International Journal of Polymer Science

International Journal of Polymer Science / 2020 / Article

Research Article | Open Access

Volume 2020 |Article ID 8858138 | https://doi.org/10.1155/2020/8858138

A. F. Al Naim, J. Mazher, S. S. Ibrahim, "Morphological and Thermal Properties of Poly(Vinyl Alcohol)/Layered Double Hydroxide Hybrid Nanocomposite Fibers", International Journal of Polymer Science, vol. 2020, Article ID 8858138, 14 pages, 2020. https://doi.org/10.1155/2020/8858138

Morphological and Thermal Properties of Poly(Vinyl Alcohol)/Layered Double Hydroxide Hybrid Nanocomposite Fibers

Academic Editor: Wen Shyang Chow
Received08 Aug 2020
Revised04 Oct 2020
Accepted21 Oct 2020
Published05 Nov 2020

Abstract

Nanolayered particulate of Zn-based layered double hydroxide (LDH) was prepared by a low temperature greener sol-gel method. X-ray diffraction (XRD) studies were performed on the particles annealed at different temperatures. Hexagonal crystal structure of the as-grown LDH particulates was observed. The crystal structure was modified to tetragonal structure of layered double oxide (LDO) on annealing at 250°C. Rietveld fittings showed a collapse of interlayer separation distance along the preferred orientation of the LDH particles as a result of heat treatment. Further, LDH particles were used as fillers of electrospun poly(vinyl alcohol) (PVA) fibers. Heat treatment of the polymer fibers was also performed at different temperatures, and thermal changes were studied by thermogravimetric analysis (TGA), Raman spectroscopy, and scanning electron microscopy (SEM) techniques. Improved interaction of fibers with LDH nanoparticles was observed and ascribed to LDH-related LDO phase transformation at higher temperature. Thermal mechanisms of the rapid weight loss in filled fibers were discussed in comparison to the pure PVA fiber losses. Experimental Raman frequencies of the composite fibers were compared with the calculated Raman modes of the enol and ZnO monomers. The molecular vibration frequencies were found to differ significantly due to heat treatment. Finally, the role filler in the faster and greener thermal decomposition of polymeric fibers was also discussed in the present work.

1. Introduction

Layered double hydroxides (LDHs) have recently been under intensive investigation, largely owing to the potential applications of LDH films in enhancing the hydrophobic nature of, for example, surfaces, biomaterial and chemical sensors, photodegradation, photocatalysis, and fuel cells [14]. The layered nature of LDH arises from the extra cationic nature of its crystalline layers, which is balanced by anionic species present in between the two positive layers [5]. The LDH structure can be compared to the hexagonal structure of anionic clays [6]. Thus, LDH materials can demonstrate a variety of physiochemical properties depending on the type of sandwiched anions [5, 7]. Poly(vinyl alcohol) (PVA) is a common, nontoxic, biofriendly polymer with enormous applications in biomedical implants arising from its chemoresistance, high water solubility, biocompatibility, and low protein absorption [8]. Poly(vinyl alcohol) is also an excellent embedding medium for a variety of fillers, such as silver nanoparticles, oxide nanoparticles, and clays, providing antibacterial, photocatalytic, and mechanical strength to the polymer composites [9]. Understandably, PVA embedding also helps in lowering the toxicity of nanomaterials and highly reactive fillers. Novel chemical and physical traits can be observed in the polymer composites of PVA with LDH fillers, and this has interesting applications in the fields of thermal management, biosensors, medical implants, gas detection, and photocatalysis [811]. Furthermore, the annealing of PVA-based hybrid composites is equally as helpful in the fundamental studies of the antifatigue, thermal stability, and antifracture traits of polymers as in extensive applications in soft robotics and hydrogel-based soft machines [12].

The sol-gel method of synthesis that involves moderate temperatures of synthesis with respect to the solid-state growth routes and lack of harmful toxic solvents during the synthesis process is generally known as the green sol-gel method [13]. We were interested in deploying this green sol-gel synthesis by adopting a room-temperature growth process and employing only common, nontoxic solvents in our environmentally friendly process of preparation of ZnO-LDH powders. The novel green methods of synthesis are highly important, as exposure to harmful solvents can be dangerous and create long-term human health issues, such as respiratory and thyroid syndromes, as well as polluting the soil and atmosphere [14].

