International Journal of Superconductivity

Volume 2014 (2014), Article ID 957045, 15 pages

http://dx.doi.org/10.1155/2014/957045

## Charge and Spin Currents in Ferromagnet-Insulator-Superconductor Tunneling Junctions Using Hg-1223 High- Superconductor

Department of Electrical and Electronic System Engineering, Utsunomiya University, 7-1-2 Yoto,Utsunomiya, Tochigi 321-8585, Japan

Received 25 April 2014; Revised 7 July 2014; Accepted 8 July 2014; Published 26 August 2014

Academic Editor: Zigang Deng

Copyright © 2014 Michihide Kitamura et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

#### Abstract

Charge and spin currents along the -axis in ferromagnet-insulator-superconductor (F/I/S) tunneling junctions have been studied within the framework of the tunneling Hamiltonian model. As a superconductor , HgBa_{2}Ca_{2}Cu_{3}O_{8+δ} (Hg-1223) with copper-oxide high- superconductor has been selected, and as a ferromagnet *F*, Fe metal with bcc structure has been selected for simplicity. The electronic structures of above materials have been calculated on the basis of the band theory using the spin-polarized self-consistent-field data for the atomic orbital energies and the universal tight-binding parameters (UTBP) for the interactions. For the and defined in the present paper, which are tunneling probabilities of the majority and the minority spin electrons, it is shown that the condition means the standard F/I/S tunneling junction with a nonmagnetic insulating layer, and the condition means the F/I/S tunneling junction with a magnetic insulating layer showing a detectable magnetization. We have found that the charge current and the differential conductance nearly remain the same as the change of , but the spin current is largely changed due to the change of . As an experimental method to detect the change of the spin current, the validity of an X-ray magnetic circular dichroism (XMCD) has been pointed out.

#### 1. Introduction

In 1982, Blonder, Tinkham, and Klapwijk (BTK) presented a pioneering paper for an interface at the normal (N) material and superconductor (S), in which they proposed a simple theory for the current-voltage (-) curves of normal (N)-superconducting (S) microconstriction contacts which describes the crossover from metallic to tunnel junction behavior [1]. Their model based on the Bogoliubov-de Gennes (BdG) equation, now called as “BTK model," worked well to understand the transmission and reflection of particle at N-S interface. Their results told us that the probability of Andreev reflection decreases with increasing the barrier strength at the interface and the BTK model reaches to the tunneling Hamiltonian model due to the increasing -value. Based on the BTK model, Kashiwaya et al. theoretically studied the origin of zero-bias conductance peaks (ZBCPs) observed in the YBCO high- superconductors and found that the calculation is in good agreement with the experiment [2]. The ZBCPs are observed at the - characteristics of the NS-interface. Within the framework of the BTK model, Kashiwaya et al. further studied the - characteristics of N/I/S and F/I/S junctions [3, 4]. Here it is noted that they have adopted the BTK model, so that the potential of the real insulating layer has been treated as a delta-functional and the tunneling electron has been regarded as a free particle under the effective mass approximation. Similar considerations have also been done by Annunziata et al. [5].

In the present paper, we consider the -axis electron tunneling in the F/I/S tunneling junction using the -wave high- superconductors. The insulating layer with a real dimension is considered here, so that the tunneling Hamiltonian model could be reliable for the present purpose because of a large -value. Furthermore, the electron is treated as not free but Bloch type, so that the electron states have been calculated on the basis of the band theory. It is well known that the superconducting energy gaps of -wave copper-oxide high- superconductors strongly depend on the wavenumber vector characterizing the CP, that is, , and that the -dependence of is given by . It should be emphasized here that, in the tunneling Hamiltonian model adopted in the present paper, the -dependence of the is exactly taken into account in all the calculation procedures.

