthosilicate (TEOS) as silica precursor. Thus, propionitrile, aminopropyl, or mercaptopropyl groups are incorporated on the surface of silica galleries, and surface chemical and physics properties can be modified for specific applications [2431]. In this line, mercaptopropyl groups can be oxidized to sulfonic acid increasing the acidity and CEC [27].

High specific surface area and CEC are two parameters interesting for the synthesis of Fe2+ exchanged PPH or Fe2+ supported PPH using as well PPH pure silica or a hybrid sulfonic-PPH obtained by oxidation of the respective mercaptopropyl-PPH precursor, obtaining new materials with potential use as heterogeneous catalyst for Fenton and photo-Fenton reactions.

In the present work, Fe2+-PPH materials were synthesized by different procedures, and the decolourization of Reactive Black 5, a textile azo dye, was achieved by means of heterogeneous Fenton reagent process. Colour and iron leaching were followed along experiments.

2. Experimental

2.1. Materials

Azo dye Reactive Black 5 (RB5, CI 20505) was obtained from Dystar Anilinas Texteis Lda (Portugal) and used without any further purification. H2O2 (Perhydrol, 30% w/w) and FeSO47H2O were purchased from Merck (Darmstadt, Germany) and Sigma-Aldrich Spain, respectively, and other chemicals were at least analytical grade reagents. Solutions were prepared by dissolving the dye in deionized Millipore water accordingly to desired final concentrations (w/v). The pH was monitored in initial and treated samples (Denver Instrument Company).

2.2. Preparation of the Catalyst

Porous phosphate heterostructures (PPH) were synthesized according to previously reported procedures [21]. Thus, to a solution of CTMA-Br in 1-propanol and H3PO4 (85%), zirconium(IV) propoxide (70%) is added with a respective molar ratio CTMA-Br : H3PO4 : Zr-oPr 1,5 : 1 : 0,5. After 3 days under stirring, the obtained cetyltrimethylamonium-ZrP (CTMAZrP) was centrifuged and washed three times with 1-propanol and suspended in water (10 g L−1). Next, a solution of hexadecylamine in 1-propanol (35 g L−1) was added as a cosurfactant. After one day of stirring, a solution (50%, v/v in 1-propanol) of tetraethylorthosilicate (TEOS) is added. After three days under stirring the solid is recovered by filtration, washed three times with deionised water, and dried 1 day at 60°C in air. The solid was calcined at 550°C for 5 hours (1.5 K min−1 heating rate) and PPH is obtained.

Hybrid S-PPH was obtained by a similar process [25], but mercaptopropyltrimethoxysilane (MPTMS) was added together with TEOS at 5 : 1 TEOS : MPTMS molar ratio. In this case, it is not possible to remove surfactant molecules by calcination, and an acid extraction was carried out with an HCl : ethanol solution (1 : 10 v/v). To oxidize thiol group to sulfonate, S-PPH (1 g) was suspended in methanol (10 mL), and H2O2 (33%, 1 mL) was added. After 1 day under stirring, the solid is filtered and washed with water, ether and acidified with a solution of H2SO4 0.2 M [27]. The solid is dried in air at 60°C, and SO3-PPH is obtained. Thus, with the incorporation of sulfonic acid on the surface of silica galleries, the CEC is increased from 1.7 to 3.10 meq g−1 for PPH. Fe exchanged materials were obtained by adding PPH and SO3-PPH to an adequate volume of solution, which contains 10 times the respective CEC. The solid was washed three times with deionised water and dried in air at 60°C. These solids were named Fe-PPH (exc) and FeSO3-PPH (exc), respectively. Fe impregnated PPH material, PPH-Fe (imp), was prepared by wet incipient impregnation of the PPH support using an aqueous solution FeCl2 (0.2 M) which contains 2 times the CEC. After impregnation the sample was dried at 60°C in air.