Layered double oxide (LDO) can be formed by calcining the parent LDH compound [15]. A variety of interesting traits are exhibited by the LDO material, such as an increase in the surface area [16], binder-induced tuning of the angle between super hydrophilic and hydrophobic contacts [16], and higher photocatalysis for faster photodegradation of dyes [17]. Moreover, battery electrodes prepared from Zn-LDO have been reported to show larger discharge capacity, reversibility, and layer cycle lifetime [18]. In addition, Zn-LDO-incorporated LDH materials have recently been deployed to sense acetone, which is an important diabetic biomarker in human plasma [19]. However, in the contemporary literature, the calcination of Zn-based LDH compounds has only been reported to convert into hexagonal Zn-LDO layers, albeit at high calcination temperatures of ~600°C [15, 17]. Furthermore, quite often in the literature, nongreen synthesis routes have been selected to prepare the ZnO-based LDH compounds using higher synthesis-chamber temperatures, higher chamber pressures, and higher annealing-furnace temperatures [18]. To the best of our knowledge, a green sol-gel route for Zn-based LDH preparation and their PVA composites have not been reported before in the available literature. Electrospun fibers of a blend of LDH nanofiller with polymers are of considerable scientific interest owing to myriad of applications in bioengineering, drug molecule delivery, diagnosis, and biomimetics, thermal management, energy, and catalysis [20, 21]. The successful and homogeneous formation of the composite material largely depends upon the extent to which the PVA chains are intercalated in the double-layered material [10]. Clay–polymer composites are already popular, due to successful composite formation, and are deployed in large-scale industrial applications ranging from synthetic fabrics to automobiles, replacing conventional plastics [11]. One of the potential applications of the nanofiller blending in polymers arises in the realization of greener electronics in which low temperatures are required for thermal decomposition of the electronic components [22, 23]. In this report, we present our results for the synthesis of Zn-based LDH clay and the effects of annealing on the structural properties of LDH. Thermogravimetric analysis (TGA) and Raman analysis of the composite PVA fibers containing LDH fillers were performed with respect to annealing temperatures.

2. Materials and Methods

2.1. Synthesis of Zn-LDH and Nanocomposite Fibers

Zinc acetate, of 99.98% purity and purchased from Sigma-Aldrich, USA, was dissolved in ethanol and acetylacetone in a 0.05 : 1 : 0.005 molar ratio and stirred for 1 h at 40°C. A solution of 1 M ethanol–NaOH, of 99.7% purity and purchased from Sigma-Aldrich, USA, was added to the solution until a constant pH value of ~8 was obtained. A thick LDH gel was formed, which, on drying at 75°C for 2 days, converted into a white clay-type solid. This LDH clay was powdered using a pestle and mortar and mixed with PVA, of 99.9% purity and purchased from Sigma-Aldrich, USA, in a weight ratio of 1 g in the 25 ml in water. The PVA/LDH melt was drawn and solidified into fibers using a Nanofiber Electrospinning Unit (Kato Tech, Japan). Electrospinning was performed at a fixed needle-cylinder distance of ~9.5 cm, a rotational speed of ~3.6 rpm, and a voltage of ~23 kV. Fibers were dried at 75°C for 2 days. Overall, seven samples of LDH and hybrid nanocomposite fibers were prepared, and their treatment details are shown in Table 1.


