Research Article

New 1,2,3-Triazole Containing Polyesters via Click Step-Growth Polymerization and Nanoparticles Made of Them

Table 7

The influence of the catalyst and ligand’s nature on the characteristics of PE8E4.

Catalyst/ligand Yield (%) (g/mol) (g/mol) (dL/g)

CuI/TEA
CuI/DBU
CuI/DIPEA
CuI/PMDTA
CuBr/TEA
CuBr/DBU
CuBr/DIPEA
CuBr/PMDTA
CuBr(PPhe3)3/TEA
CuBr(PPhe3)3/DBU
CuBr(PPhe3)3/DIPEA
CuBr(PPhe3)3/PMDTA

in 0.1 M LiBr/DMF versus PMMA standards at a flow rate of 1.0 mL/min and 35°C. in DMF at 25°C.