Journal of Analytical Methods in Chemistry / 2017 / Article / Tab 1 / Research Article
Development of a Novel, Sensitive, Selective, and Fast Methodology to Determine Malondialdehyde in Leaves of Melon Plants by Ultra-High-Performance Liquid Chromatography-Tandem Mass Spectrometry Table 1 Comparison of the analytical performance of the proposed methodology with others previously reported in the literature.
Detection technique Separation technology Derivatization reagent (derivatization time) Matrix Sample clean-up LOD (μ g L−1 ) LOQ (μ g L−1 ) References MS/MS UPLC (BEH C18 ) — Plant tissue SPE (OASIS HLB) 0.020 0.080 This study MS/MS HPLC (Hypercarb porous-graphite) — Urine SPE 0.087 0.105 [25 ] Plasma Protein precipitation with acetonitrile 0.031 0.039 Exhaled breath SPE 0.021 0.032 MS HPLC (Hyperclone C18 ) TBA (40 min) Plasma Hydrolysis with sodium hydroxide and protein precipitation with sulphuric acid 62 206 [21 ] MS/MS HPLC (C18 ) 4,2-trimethylammonio ethoxybenzenaminiumHalide or 4-APC (240 min) Plasma Protein precipitation with acetonitrile and on-line weak-cation exchange SPE (WCXE) 0.036 — [16 ] MS/MS HPLC (C18 ) 2,4-dinitrophenylhydrazine or DNPH (70 min) Urine Automated SPE 0.11 0.46 [15 ] PDA UHPLC (HSS T3 strength silica) — Urine Microextraction by packed sorbent (eVols-MEPS) 0.72 1.57 [26 ] UV HPLC (C18 ) — Serum Protein precipitation with perchloric acid 0.86 — [24 ] PDA Rocket HPLC (C18 ) TBA (30 min) Plant tissue Protein precipitation with metaphosphoric acid 0.022 — [13 ]
