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International Journal of Photoenergy
Volume 2015 (2015), Article ID 591428, 7 pages
Research Article

Photodegradation of Methylene Blue by TiO2-Fe3O4-Bentonite Magnetic Nanocomposite

1Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China
2College of Environmental Science, Hohai University, Nanjing 210098, China

Received 20 September 2014; Revised 9 January 2015; Accepted 12 January 2015

Academic Editor: Yasser Shaban

Copyright © 2015 Wei Chen et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


-bentonite nanoparticles have been prepared by a coprecipitation technique under a nitrogen atmosphere. An aqueous suspension of bentonite was first modified with FeCl2 and FeCl3. TiO2 was then loaded onto the surface of the -bentonite by a sol-gel method. After sufficient drying, the colloidal solution was placed in a muffle furnace at 773 K to obtain the -bentonite composite. The material has been characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) analysis, and vibrating sample magnetometry (VSM). Morphological observation showed that and TiO2 nanoparticles had been adsorbed on the surface of bentonite nanoneedles. The material was then applied for the photodegradation of the azo dye methylene blue (MB). It was found that the removal efficiency of MB exceeded 90% under UV illumination, and that only a 20% mass loss was incurred after six cycles. The composite material thus showed good photocatalytic performance and recycling properties.