Synthesis of Fluorinated Amphiphilic Block Copolymers Based on PEGMA, HEMA, and MMA via ATRP and CuAAC Click Chemistry

Table 2

Compositions of P(HEMA--MMA) obtained from ¹H-NMR data.

Comonomers in feed (volume ratio)^a	Comonomers in feed % HEMA/% MMA (mol %)^b	Comonomers in polymer % HEMA/% MMA (mol %)^c
HEMA(5)-MMA(95)	4.4/95.6	4.7/95.3
HEMA(20)-MMA(80)	18.1/81.9	18.5/81.5
HEMA(30)-MMA(70)	27.4/72.6	25.0/75.0
HEMA(50)-MMA(50)	46.9/53.1	49.1/50.9

^aby volume, ^bby moles, and ^ccalculated from ¹H-NMR.