Research Article
Photoinduced Copolymerization of APMP-MMA: The Role of Reactive Hindered Amine APMP
Table 2
Composition data of poly(APMP-co-MMA) estimated from 1H NMR spectra.
| Number | Feed ratio (APMP/MMA) | | Conv. | | | (APMP) | (MMA) |
| AM19-1 | 10/90 | 0.1 | 0.192 | 4.63 | 0.55 | 0.36 | 0.64 | AM19-2 | 0.1 | 0.325 | 3.80 | 0.42 | 0.29 | 0.71 | AM19-3 | 0.1 | 0.462 | 3.68 | 0.30 | 0.23 | 0.77 | AM19-4 | 0.1 | 0.439 | 3.34 | 0.25 | 0.20 | 0.80 | AM19-5 | 0.1 | 0.561 | 3.41 | 0.26 | 0.20 | 0.80 | AM19-6 | 0.1 | 0.605 | 3.47 | 0.25 | 0.20 | 0.80 | AM19-7 | 0.1 | 0.656 | 3.21 | 0.20 | 0.17 | 0.83 |
| AM37-1 | 30/70 | 0.3 | 0.127 | 8.25 | 0.86 | 0.46 | 0.54 | AM37-2 | 0.3 | 0.258 | 7.68 | 0.78 | 0.44 | 0.56 | AM37-3 | 0.3 | 0.324 | 7.60 | 0.77 | 0.44 | 0.56 | AM37-4 | 0.3 | 0.402 | 6.95 | 0.69 | 0.41 | 0.59 | AM37-5 | 0.3 | 0.420 | 6.88 | 0.68 | 0.40 | 0.60 | AM37-6 | 0.3 | 0.477 | 6.91 | 0.68 | 0.41 | 0.59 | AM37-7 | 0.3 | 0.513 | 7.01 | 0.70 | 0.41 | 0.59 |
| AM55-1 | 50/50 | 0.5 | 0.277 | 11.09 | 1.23 | 0.55 | 0.45 | AM55-2 | 0.5 | 0.277 | 10.82 | 1.19 | 0.54 | 0.46 | AM55-3 | 0.5 | 0.401 | 10.89 | 1.20 | 0.55 | 0.45 | AM55-4 | 0.5 | 0.431 | 10.62 | 1.17 | 0.54 | 0.46 | AM55-5 | 0.5 | 0.534 | 9.94 | 1.08 | 0.52 | 0.48 | AM55-6 | 0.5 | 0.571 | 9.94 | 1.08 | 0.52 | 0.48 |
| AM73-1 | 70/30 | 0.7 | 0.420 | 17.14 | 2.02 | 0.67 | 0.33 | AM73-2 | 0.7 | 0.493 | 19.69 | 2.35 | 0.70 | 0.30 | AM73-3 | 0.7 | 0.537 | 16.53 | 1.94 | 0.66 | 0.34 | AM73-4 | 0.7 | 0.615 | 16.09 | 1.88 | 0.65 | 0.35 |
| AM91-1 | 90/10 | 0.9 | 0.287 | 40.78 | 5.10 | 0.84 | 0.16 | AM91-2 | 0.9 | 0.394 | 38.20 | 4.77 | 0.83 | 0.17 | AM91-3 | 0.9 | 0.569 | 39.23 | 4.9 | 0.83 | 0.17 | AM91-4 | 0.9 | 0.608 | 38.51 | 4.81 | 0.83 | 0.17 |
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