2.3. Fenton’s Reagent Experiments

Batch experiments for Fenton oxidation were performed in a cylindrical borosilicate glass reactor of 800 mL of capacity, with sampling ports at the top. The reaction temperature was kept at the desired value within 5°C using a thermostatically controlled outer water jacket. For every experiment performed, the reactor was initially loaded with PPH (1 gL−1) and 500 mL of RB5 (50 mgL−1) aqueous solution, and continuous mixing was maintained by means of a magnetic stirrer. In all experiments necessary quantities of freshly RB5 and H2O2 ( M) were prepared from stock solutions. Experiments were carried out, at an initial pH 5 because the nonbuffered solutions used in the reaction of Fenton suffer a pH decrease during the reaction time to a pH range around 3-4 [23]. Absorbance readings at visible maximum peak were performed using a Jasco V-530 spectrophotometer. Na2SO3 was used to quench the oxidation before the spectrophotometer analysis. The iron lixiviation from PPH support was followed by atomic absorption spectroscopy (AAS) using a Unicam ICE 3000 Series. All values presented are the means of at least three independent assays unless otherwise stated. The observed standard deviation of experimental data was always less than 6% of the reported value. The concentration of residual RB5 was calculated by Beer-Lambert law, after dilution when necessary, using the optical density and the molar extinction coefficient observed at the characteristic wavelength and expressed as where and are the concentrations of RB5 at reaction time and initial, respectively.

2.4. Characterization Methods

Powder X-ray diffraction (XRD) patterns were recorded on a Siemens D5000 diffractometer, equipped with a graphite monochromator and using Cu Kα radiation. The specific surface areas of the solids were evaluated from the N2 adsorption-desorption isotherms at −196°C in a MICROMERITICS ASAP 2020 apparatus, after degassing at 200°C and 1.3.10-2 Pa for 24 h. Fe content was determined using inductively coupled plasma spectrometry (ICP) Optima 7300 DV. For this, the solids were dissolved in 0.2 mL of hydrofluoric acid (40%, v/v) at room temperature and diluted to an adequate concentration for ICP measurements.

3. Results and Discussion

3.1. Characterization of Catalyst

All materials prepared show a diffraction peak at low angle centered around 40 Å, which indicates that galleries' structure is preserved after cationic exchange as well as after the impregnation. Also, no peak is observed at high angle, even for Fe2+ supported material that evidences high dispersion of Fe2+ ions and the possible aggregates of Fe2+ salt was not formed, and due to the small size or amorphous structure, no sharp diffraction peaks are produced (see Supplementary Information in Supplementary Material available online at

Textural parameters were obtained from the N2 adsorption-desorption isotherms at 77 K. These isotherms were of type IV (Figure 1), corresponding to mesoporous type materials, and reflected their porosity due to the presence of silica galleries in the materials as is noted above in XRD characterization (Table 1).

Table 1: Textural parameters of the different substrate used in RB5 decolourization.
Figure 1: N2 adsorption-desorption isotherms at 77 K: (a) Fe-PPH (exc), (b) FeSO3-PPH (exc), and (c) PPH-Fe (imp).

In all cases, a decrease in the Brunauer-Emmett-Teller (BET) surface area was achieved with respect to the pure silica PPH material (620 m2 g−1) [20]. The BET surface area decreases with the incorporation of the Fe species.

This decreasing is more evidenced on FeSO3-PPH, because this solid requires more steps in its formation and the hybrid starting material (S-PPH) has low surface (472 m2 g−1) [24] than PPH. Here the Fenton’s reaction with RB5 leads to the decrease in aromaticity which eventually results in an increase in biodegradability and color removal of dye.

3.2. The Fenton Process in the Decolourization of RB5

Figure 2 presents the results obtained with the Fenton’s reaction in the experiments using as source of iron three PPH catalysts. FeSO3-PPH (exc) and Fe-PPH (exc) revealed to be ineffective in promoting the Fenton process. The decolourization achieved with these two PPH catalysts was small, 15.3 and 20.8%, respectively. This can be explained by the low iron available to catalyse the generation of hydroxyl radicals and consequently decolourize the RB5 solution. For other side, PPH-Fe (imp) showed an excellent capacity to catalyse the production of hydroxyl radicals. This PPH catalyst allowed reaching an RB5 decolourization of 95%, for the same reaction time, 360 minutes.

Figure 2: RB5 decolourization through heterogeneous Fenton’s reaction using three different PPH with Fe2+. [RB5] = 50 mg L−1; [PPH] = 1 g L−1;  mol L−1.

The mechanism of reaction can be described as presented in Figure 3. The iron present in the PPH-Fe (imp) structure (Fe2+) reacts with the H2O2 to generate HO radicals, which will break the azo bonds (–N=N–) and promote the RB5 decolourization.

Figure 3: Mechanistic representation of reactions possible involved in heterogeneous Fenton-like catalysed by Fe-PPH.

Figure 4 presents the UV-Vis spectra and the RB5 colour evolution along the Fenton experiment with the PPH-Fe (imp) catalyst. The RB5 UV-Vis spectra consist in two main characteristic absorption bands: one in the UV region (at 310 nm) and other in the visible region, at 595 nm.

