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International Journal of Polymer Science
Volume 2017, Article ID 3920524, 12 pages
Research Article

Study of Na-Montmorillonite–Polyamide Fiber/Polypropylene Hybrid Composite Prepared by Reactive Melt Mixing

1Unit of Emergent Research Materials, Ferhat Abbas Sétif 1 University, Setif, Algeria
2Materials Science and Engineering-Metallurgy Department, Jean Lamour Institute, UMR 7198 CNRS, University of Lorraine, Nancy, France

Correspondence should be addressed to Samia Kerakra; moc.liamg@arkarekaimas

Received 23 May 2017; Revised 28 August 2017; Accepted 25 September 2017; Published 30 October 2017

Academic Editor: Cornelia Vasile

Copyright © 2017 Samia Kerakra et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Hybrid composites of polypropylene (PP)/sodium montmorillonite (Na-MMT)/short polyamide fibers (PAfs) were prepared by reactive melt mixing in a Brabender plastograph. To enhance filler interactions within polypropylene, a functionalizing agent (FA) and a coupling agent were added to the Na-MMT and PAfs, respectively. An organic peroxide/sulfur mixture and tetramethylthiuram disulfide as an activator for sulfur were used to functionalize Na-MMT; on the other hand, the PAfs surface was treated using stearic acid. The aim of this study is to investigate how the morphology and the structural properties of 3, 5, and 7 wt% recycled functionalized sodium montmorillonite nanocomposites (f-Na-MMT) are affected by the presence of 5 wt% treated short polyamide fibers (t-PAfs). According to the obtained results, 5 wt% recycled f-Na-MMT/5 wt% t-PAfs/PP hybrid composite showed Na-MMT layers exfoliation. The nucleating effect of f-Na-MMT and t-PAfs was indicated by the differential scanning calorimetry (DSC) measurements. Morphological analysis of the hybrid composites was performed using scanning electron microscope (SEM) and optical polarized microscopy (POM), showing a good dispersion of the fibers with an interesting interfacial adhesion between the PP and t-PAfs phases. Hybrid composites of PP/f-Na-MMT/t-PAfs are considered for automotive industry.