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International Journal of Polymer Science
Volume 2017, Article ID 9051914, 11 pages
Research Article

The Influence of Nanohydroxyapatite on the Thermal, Mechanical, and Tribological Properties of Polyoxymethylene Nanocomposites

1Department of Biomaterials, Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, Poland
2Polymer Institute, Technical University of Lodz, ul. Zwirki 36, 90-924 Łódź, Poland
3Institute of Materials Science, Faculty of Computer Science and Materials Science, University of Silesia, ul. 75 Pułku Piechoty 1A, 41-500 Chorzów, Poland

Correspondence should be addressed to Kinga Pielichowska; lp.ude.hga@eipagnik

Received 5 March 2017; Revised 25 April 2017; Accepted 15 May 2017; Published 15 June 2017

Academic Editor: Hossein Roghani-Mamaqani

Copyright © 2017 Kinga Pielichowska et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The influence of nanohydroxyapatite on the glass transition region and its activation energy, as well as on the tribological and mechanical properties of polyoxymethylene nanocomposites, was investigated using DMA, TOPEM DSC, nanoindentation, and nondestructive ultrasonic methods. It was found that the glass transition for unmodified POM was in the lower temperature range than in POM/HAp nanocomposites. Moreover, and activation energy were larger for POM/HAp nanocomposites. Friction coefficient was higher for POM/HAp nanocomposites in comparison to both POM homopolymer and POM copolymer. Simultaneously, the indentation test results show that microhardness is also higher for POM/HAp nanocomposites than for POM. From ultrasonic investigations it was found that the highest values of both longitudinal and transverse propagation waves and Young’s and shear modulus for POM homopolymer (DH) and POM copolymer T2H and their nanocomposites can be attributed to their higher degree of crystallinity in comparison to UH copolymer. Moreover, for POM/HAp nanocomposites with 5% of HAp, ultrasonic longitudinal wave velocity was almost constant even after 1000000 mechanical loading cycles, evidencing an enhancement of mechanical properties by HAp nanoparticles.