Figure 4: RB5 photodegradation with Fe-PPH: (a) UV-Vis spectra evolution (inset the chemical structure of RB5). (b) Dye colour evolution. [RB5] = 50 mg L−1; [PPH] = 1 gL−1;  mol L−1.

The UV band is characteristic of two adjacent rings, whereas the visible band is owing to long conjugated system linked by two azo groups [32]. The RB5 decolourization spectra show that the intensity of the visible band (at 595 nm) starts to decrease faster. The UV band (at 310 nm) also vanishes but at a lower rate than the visible band. Thus, the spectra suggest that HO radicals generated first attacks azo groups, through transfer of one electron, and open the –N=N– bonds, destructing the long conjugated systems and degrading it efficiently.

Afterwards, the aromatic rings elimination also took place but needs a relative longer period of time [33]. From Figures 4(a) and 4(b) it is also possible to observe a fast color disappearance in the first minutes. This behavior reveals that iron is available to react with hydrogen peroxide as long as the experiment started, taking into account that any adsorption step was performed before Fenton’s experiment, H2O2 and Fe2+ generating hydroxyl radicals immediately, when Fe2+ belongs to the PPH structure. Thus, it is possible to assume that Fenton’s process starts without any iron leaching from PPH catalyst. Nonetheless, the concentration of Fe in solution was monitored at the end of each Fenton’s process.

The experiment performed with FeSO3-PPH (exc) revealed an iron concentration of 0.81 mg Fe L−1, the Fe-PPH (exc) 1.58 mg Fe L−1 and the PPH-Fe (imp) 4.92 mg Fe L−1, after a reaction time of 360 minutes. Therefore, although apparently at the beginning of each experiment iron is linked to the PPH, throughout the Fenton’s experiment its leaching occurs and influences the RB5 color removal. Moreover, the highest RB5 decolourization occurs precisely with the PPH catalyst that releases more iron to the solution. PPH-Fe (imp) presented the best results regarding RB5 decolourization, although its application as iron source did not avoid the presence of iron on the final treated solution.

4. Conclusions

In summary, PPH revealed to be useful as Fe2+ support in the Reactive Black 5 decolourization through Fenton reagent, although PPH ability to promote a heterogeneous Fenton reaction without iron leachate, under the experimental conditions used, seems to be inefficient. In order to overcome the drawback of the fixation of Fe2+ onto PPH supports avoiding the iron leaks, subsequent studies are planned to improve the system proposed to be applicable to water treatment.


The authors would like to thank the PEst-C/QUI/UI0616/2011 and Ciência 2007 from FCT (Lisbon, Portugal). Also thanks are due to the Spanish Ministry of Economy and Competitivity (Project CTQ2012-37925-C03-03) and Andalucía Tech Program from University of Malaga.


