Headspace Solid-Phase Microextraction Coupled to Comprehensive Two-Dimensional Gas Chromatography Time-of-Flight Mass Spectrometry for the Determination of Short-Chain Chlorinated Paraffins in Water Samples

<div>(a) GC × GC-TOF-MS chromatogram and elution pattern of a mixed SCCPs standard solution (C<sub>10–13</sub>, 55.5% chlorine) obtained on Rxi-5Sil MS × Rxi-17Sil MS column combination. Lower right: 3D contour plot. (b) Mass spectrum of a selected SCCP congener C<sub>10</sub>H<sub>17</sub>Cl<sub>5</sub>, where the fragment ion <i>m</i>/<i>z</i> 91 is the quantitative ion.</div>

Journal of Analytical Methods in Chemistry

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Figure 4

Figure 4: Headspace Solid-Phase Microextraction Coupled to Comprehensive Two-Dimensional Gas Chromatography Time-of-Flight Mass Spectrometry for the Determination of Short-Chain Chlorinated Paraffins in Water Samples 

Figure 4 | Headspace Solid-Phase Microextraction Coupled to Comprehensive Two-Dimensional Gas Chromatography Time-of-Flight Mass Spectrometry for the Determination of Short-Chain Chlorinated Paraffins in Water Samples 