Recently, an interesting experimental paper has been presented by Takeshita et al. [6], in which they have measured the electrical resistivity of a (Hg-) polycrystalline sample under the high pressure and found the with K at the hydrostatic pressure of GPa. It was already reported and well known that the Hg-based copper-oxides high- superconductors with and , which are denoted as Hg-, Hg-, Hg-, and Hg-, show higher as compared with the other copper-oxides superconductors such as BSCCO and YBCO. The in K is , , , and , respectively [7], for the Hg-, -, -, and -, and the superconducting gap at low temperature region in meV is , , and for the Hg-, -, and -, respectively [8]. It has been reported that the measured values of in high-T samples are approximately in Hg-, in Hg-, and in Hg- [9]. The of Hg-based copper-oxides superconductors is fairly higher than the liquid nitrogen temperature ( K), so it is surely expected that the superconductivity is well kept even in the case that the Hg-based copper-oxides superconductors have been operated at . From the experimental and the applicational points of view, in the present paper, the Hg- high- superconductor with , that is, whose is K, is selected as the superconducting (S) layer. The sample temperature in the present calculations is fixed to , so that the value of is . The value of is meV, so that the BCS curve for the energy gap as a function of the reduced temperature gives a value of meV at .

In the present paper, for simplicity, Fe metal with bcc structure has been adopted as a ferromagnetic (F) layer. It is sure that the electron states in the vicinity of the Fermi level mainly come from orbital of the transition metals and that the density of states (DOS) that originated from the orbital shows a pointed structure meaning the localized nature, on the contrary to the DOS from and orbitals which show a broadened structure, that is, the extended nature. It may be sure that the effective mass approximation works well for the extended nature but not so for the localized one. This is just a reason why we have adopted the tunneling Hamiltonian model based on the electrons with the Bloch states.

#### 2. Theoretical

The charge and spin currents, and , as a function of an applied voltage can be evaluated by using (A.8) and (A.9). In the following, therefore, we consider the tunneling current given by (A.9); that is,

Generally, can be written as . Here is a value depending only the spin state and the is a* dimensionless* value as a function of and . As a value of , we consider here three cases; that is, the first one is the coherent tunneling case denoted by , the second one is the incoherent case , and the third one is the case based on the WKB approximation . It is clear that and . In the WKB treatment, the momentum parallel to the junction plane is conserved in the tunneling processes [11]. If we use a geometrical configuration such that the axis normal to the junction plane is -axis which is parallel to the -axis, then can be written as , where and . Here it should be noted that two wavenumbers and have been introduced so as to satisfy the condition such that the and must be the dimensionless values. Namely, it must be emphasized that the amplitudes of and are not essential in the evaluation of and that the influence of the amplitudes and is included in the value of . From the above, the given by (1) can be rewritten as follows:
For the function , there are three functions , , and corresponding to the coherent, incoherent, and WKB cases. Those are given as follows:
where and the is the total density of states (TDOS) of the ferromagnetic layer for the -spin state as a function of .

In the present paper, one-electron energies such as and , which are for ferromagnetic and superconducting layers, are calculated on the basis of the band theory using a universal tight-binding parameters (UTBP) method proposed by Harrison [12]. The energies of the atomic orbitals used in the band structure calculations have been calculated by using the spin-polarized self-consistent-field (SP-SCF) atomic structure calculations based on the Herman and Skillman prescription [13] using the Schwarz exchange correlation parameters [14]. The calculation procedure of the present band structure calculation is the same as that of our previous band structure calculation [15].

The energy of an electron with a -spin state is calculated for the wavenumber within the 1st Brillouin zone (BZ) and the total wave function is expanded by using Bloch orbitals as follows: where and are the site to be considered and the quantum state of atomic orbital, respectively, and is the coefficient in the Bloch expansion of the total wave funtion. Therefore, the following relation is found for the superconducting layer : Here it is noted again that the can be regarded as when the CPs in superconducting layer are in the spin-singlet state. An index “" in and means the superconducting layer , so the and are the site and quantum state adopted in the band structure calculation of the .

Using (8), (3) can be rewritten as follows:
where is the first BZ of . is defined by
The defined here is the tunneling probability of a -spin electron in the F/I/S tunneling junction, so it is sure that the value of strongly depends on the magnetic nature of an insulating layer . It is clear that when the shows no magnetic nature, the tunneling probabilities of majority and minority spin electrons should be equal, that is, , and that when the shows magnetic nature, those should differ from each other, that is, . As already stated, the present model does not* explicitly* include the details of the magnetic nature of the ; therefore, the value of should be treated as a parameter if we wish to extend the present model to the case in which the shows the magnetic nature. It is sure that when the magnetization of , , is parallel to that of , , that is, , the current due to the majority spin is larger than the minority one , and in the case of , the is largely decreased as compared with the parallel case . Namely, a relation should be satisfied for the parallel case , and a relation should be satisfied for the antiparallel case . In the present paper, therefore, is treated as a parameter characterizing the magnetic nature of the insulating layer .

