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International Journal of Polymer Science
Volume 2017 (2017), Article ID 9721934, 11 pages
Research Article

Use of TBzTD as Noncarcinogenic Accelerator for ENR/SiO2 Nanocomposites: Cured Characteristics, Mechanical Properties, Thermal Behaviors, and Oil Resistance

1Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand
2MTEC, National Science and Technology Development Agency (NSTDA), Thailand Science Park, Khlong Luang, Pathum Thani 12120, Thailand

Correspondence should be addressed to Anyaporn Boonmahitthisud;

Received 6 April 2017; Accepted 7 June 2017; Published 31 July 2017

Academic Editor: Domenico Acierno

Copyright © 2017 Laksamon Raksaksri et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


This study reported the use of tetrabenzylthiuram disulphide (TBzTD) as a noncarcinogenic accelerator in a traditional sulfur curing system of epoxidized natural rubber (ENR)/nanosilica (nSiO2) composites. ENR used in this work was synthesized via in situ epoxidation of natural rubber (NR) in the presence of performic acid generated from the reaction of formic acid and hydrogen peroxide at 50°C for 8 h to acquire the epoxide content of about 40 mol%. Accordingly, the resulting ENR was referred to as ENR 40. The curing characteristics, mechanical properties, thermal behaviors, dynamic mechanical properties, and oil resistance of ENR 40/nSiO2 nanocomposites filled with three loadings of nSiO2 (1, 2, and 3 parts per hundred parts of rubber) were investigated and compared with NR and neat ENR 40. The results revealed that the scorch and cure times of ENR 40/nSiO2 nanocomposites were slightly longer than those of NR but slightly shorter than those of ENR 40. The tensile properties and tear strength for both before and after aging of all ENR 40/nSiO2 nanocomposites were higher than those of ENR 40, while the glass transition temperature, storage modulus at −65°C, thermal stability, and oil resistance of ENR 40/nSiO2 nanocomposites were higher than those of NR and ENR 40.