Research Article
Preparation and Characterization of Polymer Electrolyte of Glycidyl Methacrylate-Methyl Methacrylate-LiClO4 Plasticized with Ethylene Carbonate
Table 1
Vibrational mode assignments of P(GMA-co-MMA)-25% LiClO4 based polymer electrolyte with different percentage of EC.
| Vibrational mode of P(GMA-co-MMA) | Wavenumber (cm−1) | | 0 | 20% | 40% | 60% | 80% |
| C=O stretching of EC | — | 1802, 1773 | 1801, 1771 | 1802, 1773 | 1801, 1772 | Carbonyl group stretching | 1712 | 1719 | 1719 | 1720 | 1720 | Symmetric stretching of epoxy and ester group | 1252, 1068, 850 | 1253, 1071, 566 | 1246, 1071, 875 | 1252, 1071, 890 | 1249, 1071, 896 | Stretching C–O–O of ester group | 1154 | 1153 | 1157 | 1153 | 1154 | Asymmetric stretching of epoxy | 906 | 903 | 901 | 902 | 903 | C–H blending vibration of epoxide ring | 748 | 749 | 748 | 749 | 748 | C=O bending | — | 718 | 718 | 718 | 718 |
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