Serial numberSample nameMaterial preparedGrowth temperatureHeat treatment temperature

1.LDH75ZnO-layered double hydroxide20°C75°C
2.LDH250 or LDOZnO-layered double oxide20°C250°C
3.PF75Electrospun PVA fiber25°C75°C
4.PF250Electrospun PVA fiber25°C250°C
5.CF250Hybrid composite fiber of PVA-filled ZnO-layered double oxides25°C250°C
6.CF150Hybrid composite fiber of PVA-filled ZnO-layered double oxides25°C150°C
7.CF75Hybrid composite fiber of PVA-filled ZnO-layered double oxides25°C75°C

2.2. Materials Characterization and Simulation

A field emission scanning electron microscope (JSM-7500; Jeol) was used for imaging the samples in high-resolution mode with 100,000x magnification, and a powder X-ray diffractometer (Ultima IV; Rigaku, Japan) was used for X-ray diffraction (XRD) analysis of the LDH powders. Phase analysis and (hkl) plane indexing of the LDH powders were performed using the FullProf Rietveld analysis software [20]. An X-ray photoelectron spectrometer (ESCA-II; Omicron) was utilized to perform chemical shift analysis of the LDH powders. Carbon 1s (sp3) edge was used to calibrate edge energy at 0.05 eV resolution. A TA Instruments-Q500 analyzer was employed for the TGA of LDH-PVA fibers at a 10°C/min ramp in an N2 environment. Raman spectra of fibers were collected using a confocal microscopic spectrometer (LabRAM-HR; Horiba) with a laser excitation line of wavelength 632.8 nm. A 50x objective was used with an ~50% numerical density filter on samples, and Raman signals were scanned using a 1800-line/mm grating for the Si detector. The molecular vibrations of the hexagonal-phase ZnO and the enol monomer of PVA were calculated by the reduced Hartree–Fock (RHF) method implemented in the ORCA software version 4.0 [24].

3. Results and Discussion

3.1. Morphological and Structural Studies of Zn-LDH Nanoparticles

The LDH powder samples were morphologically, structurally, and compositionally characterized using scanning electron microscopy, XRD, and X-ray photoelectron spectrometry (XPS) techniques, respectively. Figure 1(a) shows an electron microscope image of dried powder from the LDH75 sample. The layered nature of this pure LDH sample is apparent from the visible platelets. The high-resolution image (×100 k magnification) of the pure LDH in Figure 1(b) clearly manifests strata-type structures comprising of vertically upright plates. Similarly, the platelets and the layered nature of the oxide are observed in the LDO sample in Figure 1(c). However, the LDO morphology is more compacted, resulting from changes in the interlayer separation and subsequent crumpling of the layers upon heating. In some regions, very large layers of the LDO structures with dimensions of ~1–5 μm are also visible, as shown in Figure 1(d). The presence of such large layer structures indicates that the very fine LDO platelets have lumped together into larger agglomerations of clusters during heat treatment of LDH, showing the higher inter- and intralayer interactions among the double layers.

The experimental XRD spectrum of the pure Zn-LDH sample (LDH75) is shown in Figure 2(a), along with the structural refinement data. Rietveld fitting [25] of the XRD profile shows the hexagonal (P6) symmetry of the pure LDH powders, as also described by the red curve fit in Figure 2(b). The Miller planes of the major reflection peaks were (003), (118), (220), (416), (0019), and (603), confirming the hexagonal structure of the LDH layers. The cell constants determined from the structural analysis were as follows: a(8.2934), b(8.2934), c(23.5089), α(90°), β(90°), and γ(120°). The hexagonal (brucite) structure of Zn-based LDH clays has also been reported in the literature [26]. Owing to the strongest peak intensity of (003) XRD reflection positioned at the smallest 2θ value of ~11.5°, we expect that the preferred orientation of the as-formed LDH powder was along the (003) plane’s direction. Clearly, the interplanar separation distance along the (003) plane was large enough ( value ≈1.1 nm) to allow the process of molecular intercalation. Notably, the annealed LDH sample or the LDO sample, showed a lack of certain X-ray reflections, and the most intense reflection, indexed as (003), disappeared on annealing. The change in reflections indicates a possible phase transformation, which was subsequently confirmed by the Rietveld profile fitting. The LDO’s XRD spectrum, as shown in Figure 2(b), also fitted well with the tetragonal symmetry (P4) pattern. The (hkl) planes of the major X-ray peaks obtained from the structural analysis for LDO250 were (305), (330), (0010), (602), (3115), and (4214). The cell constants determined from the structural analysis were a(8.8089), b(8.8089), c(20.7169), α(90°), β(90°), and γ(90°). However, the LDO layers were also clearly characterized by large interlayer separation along the c-vector. Therefore, the LDO layers were equally suitable for the exfoliation and intercalation of polymer chains.

