Research Article | Open Access
Preparation and Self-Repairing Properties of Urea Formaldehyde-Coated Epoxy Resin Microcapsules
Urea formaldehyde resin-coated epoxy resin microcapsules were prepared by two-step in situ polymerization. The effects of five factors on the yield, coverage rate, repair rate, and morphology of the microcapsules were investigated by five factors and four levels of orthogonal test. These five factors were the mass ratio of the core to the wall material (), the mass ratio of the emulsifier to the core material (), stirring rate, deposition time, and mass ratio of the emulsifier solution to the core material (). The ideal technological level of microcapsule synthesis was determined. According to the results of the range and variance of yield, coverage rate, and repair rate, the comprehensive properties of microcapsules became ideal. At this time, the was 0.8 : 1, was 1 : 100, stirring rate was 600 r/min, deposition time was 32 h, and was 8 : 1. When the concentration of microcapsules in the epoxy resin was 10.0%, the self-repair rate was the best and the repair rate was 114.77%. This study is expected to provide a reference value for the preparation of a microcapsule self-healing technology and lay a foundation for the subsequent development of self-healing materials.
A finishing process is an important means to adjust surface characteristics, but its process is complex, and it is easy to produce many fine defects in the process of finishing and subsequent production. In recent years, by imitating the self-repair function of the organism and the participation of external environmental factors, internal and external damage can be automatically repaired in the matrix material and the useful life of the material can be prolonged . Bolimowski et al. prepared microcapsules from commercially available epoxy resin and an organic solvent (ethyl phenylacetate (EPA)) for application to self-healing epoxides . The application of the self-repair technology of the microcapsule to a coating surface can avoid a complicated artificial repair when the coating surface is damaged and cracked, and thus, the life of the coating can be improved and the useful period is prolonged . A microencapsulation self-repairing technology has very broad application prospects in wood coatings , pigments, textile printing, and dyeing, as well as architectural, aerospace, and ship coatings . Through the microencapsulation technology, the anticorrosion, antifouling, heat insulation, and flame retardant functions of coatings were enhanced according to requirements and the application scope of the coating was broadened.
In the preparation of self-repair microcapsules, the selection of core and wall materials for a microcapsule system is particularly important. A microencapsulated self-repairing system mainly includes the dicyclopentadiene-Grubbs curing agent system, epoxy resin core microcapsule self-repairing system, isocyanate microcapsule self-repairing system, dry oil microcapsule self-repairing system, polar solvent core self-repairing system, siloxane self-repairing system, and silicone oil self-repairing system. However, it is still difficult for these self-repairing systems to be widely used in the field of coatings. Based on research results, the microcapsule preparation method selected was in situ polymerization, which is easy to control and easily realized . Microcapsules of the epoxy resin system have high hardness, good flexibility, good adhesion to metal and nonmetal, and good dimensional stability and are widely used in paint, adhesions, impregnation, and so on, which is very suitable for self-repair of coatings . However, the morphology of epoxy resin microcapsules is not easy to control and the coverage rate and repair rate are relatively low, which is not conducive for industrial production and application. Therefore, in this paper, the microcapsule of urea formaldehyde-coated epoxy resin (epoxy resin coated with urea formaldehyde) was selected as the research object. In situ polymerization was used to prepare the microcapsules, and the best technological parameters for the preparation of the self-repair microcapsule of the coatings were explored in order to establish a foundation for the application of the self-healing microcapsules in engineering.
