Research Article

Effects of Iron Concentration Level in Extracting Solutions from Contaminated Soils on the Determination of Zinc by Flame Atomic Absorption Spectrometry with Two Background Correctors

Table 3

Pseudototal Fe, Cu, and Zn concentrations (mean value ± standard deviation) measured in certified reference soil ( 𝑛 = 3 ) and kitchen garden (KG) soil samples ( 𝑛 = 3 ).

SamplesFe in this work (mg kg−1)Cu in this work (mg kg−1)Zn certified value (mg kg−1)Zn with the D2 method (mg kg−1)Zn with the HSSR method (mg kg−1)

BCR-48326,642 ± 1,180a403 ± 11c987 ± 37b,c939 ± 481,013 ± 59
BCR-70136,975 ± 342d43.8 ± 1.5e454 ± 19f474 ± 15478 ± 7
KG122,496 ± 717 3 5 . 5 ± 2 . 3 821 ± 10808 ± 6
KG224,681 ± 799 2 5 . 6 ± 1 . 9 513 ± 4531 ± 7
KG323,628 ± 685 1 3 . 3 ± 1 . 3 813 ± 15958 ± 17
KG418,846 ± 578 7 8 . 2 ± 3 . 1 867 ± 9895 ± 1
KG520,026 ± 624 7 4 . 4 ± 2 . 8 1,052 ± 211,051 ± 12
KG624,399 ± 790 6 3 . 3 ± 2 . 3 1,398 ± 211,410 ± 24
KG718,851 ± 580 2 7 . 3 ± 1 . 1 505 ± 3522 ± 6
KG827,029 ± 890 1 7 0 . 4 ± 5 . 4 4,502 ± 254,842 ± 54
KG931,440 ± 661 1 2 . 6 ± 1 . 0 655 ± 5667 ± 5

aFrom Kubová et al. [38], [Fe] = 26,700 ± 480 mg kg−1.
bIndicative value from Rauret et al. [39], ( 𝑛 = 5 ).
cFrom Pueyo et al. [40], [Zn] = 1,026 ± 37 mg kg−1; [Cu] = 373 ± 14 mg kg−1 ( 𝑛 = 6 ).
dFrom Kubová et al. (2004) [38], [Fe] = 38,580 ± 220 mg kg−1.
eCertified value: [Cu] = 4 6 . 4 ± 1 . 8  mg kg−1 ( 𝑛 = 6 ).
fFrom Pueyo et al. [40], [Zn] = 474 ± 10 mg kg−1 ( 𝑛 = 6 ).