Only two binding energy peaks related to O and Zn atoms were observed in the XPS data analysis. High-resolution XPS spectra corresponding to LDH75 and LDO samples are shown in Figure 3 for O1s and Zn2p electronic binding energies. Figures 3(a) and 3(b) represent O1s, and Figures 3(c) and 3(d) represent zinc (2p) binding energies before and after the annealing of LDH samples, respectively. The O1s peak had binding energy contributions from oxygen atoms present in the lattice layers (native-O) as well as from uncoordinated hydroxide (OH) groups present in out-of-lattice configurations. The native-O1s peak had lower binding energy because oxygen accepted electrons from electropositive Zn during metal-oxide formation. In contrast, the hydroxide peak was shifted towards a comparatively higher binding energy ( eV) owing to electron sharing with the H atom of the OH group. The shift between the two different O atoms was small and usually smeared, even in the high-resolution spectrum, due to instrumental broadening. However, deconvulation of the O1s peak for sample LDH75 revealed the positions of the two peaks at 530.3 eV and 532.1 eV. Similarly, for sample LDO, the native-O and hydroxide peaks were positioned at 530.3 eV and 532.3 eV. The percentage of O atoms in native-O and uncoordinated hydroxide positions can be calculated by taking area ratios of the two peaks. For the LDH75 sample, the percentage of O atom occupancy in native-O positions was 67%, while for hydroxide positions, the occupancy was only 33%. Thus, the majority of O atoms were coordinated in the anionic lattice layers of the LDH. The native-O occupancy of O atoms increased to 74.5% in the annealed sample, LDO250; however, the hydroxide occupancy decreased to 25% in the sample, owing to some dehydration taking place during annealing. The 2p XPS spectrum of Zn atoms showed a very large spin-orbit splitting gap (~23 eV), and high-resolution binding energies were recorded only for 2p3/2 electronic spins, as shown in Figures 3(c) and 3(d). We observed no change in the binding energy nor in the shape of Zn2p3/2peaks, found to be centered at 1022 eV, with respect to annealing temperature. Therefore, all the Zn atoms were fully coordinated in the cationic lattice of the layers of LDH material.

The XPS measurements also provided useful information about the Zn-rich or O-rich stoichiometry of the LDH samples. Using the atomic sensitivity factors adopted by Xu et al. [27] (4.8 for Zn and 0.66 for O), we can find the atomic percentage ratio of Zn and O atoms in an LDH sample. The XPS results showed that the atomic ratio O/Zn was 3.15. The LDH samples prepared in the current work were O rich and Zn deficient. The Zn deficiency in the LDH is expected, due to the presence of anionic O in between the double layers of LDH and LDO materials. Moreover, the Zn/O ratio remained almost similar in both the LDH75 sample and the air-annealed LDO sample (~3.42), indicating the stability of the anionic species with respect to the thermal degradation. An excess of O atoms is also naturally expected in the typical layered double compounds, owing to the large interlayer separation and presence of anionic species, such as OH- and CO3-, as well as H2O in between layers.

3.2. Morphological and Thermal Studies of PVA/LDH Fibers

Scanning electron microscopy images of the pure-fiber sample (PF75) and annealed composite fibers (CF250) are shown in Figure 4. As-prepared and 75°C-dried fibers, both with and without LDH fillers, displayed straight and rigid morphology with a uniform diameter of roughly ~100 nm as can be seen from Figure 4(a). Further, the diameters of the fibers remain fairly constant across their length confirming the diametric uniformity of the fibers. Using the high-resolution image, Figure 4(d) of PVA/LDH fibers, the average number of particles/μm2 is counted and the typical surface particle density of the nanofillers in fibers is ~1.4/μm2. Thus, the electrospinning process of the blended fibers yields both diametrically uniform fibers and a high particle density in the fibers. Moreover, Figure 1(d) is also used to calculate the average particle size of the filler distribution in the PVA/LDH composite fiber, as shown in Figure 4(e). It is found that the dispersion of the LDH nanofillers has an average particle size of  nm indicating the presence of nearly monodispersive nanostructures in the blended fibers. In the scanning electron microscope image, dehydrated LDH-filled fibers, annealed at 250°C, can be seen acquiring intertwined structures. It is possible that during annealing, thermal stress and PVA decomposition were responsible for the degradation of the fiber mesh network. However, both the fibrous nature and diameter uniformity remained preserved even after annealing.

