Review Article

Determination of Heavy Metal Ions and Organic Pollutants in Water Samples Using Ionic Liquids and Ionic Liquid-Modified Sorbents

Table 3

Determination of organic pollutants in real samples by IL solutions.

PollutantsSamplesUsed ILAnalysis conditionOperation methodAdded (μg/L)Found (μg/L)Recovery (%)LOD (μg/L)RSD (%)Ref.

o,p’-DDT, p,p’-DDT, p,p’-DDD, and p,p’-DDESnow, rain, lake, and tap water (5.0 mL)300.0 μL of [BMIM][PF6], [HMIM][PF6], [OMIM][PF6], [BMIM][BF4], [EMIM][BF4], and [BMIM]NO3R.T.; HPLCDLLME5.085.7–106.80.2–0.56.0–8.5[24]

17-β-Estradiol-benzoate, 17-α-estradiol, and quinestrolLake, well, tap, and river water (160.0 mL)80.0 μL of [BMIM][BF4] with 0.3 g of [NH4][PF6]R.T.; HPLCDLLME0.2–0.995.5–114.60.04–0.054.2–8.0[26]

Phenol, CP, DCP, TCP, and PCPAqueous emulsion (10.0 mL)0.02% (v/v) of [BMIM][PF6] in TBPR.T.; UV-visLiquid membranesExtraction efficiency: 96.9%–99.5%[79]
0.2% (v/v) of aliquat 336 in TBPExtraction efficiency: 90.1%–99.3%[80]

Phenol, o-cresol, 2-chlorophenol, and resorcinolAqueous solution5.0 mg/mL of [BMIM][Tf2N], [HMIM][Tf2N], and [PMIM][Tf2N]33°C; color reactionLiquid extraction99.99[81]

Gallic acid, vanillic acid, and vsyringic acidSalty aqueous solution (20.0 mL)5 wt% of [BMIM](SCN), [BMIM][TOS], [BMIM][N(CN)2], [BMIM][CH3CO2], [BMIM]Cl, [BMPIP]Cl, and [BMPYR]ClR.T.; UV-visATPExtraction efficiency: 66.0%–94.6%[82]

NT, DNT, and TNTTap and lake water (5.0 mL)26.0 mg of [HMIM][Tf2N] and [C6MPY][Tf2N]R.T.; HPLCDLLME5.0–20.04.7–20.093.2–101.00.7–1.13.1–4.3[83]

BPA, 4-CP, t-BP, OP, t-OP, and NPDeionized and sea water (20.0 mL)10.0 μL of [BMIM][Tf2N]R.T.; HPLCDLLME67.6–114.00.8–4.82.8–11.0[84]

BPA and 2-naphtholTap, lake, and river water (5.0 mL)35.0 μL of [OMIM][PF6]R.T.; HPLCCIA-ME20.097.1–108.10.6–0.92.3–4.1[85]

BPATap, reservoir, and beach water (0.05 mL)5.0 μL of TOAP20°C; HPLCATPM100.0–1500.095.5–1559.095.5–109.94.3–4.62.9–4.5[86]

TCL, DOX, BPA, TCS, and MTCSSea, WRTR, and tap water (5.0 mL)115.0 μL of [BMIM][PF6], [HMIM][PF6], and [OMIM][PF6]R.T.; HPLCSILM-DS8.0–50.06.3–47.774.5–106.90.1–0.82.2–6.5[87]