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International Journal of Polymer Science
Volume 2018, Article ID 7906747, 10 pages
Research Article

Temperature-Sensitive Poly(N-isopropylacrylamide)/Konjac Glucomannan/Graphene Oxide Composite Membranes with Improved Mechanical Property, Swelling Capability, and Degradability

1School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China
2State Key Laboratory Cultivation Base for Nonmetal Composites and Functional Materials, Southwest University of Science and Technology, Mianyang 621010, China

Correspondence should be addressed to Juan Shen; moc.361@naujnehs-js and Bo Jin; moc.361@8240obnij

Received 7 November 2017; Revised 31 January 2018; Accepted 8 February 2018; Published 17 April 2018

Academic Editor: Hossein Sojoudi

Copyright © 2018 Guohong Zou et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Temperature-sensitive poly(N-isopropylacrylamide)/konjac glucomannan/graphene oxide (PNIPAM/KGM/GO) composite membranes were prepared by solution blending using calcium ions as a cross-linker. The composite membranes were characterized by Fourier-transform infrared spectroscopy (FT-IR), field-emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), Raman spectroscopy (Raman), and differential scanning calorimetry (DSC). The swelling, mechanical property, phase transformation behaviors, and enzymatic degradation activities were also determined. Results revealed that the phase transition temperatures of all the composite membranes were approximately 35°C. The PNIPAM/KGM/GO composite membranes showed enhanced mechanical property. The swelling behavior and enzymatic degradation of the PNIPAM/KGM/GO composite membranes improved compared with those of conventional PNIPAM hydrogel and PNIPAM/KGM composite membranes. Thus, the PNIPAM/KGM/GO composite membranes have potential applications in the biomedical field as skin dressings.