The TGA curve of pure PVA fibers (PF75) shows two characteristic weight loss regimes of PVA related to its dehydroxylation and subsequent organic material blazing (Figure 5). The initial loss starting from 200°C corresponds mainly to a decrease in the alcohol content of the fibers and the loss of the hydroxyl (OH) groups, whilst the second mass loss starting from 300°C corresponds mainly to the complete carbonization of the PVA. For the sample PF75, the temperatures of the dehydroxylation and blazing peak positions are correspondingly marked by second-derivative peaks at 320°C and 440°C, as shown in Figure 5(a). We have found that the dehydroxylation peak position reduced to 300°C in the LDH-filled fibers (CF75), as shown in Figure 5(b). Similarly, a simultaneous early blazing temperature was also observed in the LDH-filled fibers, and this was reduced by ~20°C. Therefore, rapid and early TGA losses were observed in the LDO-filled fibers. The concurrent reduction of both of the loss peaks also indicates a type of localized sample heating in the filled PVA fibers.

The rapid loss in the filled fibers’ weight is depicted by the schematic model in Figure 6, which indicates a possible mechanism of sample heating. Using the model, one can explain the causes of the uniform lowering of the two TGA signature peaks. The schematic is divided into five steps: (i) intercalation of PVA chains in the LDH layers; (ii) melt formation of PVA and ZnO-LDF hybrid composite; (iii) drawing and solidification of the polymer melt into fibers; (iv) heat treatment of fibers and LDH-to-LDO transformation at 250°C; and (v) further heating of samples, exhibiting rapid weight loss. During steps (i)–(iii), the model first predicts the intercalation of PVA chains in the layers of LDHs, leading to the formation of rapid heating zones. On further increase in temperature, the LDH clusters present in CF75 fibers are expected to transform into LDO clusters at ~250°C. During the sample heating, the LDO oxide clusters can act as hot centers, owing to their higher thermal conductivity in comparison with that of the alcohols. The process of LDO formation in the fibers is accomplished in step (iv), and, on further increasing the temperature to >250°C, a thermal gradient between PVA and LDO guides hot centers to move towards the fiber surface. Once the migration of hot centers towards the surface of fibers has occurred, as shown in step (v), the fiber surface becomes more volatile, further contributing to rapid dehydroxylation and loss of organic fibrous content. Thus, the model adequately explains the rapid thermal losses in the PVA/LDO fibers. Alternatively, in the literature, a decrease in the intrinsic viscosities of the polymers has been ascribed to the thermal instability and degradation of polyethylene fibers [28]. Certainly, the lower loading fraction of oxide particles in the fiber, the higher surface area of fibers, and filler–matrix interactions are some important parameters to fundamentally explore observed thermal instability and rapid weight loss in hybrid composite fibers. Thus, a rapid thermal degradation at low temperatures is observed as a result of the LDH nanofiller blending, and that may be useful in the greener thermal decomposition of polymer products.

3.3. Vibrational Studies of PVA/LDH Fibers

The molecular vibration frequencies of four-atom cells of hexagonal zinc oxide and the enol monomer were calculated after the optimization of their full geometric structure. The calculated frequencies and force vector plots of the corresponding vibrations are presented in Table 2.