Urea (: 60.06 g/mol, CAS no.: 57-13-6), triethanolamine (: 149.19 g/mol, CAS no.: 102-71-6), benzyl alcohol (: 108.13 g/mol, CAS no.: 100-51-6), sodium dodecyl benzene sulfonate (: 348.48 g/mol, CAS no.: 25155-30-0), citric acid monohydrate (: 210.14 g/mol, CAS no.: 5949-29-1), octanol (: 130.23 g/mol, CAS no.: 111-87-5), ethyl acetate (: 88.11 g/mol, CAS no.: 141-78-6), and anhydrous alcohol (: 46.07 g/mol, CAS no.: 64-17-5) were purchased from Xilong Chemical Co. Ltd., Guangzhou, China. Formaldehyde solution (formaldehyde content 37%, : 30.03 g/mol, CAS no.: 50-00-0) was purchased from Guangdong Guanghua Sci-Tech Co. Ltd., Shantou, China. Epoxy resin (: 375.86 g/mol, CAS no.: 61788-97-4) was purchased from Nantong Xingchen Synthetic Material Co. Ltd., Nantong, China.
Preparation of urea formaldehyde-coated epoxy resin microcapsules was composed of three processes : preparation of the urea formaldehyde prepolymer (the wall material), preparation of the epoxy resin emulsion (the core material), and microencapsulation .
2.2.1. Preparation of the Urea Formaldehyde Prepolymer
The mixture of urea and formaldehyde solution was added to the beaker at the mass ratio of 1.00 : 1.85. The mixture was mixed well, and the pH of the solution was slowly adjusted to 8.0–9.0 by adding triethanolamine. The mixture was continuously stirred for 1 h in a constant temperature water bath at 70°C, and the wall material solution was prepared and cooled at room temperature.
2.2.2. Preparation of Epoxy Resin Emulsion for Core Material
The epoxy resin and benzyl alcohol (as diluent) were added to the beaker to be mixed completely. The mass ratio of benzyl alcohol to epoxy resin was fixed at 0.15 : 1. Certain amounts of deionized water and sodium dodecyl benzene sulfonate (emulsifier) were placed in another beaker for the emulsifier solution. Then the diluted epoxy resin solution was poured into the emulsifier solution and mixed, and the beaker was put into the water bath. In the water bath, the temperature was adjusted to 60°C, then the agitator was set for 30 min, and the core material emulsion was obtained by dropping in octanol for defoaming.
2.2.3. Microencapsulation 
At a certain speed, the wall urea formaldehyde resin was slowly added to the core material and the citric acid monohydrate was added to adjust the solution pH to 2.5–3.0. Then the water bath was slowly heated to 70°C, and stirring continued for 3 h. The product was allowed to stand for 0–48 h, then washed with deionized water and anhydrous ethanol, and filtered. The remaining product was heated to 40°C for 48 h, and the white powder obtained was used for the microcapsules .
A L16 (45) orthogonal experiment with 5 factors and 4 levels was used to optimize the preparation of microcapsules. The 5 factors were the mass ratio of the core material to the wall material (Wcore : Wwall) (), mass ratio of the emulsifier to the core material () (), stirring rate (), deposition time (), and mass ratio of the emulsifier solution to the core material () (); four levels are shown in Table 1. According to the designed orthogonal experimental parameters, the samples obtained were samples 1–16 in Table 2. The detailed list of amounts of materials was shown in Table 3.
The amounts of 20.00 g urea and 50.00 g 37% formaldehyde solution were fixed for all samples, and 30.00 g of urea formaldehyde (the wall material) was obtained according to equation (1). The amounts of the other reagents in sample 1 were as follows: 18.00 g epoxy resin, 2.70 g benzyl alcohol, 143.82 g deionized water, and 0.18 g sodium dodecyl benzene sulfonate.
Epoxy resin (10.00 g) and 1.50 g benzyl alcohol were mixed until becoming smooth, then 0.53 g, 1.11 g, 1.76 g, or 2.50 g microcapsules were added to make 5.0%, 10.0%, 15.0%, and 20.0% microcapsule concentrations of the mixture, respectively, and then the mixture was poured into the standard polytetrafluoroethylene dye. After vacuum drying for defoaming, the mixture was cured at room temperature for 12 h and then dried at 40°C for 10 h and at 80°C for 2 h and the mixture was demolded as microcapsule specimens for the repair rate test.
