Research Article

Preparation and Characterization of Polymer Electrolyte of Glycidyl Methacrylate-Methyl Methacrylate-LiClO4 Plasticized with Ethylene Carbonate

Table 1

Vibrational mode assignments of P(GMA-co-MMA)-25% LiClO4 based polymer electrolyte with different percentage of EC.

Vibrational mode of P(GMA-co-MMA)Wavenumber (cm−1)
020%40%60%80%

C=O stretching of EC1802, 1773 1801, 17711802, 17731801, 1772
Carbonyl group stretching17121719 171917201720
Symmetric stretching of epoxy and ester group1252, 1068, 850 1253, 1071, 5661246, 1071, 8751252, 1071, 8901249, 1071, 896
Stretching C–O–O of ester group1154 1153 1157 11531154
Asymmetric stretching of epoxy906 903901902903
C–H blending vibration of epoxide ring748 749 748749748
C=O bending718 718 718 718