Effects of Iron Concentration Level in Extracting Solutions from Contaminated Soils on the Determination of Zinc by Flame Atomic Absorption Spectrometry with Two Background Correctors
Table 2
Calibration data for the determination of Zn.
Background corrector
Calibration range (μg L−1)
Equation of calibration curves
LOD (μg L−1)
D2-FAASa
2–25
Abs = 0.47790 [Zn] + 0.00553 R2 = 0.9991
2.8
HSSR-FAASa
2–25
Abs = 0.44075 [Zn] + 0.00015 R2 = 0.9988
1.5
D2-FAASb
2–25
Abs = 0.37643 [Zn] + 0.00030 R2 = 0.9993
6.5
HSSR-FAASb
2–25
Abs = 0.37154 [Zn] + 0.00074 R2 = 0.9992
1.9
D2-FAASc
2–25
Abs = 0.42581 [Zn] + 0.00080 R2 = 0.9992
3.8
HSSR-FAASc
2–25
Abs = 0.31517 [Zn] − 0.00044 R2 = 0.9991
1.6
D2-FAASd
2–25
Abs = 0.42600 [Zn] + 0.00038 R2 = 0.9973
2.6
HSSR-FAASd
2–25
Abs = 0.27455 [Zn] − 0.00029 R2 = 0.9981
0.7
D2-FAASe
2–25
Abs = 0.36182 [Zn] + 0.00015 R2 = 0.9987
3.1
HSSR-FAASe
2–25
Abs = 0.32234 [Zn] − 0.00070 R2 = 0.9993
1.9
aIn water.
bIn 0.11 M acetic acid.
cIn 0.5 M hydroxylamine hydrochloride (F2).
dIn 1 M ammonium acetate pH = 2 (F3).
eIn HNO3 14%.