The tensile strength of the material was analyzed by a microcomputer-controlled electronic universal testing machine, CMT6104, MTS Systems Corporation. The microstructure of the microcapsules was analyzed using a Quanta 200 environment scanning electron microscope (SEM), FEI Company, and L2800 Biomicroscope, Guangzhou Liss Optical Instrument Co. Ltd. The components of the microcapsules were analyzed using a Nicolet iS5 infrared spectrometer, Thermo Nicolet Corporation. The microcapsule powder was directly weighed after drying to test the yield of the microcapsules. Then 1.0 g microcapsules were put into a funnel and soaked in ethyl acetate, the ethyl acetate being replaced every 24 h. The residual was washed with deionized water after 72 h soaking in ethyl acetate and dried, and the material obtained was the wall material. The coverage rate was calculated by the following:
In formula (2), is the coverage rate of microcapsules (the content of the capsule core), is the initial mass of microcapsules, and is the quality of the residual wall material after soaking. The microcapsules were added to the epoxy resin to make the specimen, and the tensile test was used to characterize the repair rate. To prepare specimens to test the repair rate of microcapsules, 10.0 g epoxy resin and 1.50 g benzyl alcohol were mixed completely, then 1.20 g of the microcapsule powder was added, and two identical specimens, A and B, were prepared. The tensile tests were carried out at the tensile rate of 2 mm/min. Tensile tests for specimen A were carried out until the breaking force was obtained. The maximum breaking force of specimen A was the initial maximum fracture force. The maximum tensile force of specimen B was set to 70% of the initial maximum fracture force of specimen A; then specimen B was put into the oven at 80°C for 2 h. Then the tensile test for specimen B was carried out until the maximum fracture force was obtained, that is, the maximum fracture force after repair was obtained. The ratio of the maximum fracture force of specimen B to specimen A (formula (3)) was used to calculate the repair rate:
In formula (3), is the repair rate, is the maximum fracture force after repair, and is the initial maximum fracture force of the specimen. The calculation method of repair rates with 5.0%, 10.0%, 15.0%, and 20.0% microcapsule concentrations was the same as above, except that the quality of the microcapsules was different. All the experiments were repeated four times with an error of less than 5.0%.
3. Results and Discussions
3.1. Structure and Performance Characteristics of Microcapsules
The morphologies of A–P shown in Figure 1 correspond to microcapsules prepared by the orthogonal experiments (samples 1–16 in Table 2). Most of the samples in Figure 1 were successfully encapsulated. Samples 4, 7, 8, 12, and 14 were not encapsulated due to an improper mass ratio or high stirring rate, which was not conducive to form the microcapsules. Microcapsule samples 6 and 10 were better. The microcapsule surface of these two samples was slightly rough, and the particle size was more uniform. Thus, the urea formaldehyde-coated epoxy resin microcapsule  with a particle size of about 100 μm was successfully prepared.
SEM of the uncoated microcapsules and encapsulated intact microcapsules was performed, and samples 8 and 10 were photographed, as shown in Figure 2. The microcapsules of sample 10 were regular spheres with a rough surface and uniform size. Sample 8 exhibited irregular precipitation and an uneven surface. It can be seen that sample 10 has a good morphology and encapsulation and the preparation factors and levels of the sample 10 microcapsule can be used as reference criteria for optimization .
Figure 3 is the infrared spectrum of sample 6 and sample 10 microcapsules in the orthogonal experiment. The attribution of the peak is shown in Table 4. The absorption peaks were basically the same, indicating that the chemical components are the same. The ratios were 0.8 : 1 and 1.0 : 1 for sample 6 and sample 10, respectively. Figure 3 shows 3400 cm-1, 2970 cm-1, 1615 cm-1, and 1516 cm-1 stretching vibration absorption peaks of the N-H, C-H, C=O, and C-N bonds, respectively . The characteristic peaks that can be seen in microcapsule samples 6 and 10 indicate that a urea formaldehyde resin has been formed. The expansion vibrations of C-O in epoxy resin were 1249 cm-1 and 916 cm-1, respectively. It was found that the chemical structure of epoxy resin did not change and the epoxy resin was coated by urea formaldehyde resin .
