International Journal of Polymer Science

Research Article

Tailor-Made, Linear, and “Comb-Like” Polyester-Based Copolymers: Synthesis, Characterization, and Thermal Behavior of Potential 3D-Printing/Electrospinning Candidates

Table 2

Values of (min), , (min−1), and at different crystallization temperatures () for linear PCL, SCL#, and HEMACL# copolymers.
/°C
1618202224/kJ mol−1
PCL     −8.3
0.30.30.30.30.3
2.82.72.72.72.7
21.119.218.518.517.8
SCL1     −1.9
0.40.50.50.50.5
3.12.62.82.52.4
10.37.97.56.15.7
SCL2     −6.9
0.40.40.50.50.5
2.62.62.62.52.3
5.55.44.44.43.8
SCL3     −8.1
0.40.40.50.40.4
3.12.92.72.42.5
8.47.45.65.14.4
SCL4     −34.3
0.40.40.40.40.5
3.43.22.92.72.8
15.913.311.88.25.6
HEMACL1     −35.2
0.60.60.60.60.7
2.52.52.62.32.3
2.62.82.91.81.3
HEMACL2     −81.3
1.72.02.53.25.4
2.52.62.32.01.9
1.4 10−11.1 10−18.5 10−26.5 10−22.9 10−2
HEMACL3     −200.7
1.52. 34.67.912.6
1.92.01.81.81.8
3.2 10−11.4 10−15.3 10−22 10−29.5 10−3