The defined in (9) shows the* partial* current term due to the tunneling of a spin electron. Only the band structure calculation makes it possible to evaluate the . Therefore, from the calculations of , we can directly see which atomic orbitals contribute to the F/I/S tunneling phenomena. This is just an advantage of the use of the .

In the calculation of the - characteristics, if we write the maximum voltage as , that is, , then the calculation done for is good enough to see the overall profile of the - characteristics, since the - curve gradually reaches to the ohmic line due to increasing the voltage . On the practical point of view, it is convenient to define the normalized current . We define it as follows: Here, is defined by using defined in (9). Here note that .

From the above considerations, it is concluded that, in order to understand the nature of the charge and spin transfers in the F/I/S tunneling junctions, it is necessary to calculate the defined by (12), that is, defined in (9), as correctly as possible.

On the above considerations, we have* implicitly* assumed that the external magnetic field applying the junctions is not strong; that is, the Zeeman energy is small as compared with the amplitude of the superconducting gap. Therefore, the effect of the magnetic field can be ignored in the present considerations. Usually, such a treatment has no problem because the value of is very small; for example, that is only meV even in the case of the extremely strong magnetic field T. Exactly speaking, however, the effect of the Zeeman energy must be taken into account. In the present paper, its effect has been taken into account by using the same method done by Tedrow and Meservey [16]. Namely, the quasiparticle excitation energy has been replaced by for the majority and the minority spin, respectively. Actually, we did a calculation for the external magnetic induction with the value of T and found that there is no detectable difference between the calculations for and T. In the present paper, therefore, the effect of the external magnetic field has not been considered anymore.

#### 3. Results and Discussion

##### 3.1. Electronic Structures

The electronic structures of a Hg- high- superconductor with , that is, , and the ferromagnetic Fe with bcc structure have been calculated on the basis of the band theory using the UTBP method. In the band structure calculations, the following atomic orbitals have been used: s and p orbits of Hg, s and p ones of Ba, s and p of Ca, d, s, and p of Cu, s and p of O, and d, s, and p orbits of Fe. In order to get the electronic structure of as correctly as possible, we have calculated it by using a unit cell consisting of Hg, Ba, Ca, Cu, and O. The unit cell of (= ) is shown in Figure 1, and the crystallographic data for Hg- with , , are tabulated in Table 1. In the present paper, the electronic structure of has been obtained by hole-doping into the electronic structure of we have calculated. The calculated densities of states (DOSs) are shown in Figure 2. Figure 2 clearly shows that the electronic structures near the Fermi level are made from Cu 3d and O 2p orbitals. This result allows us to suppose that the electronic structures near the come from layers in Hg- high- superconductor. Actually, we have clearly found it from the calculated results. This is a common feature found in all the copper-oxide high- superconductors.

The electron configuration used in the SP-SCF atomic structure calculation for the spin-polarized iron is , where . By using the spin-polarized self-consistent atomic data, the electronic structures of ferromagnetic Fe have been calculated for bcc structure. The calculated results are shown in Figures 3(a) to 3(e). Figure 3(a) is for nonmagnetic phase, that is, , and Figures 3(b), 3(c), 3(d), and 3(e) are for , , , and . Magnetic moment calculated per an atom is , , , and for Figures 3(b), 3(c), 3(d), and 3(e). Here note that the measured value of is [10].

##### 3.2. *I*-*V* Characteristics

As a tunneling process, we study here three processes such as coherent, incoherent, and WKB cases. In order to do so, we must evaluate the value of the function in (3). The TDOS in (5) can be calculated* separately*; therefore, many CPU time is not required to calculate the function for the incoherent case, because two band structure calculations for the and layers can be done* independently*. In the calculations of and , however, many CPU time is needed since two band structure calculations for the and are correlated with each other, as can be seen from (4) and (6). In the calculation of , moreover, the summation over must be done so that a very large CPU time is needed for the WKB case.

