Research Article
Preparation and Assessment of Some Characteristics of Nanoparticles Based on Sodium Alginate, Chitosan, and Camellia chrysantha Polyphenols
Table 5
Parameters obtaining from kinetic models reflecting fast release stage of PP from free PP and AGN/CS/PP nanoparticles in different pH solutions.
| Sample | Zero order kinetic | First order kinetic | Higuchi model | Hixson - Crowell model | Korsmeyer-Peppas model | | SSE | MSE | | | SSE | MSE | | | SSE | MSE | | | SSE | MSE | | | SSE | MSE | | |
| pH 2 | PP | 0.988 | 607.305 | 67.478 | <0.001 | 0.980 | 0.165 | 2.10-3 | <0.001 | 0.986 | 4.518 | 0.502 | <0.001 | 0.994 | 8.10-4 | 9.10-5 | <0.001 | 0.980 | 0.017 | 2.10-3 | <0.001 | 0.014 | PP10 | 0.996 | 4133.539 | 459.282 | <0.001 | 0.960 | 0.238 | 0.026 | <0.001 | 0.982 | 4.518 | 0.502 | <0.001 | 0.978 | 2.10-3 | 3.10-4 | <0.001 | 0.996 | 0.309 | 0.034 | <0.001 | 0.061 | PP20 | 0.992 | 3508.085 | 389.787 | <0.001 | 0.963 | 0.205 | 0.023 | <0.001 | 0.980 | 4.518 | 0.502 | <0.001 | 0.976 | 3.10-3 | 3.10-4 | <0.001 | 0.963 | 0.205 | 0.023 | <0.001 | 0.049 | PP30 | 0.990 | 3873.501 | 430.389 | <0.001 | 0.930 | 0.267 | 0.030 | <0.001 | 0.984 | 4.518 | 0.502 | <0.001 | 0.959 | 4.10-3 | 5.10-4 | <0.001 | 0.930 | 0.267 | 0.030 | <0.001 | 0.055 | PP50 | 0.978 | 3047.075 | 338.564 | <0.001 | 0.958 | 0.152 | 0.017 | <0.001 | 0.975 | 4.518 | 0.502 | <0.001 | 0.967 | 4.10-3 | 4.10-4 | <0.001 | 0.958 | 0.152 | 0.017 | <0.001 | 0.042 |
| pH 4.5 | PP | 0.988 | 923.835 | 102.648 | <0.001 | 0.981 | 0.026 | 3.10-3 | <0.001 | 0.983 | 4.518 | 0.502 | <0.001 | 0.984 | 1.10-3 | 1.10-4 | <0.001 | 0.981 | 0.026 | 0.003 | <0.001 | 0.018 | PP10 | 0.994 | 2884.072 | 320.352 | <0.001 | 0.976 | 0.135 | 0.015 | <0.001 | 0.977 | 4.518 | 0.502 | <0.001 | 0.986 | 1.10-3 | 1.10-4 | <0.001 | 0.981 | 0.194 | 0.022 | <0.001 | 0.048 | PP20 | 0.977 | 3000.095 | 333.334 | <0.001 | 0.993 | 0.168 | 0.019 | <0.001 | 0.923 | 4.518 | 0.502 | <0.001 | 0.991 | 2.10-3 | 2.10-4 | <0.001 | 0.995 | 0.227 | 0.025 | <0.001 | 0.052 | PP30 | 0.994 | 3696.342 | 410.705 | <0.001 | 0.970 | 0.213 | 0.024 | <0.001 | 0.977 | 4.518 | 0.502 | <0.001 | 0.982 | 3.10-3 | 4.10-4 | <0.001 | 0.975 | 0.280 | 0.031 | <0.001 | 0.058 | PP50 | 0.951 | 2005.854 | 222.873 | <0.001 | 0.976 | 0.091 | 0.011 | <0.001 | 0.883 | 4.518 | 0.502 | <0.001 | 0.969 | 2.10-3 | 3.10-4 | <0.001 | 0.990 | 0.144 | 0.016 | <0.001 | 0.042 |
| pH 6.8 | PP | 0.969 | 1256.285 | 139.587 | <0.001 | 0.940 | 0.047 | 0.005 | <0.001 | 0.995 | 4.518 | 0.502 | <0.001 | 0.951 | 2.10-3 | 2.10-4 | <0.001 | 0.940 | 0.047 | 0.005 | <0.001 | 0.023 | PP10 | 0.951 | 1558.834 | 173.204 | <0.001 | 0.903 | 0.059 | 0.007 | <0.001 | 0.981 | 4.518 | 0.502 | <0.001 | 0.921 | 6.10-4 | 7.10-5 | <0.001 | 0.942 | 0.106 | 0.012 | <0.001 | 0.035 | PP20 | 0.983 | 2470.368 | 274.485 | <0.001 | 0.977 | 0.106 | 0.012 | <0.001 | 0.963 | 4.518 | 0.502 | <0.001 | 0.980 | 2.10-3 | 2.10-4 | <0.001 | 0.985 | 0.160 | 0.018 | <0.001 | 0.044 | PP30 | 0.981 | 1330.367 | 147.819 | <0.001 | 0.980 | 0.050 | 0.006 | <0.001 | 0.955 | 4.518 | 0.502 | <0.001 | 0.982 | 1.10-3 | 1.10-4 | <0.001 | 0.989 | 0.093 | 0.010 | <0.001 | 0.033 | PP50 | 0.946 | 1022.319 | 113.591 | <0.001 | 0.914 | 0.035 | 0.004 | <0.001 | 0.991 | 4.518 | 0.502 | <0.001 | 0.926 | 1.10-4 | 1.10-4 | <0.001 | 0.914 | 0.035 | 0.004 | <0.001 | 0.020 |
| pH 7.4 | PP | 0.991 | 2032.912 | 225.879 | <0.001 | 0.963 | 0.108 | 0.012 | <0.001 | 0.993 | 4.518 | 0.502 | <0.001 | 0.975 | 5.10-3 | 6.10-4 | <0.001 | 0.963 | 0.108 | 0.012 | <0.001 | 0.035 | PP10 | 0.983 | 2068.180 | 229.798 | <0.001 | 0.951 | 0.081 | 0.009 | <0.001 | 0.999 | 4.518 | 0.502 | <0.001 | 0.963 | 9.10-4 | 1.10-4 | <0.001 | 0.966 | 0.134 | 0.015 | <0.001 | 0.040 | PP20 | 0.959 | 1920.721 | 213.413 | <0.001 | 0.924 | 0.072 | 0.008 | <0.001 | 0.993 | 4.518 | 0.502 | <0.001 | 0.937 | 1.10-3 | 1.10-4 | <0.001 | 0.953 | 0.123 | 0.014 | <0.001 | 0.038 | PP30 | 0.986 | 1770.371 | 196.708 | <0.001 | 0.968 | 0.063 | 0.007 | <0.001 | 0.989 | 4.518 | 0.502 | <0.001 | 0.975 | 1.10-3 | 2.10-4 | <0.001 | 0.979 | 0.111 | 0.012 | <0.001 | 0.036 | PP50 | 0.984 | 1636.824 | 181.896 | <0.001 | 0.963 | 0.056 | 0.006 | <0.001 | 0.995 | 4.518 | 0.502 | <0.001 | 0.971 | 1.10-3 | 2.10-4 | <0.001 | 0.977 | 0.103 | 0.011 | <0.001 | 0.034 |
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