Review Article
Pencil Graphite Electrodes: A Versatile Tool in Electroanalysis
Table 2
Electroanalytical applications of ETPGEs.
| Compound | Technique | Linear range (μM) | LD (μM) | Sample | Ref. |
| Alkylphenols | DPV | | | Water | [50] | 4-Nonylphenol | 1.20–94 | 0.420 | 4-Octylphenol | 0.6–78 | 0.250 | 4-tert-Octylphenol | 2.38–243 | 0.770 |
| 4-Aminophenazone Caffeine | DPV | 1–11 1–9 | 0.0796 0.00981 | Real samples | [98] |
| Benzo(a)pyrene | SWSV | 0.25–1.25 | 0.027 | Spiked human urine | [99] |
| Bisphenol A | AdDPSV | 0.05–5; 5–10 | 0.0031 | Tape and river water | [54] |
| Boron | DPV | 280–12000 | 84 | Water, steel | [4] |
| Capsaicin, dihydrocapsaicin | AdSWSV | 0.016–0.32 0.0033–0.33 | 0.0037 0.00091 | Turkish pepper | [25] |
| Chlorpromazine | DPV | 0.35–35 | 0.2 | Human plasma, urine | [22] |
| Cinchocaine hydrochloride | DPV: ox red SWV: ox red | 1.5–18 1.3–13.6 1–11 1.3–17.7 | 0.664 0.458 0.452 0.483 | Spiked human urine | [58] |
| Dopamine | ATSDPV | 0.01–5.0 | 0.00031 | Blood serum | [21] |
| Dopamine Uric acid | DPV | 0.15–15 0.3–150 | 0.033 0.12 | Pharmaceuticals, body fluids | [2] |
| Gluten | DPV | 20–100 | 7.11 | Flour, vinegar, baker’s yeast | [56] |
| Indole-3-acetic acid Kinetin | SWV | 0.5–2; 2.5–10 | 0.14 0.11 | Maize plant extracts | [100] |
| Methamphetamine | DPV | 0.074–54 | 0.05 | Human serum, urine | [101] |
| Morphine | DPV, Amp | 1–100 | 0.26 | Human urine, street drug samples | [102] |
| Nalbuphine hydrochloride | DPV SWV | 16–150 | 6.38 11.3 | Spiked urine, pharmaceuticals | [103] |
| α-Naphthol | LSASV | 0.01–2.0 | 0.0015 | Water | [47] |
| Nicotine | SWV | 7.6–107.5 | 2.0 | Cigarettes | [53] |
| Paracetamol | ATSDPV | 0.05–2.5 | 0.0025 | Blood serum | [57] |
| Phenol | SWV | 0.05–1 | 0.00417 | Water | [104] |
| Phenol, m-cresol | DPV | 40–320 | 0.120 | Insulin formulations | [9] |
| Quercetin | DPASV | 0.001–1.5 | 0.0003 | Cranberry, blackcurrant juices | [105] |
| Tannic acid | DPASV | 0.005–0.5 | 0.0015 | Beverages | [51] |
| Uric acid | DPV | 0.05–10 | 0.0015 | Body fluids | [106] |
| Uric acid | DPV | 1–160 | 0.19 | Human serum, urine | [107] |
| Vitamin C | Amp | 1–100 | 1.18 | Human plasma | [69] |
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In solution: SDS (sodium dodecyl sulphate) < critical micellar concentration; ng·mL−1; µg·mL−1; SWSV: square wave stripping voltammetry; AdDPSV: adsorptive differential pulse stripping voltammetry; AdSWSV: adsorptive square wave stripping voltammetry; ox: oxidation; red: reduction; ATSDPV: adsorptive transfer stripping voltammetry differential pulse voltammetry; LSASV: linear sweep anodic stripping voltammetry; DPASV: differential pulse anodic striping voltammetry. All the other abbreviations are like those in Table 1.
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