Investigation of the Specific Retention Volume of the Probe Volume and the Effects on the Polymer-Probe System by Inverse Gas Chromatography
Table 3
The free energy of the sorption of the probe-CHMMA polymer system.
(K)
(J/mol)
353
363
373
383
0,3 μl
0,6 μl
0,9 μl
0,3 μl
0,6 μl
0,9 μl
0,3 μl
0,6 μl
0,9 μl
0,3 μl
0,6 μl
0,9 μl
Ethyl alcohol
9567,22
9428,98
9387,02
10153,8
10079,4
10024,8
10900
10868,6
10746,2
11815,7
11695,5
11523,3
1-Propyl alcohol
8082,18
8082,18
7906,6
8763,1
8763,1
8664,08
9363,99
9363,99
9208,87
10012,5
10012,5
9931,93
1-Butyl alcohol
6179,52
6005,13
5726,53
6859
6662,69
6591,61
7600,29
7519,61
7391,3
8261,65
8248,84
8466,25
1-Pentyl alcohol
3572,75
3358,75
3104,39
4270,5
4012,41
3899,16
5466,87
5277,07
5176,84
6389,67
6139,26
6045,86
n-Hexane
7658,05
7589,82
7547,86
8106,7
8088,86
8001,26
8608,71
8608,71
8608,71
9099,49
9099,49
9099,49
n-Heptane
7652,17
7458,12
7393,2
8209
8103,52
7864,01
8684,23
8650,65
8354,94
9172,73
9126,37
8905,13
n-Octane
6745,33
6662,62
6566,28
7255,65
7176,31
7031,84
7908,25
7687,66
7632,52
8361,86
8250,78
8067,48
n-Nonane
5439,67
5093,92
4871,63
5949,05
5878,3
5547,47
6582,47
6447,1
6310,72
7063,45
6980,1
6869,73
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