3.2. Orthogonal Experimental Results
The yield, coverage rate, and repair rate of samples 1–16 in Table 2 were calculated as shown in Table 5. According to Table 5, the yield of sample 10 was the highest, reaching 40.82 g. The yield of sample 14 was the lowest, only 5.94 g. The coverage rate of sample 16 was the highest, reaching 85%, while the coverage rate of sample 14 was the lowest, only 25%. The repair rate of sample 5 was the highest, reaching 107.6%, and the repair rate of sample 14 was the lowest, only 68.72%. According to the above results, it can be concluded that the yield, coverage rate, and repair rate of sample 14 were the lowest. Sample 14 was not successfully encapsulated, with the surface morphology shown in Figure 1; therefore, the coverage rate and repair effect of sample 14 were poor. Samples 5, 10, and 16 had the highest repair rate, highest yield, and the highest coverage rate, respectively. However, the microscopic image in Figure 1 shows that although the coverage rate of sample 16 was high, the agglomeration rate was more serious, so it cannot be used only as a reference for the successful preparation of the microcapsules. In order to obtain the best preparation process parameters, the best microcapsule can be obtained by considering and combining the comprehensive information.
The yield of microcapsules is an important basis for judging whether microcapsules can be used in the industry. Using the smallest amount of materials to prepare more microcapsules is desirable. Therefore, the range analysis and remarkable analysis of the yield are very important. According to the yield calculation results of the orthogonal experimental microcapsules , Tables 6 and 7 show that the main sequence of the technological conditions affecting the urea formaldehyde-coated epoxy resin microcapsules was and the effect of the factors was remarkable. The effect of deposition time on the yield is more significant, which is probably due to the slow formation of the microcapsules during the deposition. The best condition for preparation of the urea formaldehyde-coated epoxy resin microcapsules was , that is, was 1 : 1, was 7 : 100, the stirring rate was 800 r/min, the deposition time was 32 h, and was 8 : 1.
The coverage rate of microcapsules is closely related to the content of the microcapsule core and the repair rate of microcapsules. The range analysis and remarkable analysis of the coverage rate were calculated as shown in Tables 8 and 9. According to the calculation of the repair rates of the orthogonal experiment, the main sequence of the coverage rate affecting the urea formaldehyde-coated epoxy resin microcapsules was . The mass ratio of the emulsifier solution to the core material has a great influence on the coverage rate, which may be due to the importance of proper emulsification to the high coverage rate. The optimum combination of the process conditions for preparing the urea formaldehyde-coated epoxy resin microcapsules was , that is 1 : 1, 1 : 100, stirring rate 400 r/min, the deposition time 32 h, and 8 : 1.
The repair rate of microcapsules is an indication of the repair power of microcapsules for epoxy resin. The higher the repair rate, the better the repair ability of microcapsules in materials. Therefore, range analysis and remarkable analysis of the repair rate are very important. According to the calculations of the repair rate of the orthogonal experimental microcapsules, the main sequence of the conditions affecting the repair rate of microcapsules was shown by Tables 10 and 11. The main sequence affecting the repair rate was . Factors , , , and were remarkable factors for the repair rate. The mass ratio of the core to wall material seriously affects the repair rate of microcapsules. When the mass of the core material is low, the repair rate is not good. However, if the mass of the core material is too high, the coverage rate may be reduced, which will also affect the repair rate. The optimum technological condition for preparing the urea formaldehyde-coated epoxy resin microcapsule was , which was 0.8 : 1, 3 : 100, stirring rate 600 r/min, the deposition time 32 h, and 8 : 1.
