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International Journal of Photoenergy
Volume 2014 (2014), Article ID 854217, 10 pages
Research Article

Self-Assembly of TiO2/CdS Mesoporous Microspheres with Enhanced Photocatalytic Activity via Hydrothermal Method

Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, Wuhan, Hubei 430074, China

Received 3 April 2014; Accepted 29 April 2014; Published 2 June 2014

Academic Editor: Mei Li

Copyright © 2014 Sujing Yu et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Self assembly of TiO2/CdS mesoporous microspheres was synthesized via hydrothermal method. The samples were characterized by X-ray powder diffraction (XRD), ultraviolet-visible diffuse reflectance spectroscopy (DRS), transmission electron microscopy (TEM), energy-dispersive spectroscopy analysis (EDS), high-resolution transmission electron microscopy (HRTEM), Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), and photoluminescence spectra (PL). The as-synthesized TiO2/CdS mesoporous microspheres showed superior photocatalytic activity for the degradation of RhB under either visible light or simulated sunlight irradiation; the 10 wt% TiO2/CdS sample showed the best performance. Moreover, this catalyst showed improved stability, and the activity did not decrease significantly after four recycles. The heterojunction between TiO2 and CdS may be favorable for the transport of photoinduced electrons from CdS to TiO2. In addition, the mesoporous structure could increase the utilization of light energy and facilitate the diffusion of reactants and products during the photocatalytic reaction.