The - characteristics calculated for three cases are shown in Figure 4. Figures 4(a), 4(b), and 4(c) on the first line are results calculated for the nonmagnetic Fe, that is, N/I/S junction, Figures 4(d), 4(e), and 4(f) on the second one are for the spin-polarized Fe of the electron configuration with , and Figures 4(g), 4(h), and 4(i) on the third one are for that with . The curves drawn in Figures 4(a), 4(d), and 4(g), which are on the left column, are results calculated as the coherent tunneling, those in Figures 4(b), 4(e), and 4(h) on the central column are those as the incoherent one, and those in Figures 4(c), 4(f), and 4(i) on the right one are those as the WKB treatment. When the tunneling occurs coherently, Figures 4(a), 4(d), and 4(g) clearly show some regions in which the differential conductance is evaluated as the negative value which is not reasonable. Namely, the present calculation tells us that the coherent tunneling does not occur in the F/I/S and N/I/S junctions considered here. It should be noted here that the accumulation number of the in (3) varies as a function of the applied voltage . This may be the reason why the negative differential conductance is found in the case of coherent tunneling.

In the results calculated as the incoherent and WKB cases, there is no region of the negative differential conductance, except for the region around the normalized voltage in Figure 4(c) for the WKB treatment. Furthermore, it seems that the overall profiles of the - characteristics calculated for the incoherent and WKB cases are similar to each other. As already stated, the numerical calculations for the WKB case need a huge CPU time. In the following, therefore, we present only the results calculated for the incoherent case, that is, the case such that is evaluated as depending only on the spin valuable .

The - characteristics calculated for a ferromagnet-insulator-superconductor (F/I/S) tunneling junction are shown in Figure 5. The normalized charge and spin currents, and defined by (11), are drawn together with the corresponding differential conductance obtained from the normalized current and the normalized voltage . Here note that the is defined by using the real voltage and the amplitude of . In Figure 5, (a), (b), and (c) on the first line are results calculated for the N/I/S junction; that is, the iron is in nonmagnetic phase, (d), (e), and (f) on the second line are those for the F/I/S junction calculated by using a ferromagnetic iron with the electron configuration of , (g), (h), and (i) on the third line are those of , (j), (k), and (l) on the fourth one are of , and (m), (n), and (o) on the bottom line are those of . The - characteristics drawn in (a), (d), (g), (j), and (m) on the left column have been obtained by using , those in (b), (e), (h), (k), and (n) on the middle column are for , and those in (c), (f), (i), (l), and (o) on the right column are for .

The normalized current defined by (11) can be rewritten as follows: Here, for the incoherent case defined by (5) can be well approximated as follows: Equation (14) tells us that only the quasiparticle excitation energy with the energy region of is valid for the evaluations of tunneling currents. Therefore, the DOS as a function of the energy is evaluated only in the energy region of . From a relation and our calculation conditions and meV, the DOS of ferromagnetic iron is evaluated only in the energy region of meV, whose energy is measured from the .

###### 3.2.1. Case of

As already stated, the present case corresponds to the case when the insulating layer shows no magnetic nature, that is, the case of a standard F/I/S junction. From (b), (e), (h), (k), and (n) on the middle column of Figure 5, in which a relation is satisfied, we can see that the - curve, the resultant differential conductance, and the spin current are changed due to the change of . For the spin current, moreover, an interesting result such that the minority spin current exceeds the majority one is found. This interesting result is clearly found in the positive voltage region of Figure 5(n).

On the positive voltage region, the normalized spin current can be represented as Equation (15) clearly tells us that the interesting result shown in Figure 5(n) originated from the difference between the DOSs of the majority and minority spin bands of ferromagnetic iron. The calculated results shown in Figure 3 show that the values of and satisfy the condition of except for the case shown in Figure 3(e). Here note that the results shown in Figures 5(m), 5(n), and 5(o) have been calculated by using the DOS shown in Figure 3(e). We can say that the condition has led to an interesting result mentioned above.

###### 3.2.2. Case of

Present case corresponds to the case such that the insulating layer shows a magnetic nature such as a detectable magnetization . As already stated, a relation corresponds to the , and the does to the . In the FIS tunneling junction with the magnetic insulating barrier, it may be expected that a proximity effect could be found between the magnetic barrier and the superconducting layer. In the present study, however, all possible proximity effects have been neglected for simplicity.

