Research Article

Synthesis of Poly[(3-(6-(9-anthracenylmethoxy)hexyl)thiophene)-co-(3-(6-bromohexyl)thiophene)] Postfunctionalized from Poly(3-(6-bromohexyl)thiophene): A Comparative Study of the Base Polymer with Its Chlorinated Analogous

Table 2

Characterization of the polymers.

PolymerYield%Composition% (a)HT % (b)Solubility(c)Mn (g/mol) (d) (average)Mw/Mn (d) (average)

(III)5955t3.0003.2
(IV)6173t40.0002.3
(V)1073p-

(a) Molar percent of substituent, (b) head-to-tail regioregularity, in dyads, determined by 1H-RMN spectroscopy, (c) t: Wholly soluble in common organic solvents; p: Partially soluble, (d) number average molar mass, Mn: Average polydispersity index, Mw/Mn, determinated by GPC using polystyrene as standard.