  1. H. Zollinger, Colour Chemistry: Synthesis, Properties and Applications of Organic Dyes and Pigments, Wiley-VCH, Weinheim, Germany, 3rd edition, 2003.
  2. A. Baban, A. Yediler, and N. K. Ciliz, “Integrated water management and CP implementation for wool and textile blend processes,” Clean, vol. 38, no. 1, pp. 84–90, 2010. View at Publisher · View at Google Scholar · View at Scopus
  3. A. B. A. Boxall, Transformation Products of Synthetic Chemicals in the Environment, The Handbook of Environmental Chemistry, part 2, Springer, Heidelberg, Germany, 2009.
  4. H. A. Erkurt, Biodegradation of Azo Dyes, vol. 9 of The Handbook of Environmental Chemistry, Springer, Heidelberg, Germany, 2010.
  5. L. Fishbein, Potential Industrial Carcinogens and Mutagens, vol. 4 of Studies in Environmental Science, Elsevier, New York, NY, USA, 1979.
  6. Y. Anjaneyulu, N. S. Chary, and D. S. S. Raj, “Decolourization of industrial effluents—available methods and emerging technologies—a review,” Reviews in Environmental Science and Biotechnology, vol. 4, no. 4, pp. 245–273, 2005. View at Publisher · View at Google Scholar · View at Scopus
  7. H.-Y. Shu and C.-R. Huang, “Degradation of commercial azo dyes in water using ozonation and UV enhanced ozonation process,” Chemosphere, vol. 31, no. 8, pp. 3813–3825, 1995. View at Publisher · View at Google Scholar · View at Scopus
  8. A. C. Gomes, J. C. Nunes, and R. M. S. Simões, “Determination of fast ozone oxidation rate for textile dyes by using a continuous quench-flow system,” Journal of Hazardous Materials, vol. 178, no. 1-3, pp. 57–65, 2010. View at Publisher · View at Google Scholar · View at Scopus
  9. M. H. Beak, C. O. Ijagbemi, and D. S. Kim, “Azo dye Acid Red 27 decomposition kinetics during ozone oxidation and adsorption processes,” Journal of Environmental Science and Health A, vol. 44, no. 6, pp. 623–629, 2009. View at Publisher · View at Google Scholar · View at Scopus
  10. O. Türgay, G. Ersöz, S. Atalay, J. Forss, and U. Welander, “The treatment of azo dyes found in textile industry wastewater by anaerobic biological method and chemical oxidation,” Separation and Purification Technology, vol. 79, no. 1, pp. 26–33, 2011. View at Publisher · View at Google Scholar · View at Scopus
  11. S. M. Palácio, F. R. Espinoza-Quiñones, A. N. Módenes, D. R. Manenti, C. C. Oliveira, and J. C. Garcia, “Optimised photocatalytic degradation of a mixture of azo dyes using a TiO2/H2O2/UV process,” Water Science and Technology, vol. 65, no. 8, pp. 1392–1398, 2012. View at Publisher · View at Google Scholar · View at Scopus
  12. A. R. Khataee, M. N. Pons, and O. Zahraa, “Photocatalytic degradation of three azo dyes using immobilized TiO2 nanoparticles on glass plates activated by UV light irradiation: influence of dye molecular structure,” Journal of Hazardous Materials, vol. 168, no. 1, pp. 451–457, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. C. P. Huang, Y. F. Huang, H. P. Cheng, and Y. H. Huang, “Kinetic study of an immobilized iron oxide for catalytic degradation of azo dye reactive black B with catalytic decomposition of hydrogen peroxide,” Catalysis Communications, vol. 10, no. 5, pp. 561–566, 2009. View at Publisher · View at Google Scholar · View at Scopus
  14. A. Xu, X. Li, Z. Xiong, Q. Wang, Y. Cai, and Q. Zeng, “High catalytic activity of cobalt (II)-triethylamine complex towards orange II degradation with H2O2 as an oxidant under ambient conditions,” Catalysis Communications, vol. 26, pp. 44–47, 2012. View at Google Scholar
  15. B. Ahmed, E. Limem, A. Abdel-Wahab, and B. Nasr, “Photo-Fenton treatment of actual agro-industrial wastewaters,” Industrial and Engineering Chemistry Research, vol. 50, no. 11, pp. 6673–6680, 2011. View at Publisher · View at Google Scholar · View at Scopus
  16. N. Klamerth, S. Malato, A. Agüera, A. Fernández-Alba, and G. Mailhot, “Treatment of municipal wastewater treatment plant effluents with modified photo-fenton as a tertiary treatment for the degradation of micro pollutants and disinfection,” Environmental Science and Technology, vol. 46, no. 5, pp. 2885–2892, 2012. View at Publisher · View at Google Scholar · View at Scopus
  17. M. S. Lucas and J. A. Peres, “Decolorization of the azo dye reactive black 5 by Fenton and photo-Fenton oxidation,” Dyes and Pigments, vol. 71, no. 3, pp. 236–244, 2006. View at Publisher · View at Google Scholar · View at Scopus