The - characteristics calculated for the case of are shown in (a), (d), (g), (j), and (m) on the left column, and those for are in (c), (f), (i), (l), and (o) on the right column of Figure 5. In the present subsection, we consider the case of . Therefore, in the following, only the case of the F/I/S tunneling junction, that is, the case excepting Figures 5(a), 5(b), and 5(c) for the N/I/S junction, is considered.

From (13) and (14), we can see that (I) the condition works by increasing the DOS and decreasing the and (II) the condition inversely works as mentioned in (I), that is, by decreasing the majority spin band and increasing the minority one. A result such that the minority spin current exceeds the majority one is clearly found in Figures 5(f), 5(l), and 5(o). We can see that the - curve and the resultant diffrential conductance nearly remain the same as the change of , but the spin current is largely changed due to the change of . Such a behavior is clearly found from the comparison of three Figures 5(d), 5(e), and 5(f) on the second line. In the next subsection, therefore, we consider the spin currents found in Figures 5(d), 5(e), and 5(f).

###### 3.2.3. Spin Current

It has already been stated that the defined in (9) shows the* partial* current term due to the tunneling of a spin electron, so that the present calculation is able to show which atomic orbitals contribute to the F/I/S tunneling phenomena. This is just an advantage of our calculation method. It is easy to divide the spin currents drawn in Figures 5(d), 5(e), and 5(f) into the atomic orbital parts, , , , , , , , , and . The calculated result clearly showed that the most important atomic parts are orbitals of Cu, as is expected. The , , , , and parts of the spin currents drawn in Figures 5(d), 5(e), and 5(f) are shown in Figures 6(a), 6(b), and 6(c). The calculated results tell us that the most dominant spin current is observed in an electron tunneling between the orbits of ferromagnetic Fe and the Cu orbit of Hg- high- superconductor. Cu and O and atomic orbitals make a -bonding state which acts as a stage of an electron transfer within a superconducting layer. This is a common feature found in all the copper-oxide high- superconductors; therefore, it seems that the change of the spin state of the Cu atomic orbital makes a large effort to the superconductivity. In the following, therefore, we focus our attention on only the Cu atomic orbital and consider how the change of spin should be observed.

It is well known that the experiment of the X-ray magnetic circular dichroism (XMCD) is a powerful tool to see directly the nature of the spin dependent electron state near the . Now, let us consider two absorption processes such as the and the for the Cu atom in Hg- high- superconductor. The Cu orbit is written as where is the radial wave function of Cu atomic orbital and is the spherical harmonics. Therefore, the hole state of , which is the electron state just above the , can be written as where , , and a relation is satisfied. Using Clebsch-Gordan coefficients, the and states can be written as follows: For the circular polarized lights with the helicity , the Hamiltonian of the dipole-allowed transition is written as where is the amplitude of the electric field . It is clear that (20) becomes a standard Hamiltonian for the dipole-allowed transition when a zero helicity light is considered, that is, when is replaced by . There are some allowed-absorption processes. In the present paper, only the allowed transition with is considered for simplicity.

It is easy to calculate the oscillator strength . When , the is evaluated as follows: where and . An integral in (21) is calculated as follows: Here is a Gaunt integral. In the and XMCD absorption spectra with helicity , the oscillator strength is finally written as follows: where we note that . By using (23), the absorption ratio is calculated as The value of is exactly equal to when no spin current is observed. In such a situation, therefore, the value of remains . However, if a sizable spin current is found, then it is sure that the value of differs from . As can be seen from (17), the reflects the nature of the minority spin hole. Therefore, if the spin state of electrons injected into the superconductor is largely changed, such as the case of Figures 5(d), 5(e), and 5(f), then it could be expected that a considerable change is observed experimentally for the absorption ratio because of a large change of . For example, let us consider the spin current at a positive voltage such as the normalized voltage . In the spin current shown in Figure 5(d), the electron with the majority spin is dominant; that is, the minority spin hole is dominant, so it is expected that a relation is satisfied for the spin current shown in Figure 5(d). Similar consideration gives a result such that a relation is satisfied for the spin current shown in Figure 5(f). Namely, it may be expected that the absorption ratio decreases due to the change from Figures 5(d) to 5(f), that is, with decreasing the . It may be possible to control the value of by experimentally handling the amplitude of the external magnetic field applied parallel to the junction surface. It is not so easy to detect the spin current; however, we believe that present prediction based on the XMCD could be useful to see qualitatively the spin current found in the F/I/S tunneling junction using the copper-oxide high- superconductors.