Figure 4 is a diagram of the effects of , , , , and on the yield, coverage rate, and repair rate of microcapsules. It can be seen clearly that factor A has the most significant effect on the repair rate . Factors and have significant effects on yield, and factor has the most significant effect on the coverage rate. According to the analysis and calculation of the yield, coverage rate, and repair rate of the microcapsules, the optimum combination of the preparation of urea formaldehyde-coated epoxy resin microcapsules was , , and . Because the optimum levels of factors and on the yield, coverage rate, and repair rate of microcapsules were the same, the level of was selected. Factor has a prominent effect on the repair rate; therefore, level was selected . Factor has a great effect on the coverage rate; therefore, level with the smallest was selected. The effect of on the coverage rate was more significant, so level was chosen. Therefore, a comprehensive analysis showed that the optimal parameters for preparing urea formaldehyde-coated epoxy resin microcapsules was , that is, 0.8 : 1, 1 : 100, stirring rate 600 r/min, the deposition time 32 h, and 8 : 1.
3.3. Self-Repairing Properties
Figure 5 is an SEM image of the optimized preparation of microcapsules. The microcapsules shown in Figure 5 were successfully coated with urea formaldehyde resin, forming urea formaldehyde-coated epoxy resin microcapsules with a uniform particle size distribution and rough shell. Compared with microcapsules 1–16 in the orthogonal experiment, the morphology of the microcapsules had very little superfluous sediment and few damaged microcapsules and the optimized microcapsules were improved.
The particle size of the microcapsules was measured using ImageJ software . The average particle size of the microcapsules was 109.414 μm, and the size distribution diagram of the microcapsules is shown as Figure 6. The size distribution of microcapsules was in the range of 60–190 μm, mainly in the 80–140 μm interval, indicating that the optimized microcapsules had a larger span in the particle size distribution but that the distribution of the microcapsules was relatively uniform.
Table 12 shows that the yield of microcapsules after optimization was 45.63 g and the coverage rate was 75%. The maximum tensile strength of the epoxy resin was 30.64 N/mm2, and the maximum tensile strength after repair with microcapsules was 34.59 N/mm2. The repair rate of the microcapsules was 113.04% after optimization. Compared with samples 1–16 in Table 2, the yield and repair rate of the optimized microcapsules were the highest of all the samples, indicating that the optimized microcapsules had a further improvement in the yield and repair rate. In addition, the coverage rate of the optimized microcapsule was 75%; although this was not the highest, it compared favorably with the best comprehensive performance of samples 6 and 10 microcapsules (78%) in the orthogonal experiment and the difference was only 3% less. Therefore, the comprehensive performance of the optimized microcapsule was better than that of the orthogonal experiment .
In order to further verify the effect of the different concentrations of microcapsules on self-repair properties, the optimized microcapsules were added to the epoxy resin at 5.0%, 10.0%, 15.0%, and 20.0%  and were shown in Figure 7. When the concentration of epoxy resin increased from 5.0% to 10.0%, the repair rate increased from 108.81% to 114.77%. When the concentration of epoxy resin increased from 10.0% to 20.0%, the repair rate decreased from 114.77% to 97.91%. With the increasing concentration of epoxy resin in microcapsules, the repair rate first increased and then decreased and the repair rate reached the maximum when the concentration of epoxy resin in microcapsules was 10.0%. Figure 8 shows SEM of the different concentrations of microcapsules added to the epoxy resin. At the concentration of 10%, microcapsules can be evenly dispersed in the whole epoxy resin (Figure 8(a)) and the ability to repair was excellent, while a concentration of microcapsules greater than 10% would lead to agglomeration of the microcapsules (Figure 8(b)), which reduced the tensile strength of the microcapsules in the epoxy resin . When the concentration of microcapsules was less than 10%, the repair rate of the specimen did not reach the highest value. Therefore, when the concentration of microcapsules was 10.0%, the best repair effect was achieved .
