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International Journal of Polymer Science
Volume 2014 (2014), Article ID 543930, 5 pages
Research Article

Study of Natural and Accelerated Weathering on Mechanical Properties of Antioxidants Modified Low Density Polyethylene Films for Greenhouse

1Chemical Engineering Department, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia
2Deanship of Graduate Studies, The Saudi Electronic University, Riyadh, Saudi Arabia

Received 16 March 2014; Revised 15 July 2014; Accepted 29 July 2014; Published 20 August 2014

Academic Editor: Geoffrey R. Mitchell

Copyright © 2014 Othman Al Othman et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Natural and accelerated weatherings were studied to inspect the effect of antioxidants to protect low-density polyethylene (LDPE) films for commercial application as greenhouse covering materials in Saudi Arabia. In this investigation, six different formulations of LDPE film with incorporation of antioxidants were prepared and compared with neat LDPE. The samples were extruded and blown into a film using twin-screw extruder and film blowing machine. The LDPE films were exposed for outdoor weathering in Riyadh during the period of 90 days (mid of June to mid of September) while the accelerated tests were performed by Weather-Ometer. The film having 0.2 wt% Alkanox-240 (AN-0.2) stabilizers showed the highest tensile strength among all samples during natural and 100-hour accelerated weathering (10.9 MPa and 21.8 MPa, resp.). The best elongation at break was witnessed in 0.2% Good-rite antioxidants which were 64% in natural weathering; however, 0.5% Good-rite antioxidants showed 232% in accelerated weathering. The film having 0.5 wt% Good-rite 3114 (GR-0.5) antioxidant could withstand 70 days during natural exposure before the tensile strength values were reduced to 2/3rd of the initial. The present study suggested that the addition of antioxidants Good-rite, Anox, and Alkanox can improve the mechanical strength, film’s life, effectiveness, and stability and they are suitable to be incorporated in LDPE for commercial greenhouse films.