Review Article

Recent Developments in the Speciation and Determination of Mercury Using Various Analytical Techniques

Table 3

Analytical parameters of reviewed research papers about the speciation and determination of mercury by electrochemical instruments.

S. numberAnalyteAnalytical instrument used for the detectionMethodLimit of detection (LOD)#Linearity rangeAnalyzed samplesInterference studySupporting mediaReference

1Hg(II)DP-ASVElectrochemical4.99 × 10−8 MAmbient water, tap, and wastewatersPalladium-natural phosphate-carbon paste electrode enhances the selectivity for Hg2+Natural phosphate electrodes[103]

2Hg(II)SW-ASVElectrochemical0.04 × 10−6 M0.2–10.0 μMFoodstuffsSimultaneously both Cd2+ and Hg2+ are determined and 1,000-fold for K+, Na+, Li+, , Ca2+, Mg2+, Pb2+, Zn2+, Cr3+, Fe2+, Co2+, and Al3+ did not interfereCarbon paste electrode[104]

3Hg(II)Differential pulse voltammeterElectrochemical4.48 × 10−10 M0.2–10 μg L−1Spiked fish and plant samplesCu(II), Mg(II), As(III), and Cr(II) were possible interferers4,4′-Bipyridine-silver polymer[105]

4Hg(II)Cyclic voltammeterElectrochemical0.8 × 10−14 M10−14–10−7 MCu2+, Pb2+, Ni2+, Zn2+, Cr3+, Co3+, As5+, Fe2+, and Fe3+ did not interfereGold atomic cluster-chitosan[106]

5Hg(II)Voltammeter
(cyclic and differential pulse)
Biosensor3.93 × 10−12 M0.005–0.034 mMWater samplesThe working potential controlled to minimize the interference of other metal ions in test mediumPANI and PANI-co-PDTDA polymer films[107]

6Hg(II)ASVElectrochemical4.98 × 10−9 M4–160 ppbAquatic solutionsGlassy carbon electrode[108]

7Hg(II)SW-ASVElectrochemical9.2 × 10−5 M0.1–150.0 nMSoil, gasoline, fish, tap, and wastewaters400-fold mass ratio of Cu2+, Mn2+, Zn2+, Cr3+, Cr6+, Fe3+, Fe2+, Ni2+, and Co2+ did not interfere in the simultaneous determination of Cd2+, Pb2+, and Hg2+Triphenyl phosphine[109]

8Hg(II)PotentiometerElectrochemical9.77 × 10−6 M (PME)1
7.76 × 10−7 M (CGE)1
1.0 × 10−1–5.0 × 10−6 M (PME) 
1.0 × 10−1–5.0 × 10−7 M (CGE)
Water samplesAg+ has small interference in the determination of Hg2+1,3-Alternate thiacalixcrown[110]

9Hg(II)PotentiometerElectrochemical1.0 × 10−8 M5.0 × 10−8–1.0 × 10−2 MThe selectivity coefficient of the other ions is ranging from 2.9 to 4.9PVC membrane[111]

10Hg(II)DPSVElectrochemical0.05 × 10−12 M1–500 nMWater samplesPb2+, Th3+, Cu2+, Cd2+, Ni2+, and Al3+ did not interfereGold nanoparticles[112]

11Hg(II)SW-ASVUltrasonic extractionIndoor dust samplesGold nanoparticles[113]

12Hg(II)Cyclic voltammeterElectrochemical1.9 × 10−9 M40–170 μg L−1WastewatersBiotinyl Somatostatin-14 peptide [114]

13Hg(II)PotentiometerElectrochemical3 × 10−6 M5 × 10−6–1 × 10−2 MContaminated waterNa+, K+, Mg2+, Ca2+, Zn2+, Cu2+, Cr3+, Fe3+, and Pb2+ did not interfere in the determination of Hg2+Dithizone and di-n-butyl phthalate[115]

14Hg(II)DP-ASVElectrochemical0.483 × 10−6 M 300–700 ng mL−1No interference of Cd, Ni, Zn, and Cu in 50-, 25-, 100-, and 5-fold in excess, respectivelyNanocellulosic fibers[116]

15Hg(II)Electrochemical0.5 × 10−9 M1.0 nM–1.0 μMZn2+, Mg2+, Ca2+, Pb2+, Cd2+, Mn2+, Cu2+, Ni2+, and Fe3+ did not interfereG-quadruplex–hemin (G4–hemin)[117]

For the conversion of limit of detection values into moles per liter (M) the atomic weight of Hg is taken as 200.59 g, MeHg as 215.59 g, EtHg as 229.59 g, and PhHg as 277.59 g.
1PME: polymeric membrane electrode and CGE: coated graphite electrode.
Analytical instruments: DP-ASV: differential pulse anodic stripping voltammeter; SW-ASV: square wave anodic stripping voltammeter.