  18. R. Gonzalez-Olmos, M. J. Martin, A. Georgi, F. D. Kopinke, I. Oller, and S. Malato, “Fe-zeolites as heterogeneous catalysts for solar Fenton-like reactions at neutral pH,” Applied Catalysis B, vol. 125, pp. 51–58, 2012. View at Google Scholar
  19. R. Idel-aouad, M. Valiente, A. Yaacoubi, B. Tanouti, and M. López-Mesas, “Rapid decolourization and mineralization of the azo dye C.I. Acid Red 14 by heterogeneous Fenton reaction,” Journal of Hazardous Materials, vol. 186, no. 1, pp. 745–750, 2011. View at Publisher · View at Google Scholar · View at Scopus
  20. S. Perathoner and G. Centi, “Wet hydrogen peroxide catalytic oxidation (WHPCO) of organic waste in agro-food and industrial streams,” Topics in Catalysis, vol. 33, pp. 207–224, 2005. View at Google Scholar
  21. J. Jiménez-Jiménez, M. R. Alonso, D. Eliche-Quesada, E. Rodriguez-Castellón, and A. Jiménez-López, “Synthesis and characterization of acid mesoporous phosphate heterostructure (PPH) materials,” Journal of Materials Chemistry, vol. 15, pp. 3466–3472, 2005. View at Google Scholar
  22. J. Jiménez-Jiménez, M. Rubio-Alonso, D. Eliche-Quesada, E. R. Castellón, and A. Jiménez-López, “Synthesis and characterization of mixed silica/zirconia and silica/titania porous phospate heterostructures (PPH),” Journal of Physics and Chemistry of Solids, vol. 67, no. 5-6, pp. 1007–1010, 2006. View at Publisher · View at Google Scholar · View at Scopus
  23. M. D. Soriano, J. Jiménez-Jiménez, P. Concepción, A. Jiménez-López, E. Rodríguez-Castellón, and J. M. L. Nieto, “Vanadium oxide-porous phosphate heterostructure catalysts for the selective oxidation of H2S to sulphur,” Solid State Sciences, vol. 12, pp. 996–1001, 2010. View at Google Scholar
  24. R. Piazuelo, E. Rodríguez-Castellón, J. Jiménez-Jiménez, A. Jiménez-López, and J. Benavente, “Chemical surface and electrochemical characterization of zirconium phosphate heterostructures,” Microporous and Mesoporous Materials, vol. 115, pp. 23–32, 2008. View at Google Scholar
  25. J. Jiménez-Jiménez, M. Algarra, E. Rodriguez-Castellón, A. Jiménez-López, and J. C. G. E. da Silva, “Hybrid porous phosphate heterostructures as adsorbents of Hg(II) and Ni(II) from industrial sewage,” Journal of Hazardous Materials, vol. 190, pp. 694–699, 2011. View at Google Scholar
  26. G. Aguilar-Armenta, M. E. Patiño-Iglesias, J. Jiménez-Jiménez, E. R. Castellón, and A. Jiménez-López, “Application of porous phosphate heterostructure materials for gas separation,” Langmuir, vol. 22, pp. 1260–1267, 2006. View at Google Scholar
  27. S. Hamoudi and S. Kaliaguine, “Sulfonic acid-functionalized periodic mesoporous organosilica,” Microporous and Mesoporous Materials, vol. 59, no. 2-3, pp. 195–204, 2003. View at Publisher · View at Google Scholar · View at Scopus
  28. D. Eliche-Quesada, M. I. Macías-Ortiz, J. Jiménez-Jiménez, E. Rodríguez-Castellón, and A. Jiménez-López, “Catalysts based on Ru/mesoporous phosphate heterostructures (PPH) for hydrotreating of aromatic hydrocarbons,” Journal of Molecular Catalysis A, vol. 255, pp. 41–48, 2006. View at Google Scholar
  29. R. Moreno-Tost, M. L. Oliveira, D. Eliche-Quesada, J. Jiménez-Jiménez, A. Jiménez-López, and E. Rodríguez-Castellón, “Evaluation of Cu-PPHs as active catalysts for the SCR process to control NOx emissions from heavy duty diesel vehicles,” Chemosphere, vol. 72, no. 4, pp. 608–615, 2008. View at Publisher · View at Google Scholar · View at Scopus
  30. M. D. Soriano, J. Jiménez-Jiménez, P. Concepción, A. Jiménez-López, E. Rodríguez-Castellón, and J. M. L. Nieto, “Selective oxidation of H2S to sulfur over vanadia supported on mesoporous zirconium phosphate heterostructure,” Applied Catalysis B, vol. 92, pp. 271–279, 2009. View at Google Scholar
  31. J. Jiménez-Jiménez, P. Maireles-Torres, P. Olivera-Pastor, E. Rodríguez-Castellón, and A. Jiménez-López, “Sol-gel synthesis of dodecyltrimethylammonium-expanded zirconium phosphate and its application to the preparation of acidic porous oligomeric gallium(III)-exchanged materials,” Langmuir, vol. 13, no. 10, pp. 2857–2862, 1997. View at Google Scholar · View at Scopus
  32. J. A. Peres, L. Carvalho, R. Boaventura, and C. Costa, “Removal of COD from olive mill wastewater by Fenton's reagent: kinetic study,” Journal of Environmental Science and Health A, vol. 39, pp. 1–17, 2004. View at Google Scholar
  33. R. M. C. Silverstein, G. C. Basdler, and G. C. Morrill, Spectrophotometric Identification of Organic Compounds, Wiley, New York, NY, USA, 1991.