#### 4. Summary

We have studied the -axis charge and spin currents in ferromagnet-insulator-superconductor (F/I/S) tunneling junction on the basis of the tunneling Hamiltonian model. As a ferromagnet, Fe metal with bcc structure has been selected for simplicity, and the electronic structure has been calculated on the basis of the spin-polarized band theory using the spin-polarized self-consistent-field atomic data for the atomic energies and the universal tight-binding parameters for the interactions. As a superconductor, (Hg-) with copper-oxide high- superconductor has been selected from the reason of the high of K. The electronic structure of Hg- has been calculated by using the same method done for the ferromagnetic Fe. The band structure calculation for Hg- has clearly showed that the electronic structures near the Fermi level are made from Cu and O atomic orbitals and that the most important orbit is the Cu one in CuO layers in Hg-.

The -axis charge and spin currents in an F/I/S tunneling junction have been calculated as a function of the magnetization of ferromagnet and the applied voltage . Using a calculated charge current, the differential conductance has been also calculated. If the insulating layer shows a magnetic nature, it is surely expected that the tunneling probabilities of the majority and the minority spin electrons differ from each other. We have defined the and giving the tunneling probabilities of majority and the minority spin electrons. The calculated results have showed that the charge current and the resultant differential conductance nearly remain the same as the change of , but the spin current is largely changed due to the change of .

Present model includes the band theory, so that it is possible to see directly which atomic orbital contributes to the F/I/S tunneling phenomena. This is just an advantage of the model we have proposed here. We have clearly found that the most important orbit in the present F/I/S tunneling junction is the Cu atomic orbital in the Hg- high- superconductor. This is a common feature observed in not only the Hg-based superconductors but also the other copper-oxide superconductors such as YBCO and BSCCO. As a method to detect the change of the spin current, we have pointed out to the validity of the experiment of an X-ray magnetic circular dichroism (XMCD).

#### Appendix

#### Deduction of (1)

First, let us consider a tunneling junction consisting of material /insulator /material . For an electron tunneling from to , the tunneling Hamiltonian is given by Here, is an annihilation operator for an electron with the wavenumber and spin in material and is a creation operator for a -electron in . is the matrix element for an electron tunneling from state to one. We consider here the case in which no spin-flip is found for an electron tunneling. Therefore, the total Hamiltonian defined by is given as follows:

Next, we consider the case such that the is a ferromagnetic material and the is a superconductor , that is, an F/I/S junction. Only a superconductor in which all Cooper-pairs (CPs) are in a spin-singlet state is considered here, so it is instructive to rewrite (A.2) as follows: where and a relation is held. Using Bogoliubov transformation, and in (A.3) can be written as follows: where we note that and . It is clear that and are creation and annihilation operators for a quasiparticle characterized by , respectively, and that the and are expansion coefficients in the BCS wave function .

Equation (A.4) tells us that an electron tunneling from -electron in to one in can be regarded as a combination of four fundamental tunneling processes. Statistical averaging for operators such as , , , and gives the following corresponding relations: where means the statistical average and is Fermi-Dirac distribution function. Here it is very instructive to point out that the symbol “" in (A.6) appears when the semiconductor model is adopted for the superconductors [1]. is the energy relative to the Fermi level of a -electron in ferromagnetic layer , which is obtained from the band structure calculation. Here note that a relation is satisfied for almost all the materials. is a quasiparticle excitation energy defined by . Here it should be noted that the superconducting energy gap as a function of does not include explicitly the spin variable since the spin-singlet CPs are considered here. is the energy relative to the Fermi level of a -electron in superconducting layer , which is also obtained from the band structure calculation. We consider here CP with a spin-singlet state, so that the should be nonmagnetic layer. Namely, the spin variable of the one electron energy should be dropped out; that is, a relation should be held. A relation is of course satisfied, so that a relation is obtained for the quasiparticle excitation energy. A similar treatment is also done for operators in (A.5).

From Fermi’s golden rule, we can get the tunneling probabilities and for and tunneling as follows: Finally, we can get the charge and spin currents, and , as a function of an applied voltage . The result is given as follows: and the tunneling current for the spin electron is given by

#### Conflict of Interests

The authors declare that there is no conflict of interests regarding the publication of this paper.

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