The surface morphology and chemical composition of microcapsules prepared by an orthogonal experiment were characterized by scanning electron microscopy and infrared spectroscopy. The results showed that microcapsules with a high coverage rate, high repair rate, and high yield were successfully prepared. Through the orthogonal experimental five factors and four levels, the morphology of the microcapsules and the range and remarkable analysis on the yield, the optimal repair rate and the coverage rate of microcapsules were elucidated. The optimum process parameters for preparing urea formaldehyde-coated epoxy resin microcapsules were obtained by A2B1C1D3E1. When was 0.8 : 1, 1 : 100, stirring rate 600 r/min, the deposition time 32 h, and 8 : 1, microcapsules with better morphology, a high encapsulation rate, higher repair rate, and higher yield were prepared. The effect of the addition of 5.0%, 10.0%, 15.0%, and 20.0% microcapsules on the repair properties was studied, which revealed that the optimum concentration of microcapsules was 10.0% and the repair rate reached 114.77%.
The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.
Conflicts of Interest
The authors declare no competing financial interest.
This project is supported by the Natural Science Foundation of Jiangsu Province (BK20150887), Youth Science and Technology Innovation Fund of Nanjing Forestry University (CX2016018), and Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
- J. H. Song, X. F. Cui, Z. Liu et al., “Advanced microcapsules for self-healing conversion coating on magnesium alloy in Ce(NO3)3 solution with microcapsules containing La(NO3)3,” Surface and Coatings Technology, vol. 307, pp. 500–505, 2016.
- P. A. Bolimowski, R. Kozera, and A. Boczkowska, “Poly(urea-formaldehyde) microcapsules - synthesis and influence of stirring speed on capsules size,” Polimery, vol. 63, no. 5, pp. 339–346, 2018.
- X. X. Yan, Y. T. Cai, R. Lu, and T. Miyakoshi, “Development and characterization of new coating material of blended epoxy-lacquer with aluminum,” International Journal of Polymer Science, vol. 2017, Article ID 5017356, 8 pages, 2017.
- T. Siva and S. Sathiyanarayanan, “Self healing coatings containing dual active agent loaded urea formaldehyde (UF) microcapsules,” Progress in Organic Coating, vol. 82, pp. 57–67, 2015.
- X. Y. Geng, W. Li, Y. Wang et al., “Reversible thermochromic microencapsulated phase change materials for thermal energy storage application in thermal protective clothing,” Applied Energy, vol. 217, pp. 281–294, 2018.
- X. Wang, T. Jin, H. W. Wang, S. Z. Liao, and H. Y. Yang, “Preparation and characterization of polysulfide sealant microcapsules based on in situ polymerization of urea and formaldehyde,” Chemical Journal of Chinese Universities-Chinese, vol. 39, no. 2, pp. 397–404, 2018.
- S. M. Wu, L. Yuan, A. J. Gu, Y. Zhang, and G. Z. Liang, “Synthesis and characterization of novel epoxy resins-filled microcapsules with organic/inorganic hybrid shell for the self-healing of high performance resins,” Polymers for Advanced Technologies, vol. 27, no. 12, pp. 1544–1556, 2016.
- F. H. Kong, W. C. Xu, X. L. Zhang, X. Wang, Y. Zhang, and J. L. Wu, “High-efficiency self-repairing anticorrosion coatings with controlled assembly microcapsules,” Journal of Materials Science, vol. 53, no. 18, pp. 12850–12859, 2018.
- Q. X. Zhou, L. Yang, J. Xu et al., “Evaluation of the physicochemical stability and digestibility of microencapsulated esterified astaxanthins using in vitro and in vivo models,” Food Chemistry, vol. 260, pp. 73–81, 2018.