Calculated vibrational frequencies (in cm-1) for ZnO (4-atom unit cell)Force vector plotCalculated vibrational frequencies (in cm-1) for enol monomer of PVAForce vector plot

157
O-Zn(2)-O wag
473
H-CH twist
408
Zn-O(1)-Zn symmetrical stretch
572
H-CH rock
681
O-Zn(2)-O asymmetrical stretch
952
H-CH wag
736
Zn-O(1)-Zn asymmetrical stretch
1236
H-CO asymmetrical stretch
1444
H-CO bend
1558
H-CH bend

Zn-O vibrations comprised mainly of wagging, symmetrical, and asymmetrical stretching modes at comparatively lower frequencies (<800 cm-1), whilst the enol monomer vibrations were found to mainly show twisting, rocking, wagging, bending, and stretching modes of CH2 along with CO bending and stretching modes. In the absence of centrosymmetry, the selection rules permit observance of all vibrations in the Raman spectra. However, due to atomic displacement and rearrangement, the bulk vibration frequencies are expected to show some frequency shifts in comparison with related molecular modes.

Taking into account the fact that the crystal structure of ZnO-LDH changes on annealing, the Raman studies were performed to optically explore the structural changes of PVA-filled ZnO-LDH hybrid composite fibers taken after annealing at 75°C, 150°C, and 250°C. The Raman spectra recorded for the three fiber samples CF75, CF150, and CF250 are shown in Figure 7. The characteristic vibrational peak for zinc oxide is a Zn-O-Zn symmetrical stretching mode, which is found in all samples, and its position in the graph is marked by a straight line, at 434 cm-1. Notably, the characteristic peak intensifies with the heat treatment, indicating strengthening of the oxide phase of ZnO-LDH system, which is in agreement with our XRD results. Concurrently, the bond softening was also evident in the form of the ~15-cm-1 shift of the characteristic peak towards higher energies. Such bond softening is indicative of either the formation of a new phase, which was in fact proved previously in our XRD studies, or the decay in the existing crystalline order. Thus, the Raman results provided supportive structural information on the ZnO-LDO phase. Similarly, the characteristic vibration of enol, HC-OH stretching mode, was found present in all the annealed samples and is marked by a straight line at 1444 cm-1 in the Raman plot. The presence of enol modes of PVA shows the robust PVA fiber structure with respect to heating without any dehydroxylation of alcohol.

4. Conclusions

Greener low temperature sol-gel method was used for the synthesis of the Zn-based LDH powders at lower synthesis temperature. Hexagonal structural phase of as-grown LDH particulates dried at 75°C was observed. A structural modification of tetragonal phase transformation was found in the furnace dried particulates at ≈250°C. The morphological changes of LDH powders upon heating were also studied by electron microscopy. Interestingly, the platelet- (layered) type as-grown LDH particulates change their shape into the faceted particulates, of size ≈45 nm, on heating further corroborating the phase transformation. In addition, the XPS spectra of modified LDH showed a steep rise in the native-O coordination (up to 74%) in LDH conforming the phase transformation.

The PVA/Zn-LDH-filled nanocomposite fibers were prepared by electrospinning process. The composite fiber samples showed straight and elongated morphology of fibers of intertwined nature along with fiber diameter uniformity. Thermal characteristics of the fibers were studied at up to 250°C heating. Nonuniform in the TGA losses of fibers was explained using a novel interaction mechanism between modified LDH and PVA fibers. Properties of the fibers were also examined by Raman spectroscopy and electron microscopy. Theoretical calculations of the characteristic vibrations of zinc oxide and the enol monomer constituents of the PVA fiber were performed. The characteristic vibrations of ZnO and PVA in the fiber showed no change in position and shape with heat treatment indicating the weak dehydroxylation of PVA. However, dehydration effects on fibers were clearly observed along with the disappearance of various CH2 vibrations on annealing. Although our studies showed greener synthesis of Zn-based LDH layers, we have found the efficient thermal decomposition of PVA due to LDO fillers at low temperature. Further studies are nevertheless required to explore the processes involved in the PVA and LDH dispersion and degradation during annealing.

Data Availability

All data used in this study are available and public (no restrictions).

Conflicts of Interest

The authors declare that there is no conflict of interest regarding the publication of this paper.

Acknowledgments

The authors acknowledge the Deanship of Scientific Research at King Faisal University for the financial support under the annual research project (Grant No. 170054).

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