Analysis of the HPLC Fingerprint and QAMS for Sanhuang Gypsum Soup

Table 7

Comparison of the results from the ESM and QAMS (μg·ml⁻¹).

Batch number	Berberine	Mangiferin		Geniposide		Liquiritin		Epiberberine		Coptisine		Baicalin		Palmatine
	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM
1	109.5341	40.2024	40.2261	181.4930	189.7332	23.0219	24.3703	6.3113	7.0281	46.8326	50.7789	134.5759	148.9816	11.4799	12.3100
2	89.2249	37.5741	37.7510	179.5150	188.7602	15.1217	16.3549	5.8212	6.5595	40.4232	44.4416	140.9748	156.3753	10.5081	11.3749
3	129.1133	35.8398	35.6103	157.0895	164.0831	15.6869	16.7843	7.5026	8.2207	54.0515	57.9725	163.0149	177.5168	12.7851	13.5988
4	124.5509	39.7362	39.6241	177.6354	185.2223	16.2344	17.3568	8.0797	8.8171	57.6934	61.7406	178.8141	193.8060	13.3434	14.1801
5	131.7465	42.8953	42.8017	215.0841	223.2552	13.4517	14.4941	8.1313	8.8596	58.7696	62.7683	177.6743	192.4197	13.8791	14.7108
6	91.8581	33.9407	33.9713	167.7467	176.4659	13.4688	14.6373	8.0163	8.8171	41.8712	45.8975	161.3843	177.2857	13.0916	14.0284
7	93.6830	33.7007	33.7037	184.5859	193.7133	12.6430	13.7785	5.6230	6.3466	40.0668	44.0134	121.2770	135.8693	10.4254	11.2738
8	83.4633	28.7922	28.7534	161.0843	170.0976	11.7671	12.9197	4.9025	5.6224	37.9355	41.9581	118.3847	133.3277	9.5326	10.3893
9	87.8692	35.7417	35.8779	191.4261	201.1430	15.2532	16.4980	5.3645	6.0910	47.1242	51.3784	151.7083	167.5237	9.7197	10.5662
10	96.1076	33.3683	33.3358	163.7588	172.1319	13.7647	14.9235	5.8754	6.6021	44.4223	48.4666	171.5295	187.5098	10.4331	11.2738
11	81.0647	21.1692	20.8931	96.3176	103.2304	10.2344	11.3452	3.7042	4.3872	33.2648	37.1624	93.3769	107.5653	7.3989	8.1907
12	127.4969	35.4701	35.2424	160.0752	167.1788	18.2031	19.3607	6.7088	7.4114	56.9690	60.9699	139.2935	153.3139	11.8422	12.6385
13	66.2826	26.8813	27.0141	161.2528	171.6896	10.7070	11.9177	4.4526	5.1965	32.0308	36.1347	95.5600	110.5690	7.9011	8.7719
value		1.0000		0.9990		1.0000		1.0000		1.0000		1.0000		1.0000
SMD		−0.14%		4.84%		5.00%		4.40%		3.88%		4.64%		5.00%
Harpagosid		Wogonoside		Cinnamic acid		Cinnamic aldehyde		Baicalein		Glycyrrhizic acid		Wogonin
QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM	QAMS	ESM
14.2582	13.7492	41.5099	41.9147	4.3225	4.4343	10.1104	10.3781	3.8998	3.8544	10.7680	10.8733	2.8363	2.8704
14.3794	13.9581	41.7443	42.4007	3.3197	3.4251	8.1171	8.3811	4.2131	4.2006	10.3196	10.4741	3.3573	3.4246
13.6995	13.1223	42.3230	42.5829	3.0224	3.0887	8.5102	8.7032	5.2322	5.2008	11.9814	12.0711	3.6155	3.6556
14.3017	13.7492	48.7639	49.2042	3.6181	3.7003	10.8341	11.0868	6.0932	6.0856	12.1021	12.2042	4.6062	4.6716
17.3874	16.8835	45.4335	45.7417	3.2033	3.2722	12.8653	13.1482	6.2136	6.2010	10.8139	10.8733	4.1144	4.1636
15.7097	15.3163	48.3223	49.1435	3.4117	3.5168	6.2494	6.4485	4.9259	4.9315	9.4250	9.5424	3.8532	3.9327
12.4737	11.9730	36.3218	36.7513	2.9684	3.0581	7.2536	7.4792	3.2858	3.2390	11.1098	11.2726	2.7346	2.7780
11.7217	11.2417	35.2517	35.7794	2.6324	2.7217	9.3460	9.6695	3.3857	3.3544	9.5254	9.6755	2.8142	2.8704
14.9799	14.5850	41.7833	42.4614	3.9107	4.0367	7.6140	7.8657	4.4720	4.4699	10.9594	11.1395	4.2506	4.3483
16.8469	16.4655	46.1440	46.8351	2.4359	2.5076	5.3190	5.4822	4.5214	4.5084	12.1523	12.3373	4.0377	4.1174
8.5808	8.0029	24.3588	24.5414	1.9207	1.9878	4.0460	4.1938	2.0815	2.0080	8.7446	8.8770	3.2131	3.2861
11.9582	11.3462	35.5964	35.7186	3.8293	3.9144	9.8943	10.1205	3.9137	3.8544	12.1083	12.2042	3.5242	3.5632
9.5187	9.0477	27.3810	27.8824	2.6982	2.8135	5.8692	6.1264	3.3202	3.3159	10.0833	10.3410	2.9233	3.0090
1.0000		1.0000		1.0000		1.0000		1.0000		0.9990		1.0000
−4.00%		1.15%		2.84%		2.92%		−0.80%		1.28%		1.75%