- J. D. Hoyos-Leyva, L. A. Bello-Perez, and J. Alvarez-Ramirez, “Thermodynamic criteria analysis for the use of taro starch spherical aggregates as microencapsulant matrix,” Food Chemistry, vol. 259, pp. 175–180, 2018.
- S. J. Wang, Y. Shi, and L. P. Han, “Development and evaluation of microencapsulated peony seed oil prepared by spray drying: oxidative stability and its release behavior during in-vitro digestion,” Journal of Food Engineering, vol. 231, pp. 1–9, 2018.
- R. Ravanfar, T. A. Comunian, and A. Abbaspourrad, “Thermoresponsive, water-dispersible microcapsules with a lipid-polysaccharide shell to protect heat-sensitive colorants,” Food Hydrocolloids, vol. 81, pp. 419–428, 2018.
- Y. Niu, L. Qi, F. Zhang, and Y. Zhao, “Geometric screening of core/shell hydrogel microcapsules using a tapered microchannel with interdigitated electrodes,” Biosensors & Bioelectronics, vol. 112, pp. 162–169, 2018.
- M. Liu, Y. Wang, Y. Q. Wu, and H. Wan, “Hydrolysis and recycling of urea formaldehyde resin residues,” Journal of Hazardous Materials, vol. 355, pp. 96–103, 2018.
- H. A. Shnawa, M. N. Khalaf, and Y. Jahani, “Thermal degradation, dynamic mechanical and morphological properties of PVC stabilized with natural polyphenol-based epoxy resin,” Polymer Bulletin, vol. 75, no. 8, pp. 3473–3498, 2018.
- X. Yan, X. Qian, R. Lu, and T. Miyakoshi, “Synergistic effect of addition of fillers on properties of interior waterborne UV-curing wood coatings,” Coatings, vol. 8, no. 1, p. 9, 2018.
- J. S. Baek, J. K. Tee, Y. Y. Pang et al., “Improved bioavailability of levodopa using floatable spray-coated microcapsules for the management of Parkinson's disease,” NeuroMolecular Medicine, vol. 20, no. 2, pp. 262–270, 2018.
- A. Mooranian, R. Negrulj, R. Takechi, J. Mamo, H. Al-Sallami, and H. Al-Salami, “The biological effects of the hypolipidaemic drug probucol microcapsules fed daily for 4 weeks, to an insulin-resistant mouse model: potential hypoglycaemic and anti-inflammatory effects,” Drug Delivery and Translational Research, vol. 8, no. 3, pp. 543–551, 2018.
- R. Wurth, P. Foerst, and U. Kulozik, “Effects of skim milk concentrate dry matter and spray drying air temperature on formation of capsules with varying particle size and the survival microbial cultures in a microcapsule matrix,” Drying Technology, vol. 36, no. 1, pp. 93–99, 2018.
- J. G. Wang, X. Li, M. Chen et al., “Fabrication of sustained-release and antibacterial citronella oil-loaded composite microcapsules based on Pickering emulsion templates,” Journal of Applied Polymer Science, vol. 135, no. 25, p. 46386, 2018.
- Y. K. Song, B. Kim, T. H. Lee et al., “Monitoring fluorescence colors to separately identify cracks and healed cracks in microcapsule-containing self-healing coating,” Sensors and Actuators B: Chemical, vol. 257, pp. 1001–1008, 2018.
- F. Safaei, S. N. Khorasani, H. Rahnama, R. E. Neisiany, and M. S. Koochaki, “Single microcapsules containing epoxy healing agent used for development in the fabrication of cost efficient self-healing epoxy coating,” Progress in Organic Coating, vol. 114, pp. 40–46, 2018.
- S. Sharma and V. Choudhary, “Parametric study for epoxy loaded PMMA microcapsules using Taguchi and ANOVA methods,” Express Polymer Letters, vol. 11, no. 12, pp. 1023–1036, 2017.
Copyright © 2019 Xiaoxing Yan et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.