Research Article
Simultaneous Analysis of Twelve Bile Acids by UPLC-MS and Exploration of the Processing Mechanism of Bile Arisaema by Fermentation
Table 6
Recoveries of the twelve compounds (n = 3).
| Analytes | Samples (g) | Origin (μg) | Spiked (μg) | Found (μg) | Mean recovery (%) (RSD, %) |
| (1) THCA | 1.0 | 52.13 | 42.72 | 94.41 | 99.23 (1.11) | 53.40 | 104.52 | 98.27 (1.79) | 64.08 | 115.56 | 97.10 (2.96) |
| (2) THDCA | 1.0 | 103.35 | 82.69 | 185.95 | 99.90 (1.95) | 103.36 | 205.63 | 98.93 (2.43) | 124.03 | 227.24 | 95.36 (2.10) |
| (3) TCA | 1.0 | 70.48 | 56.82 | 126.41 | 98.73 (2.30) | 71.02 | 143.35 | 97.87 (1.46) | 85.22 | 154.87 | 99.07 (2.13) |
| (4) GHCA | 1.0 | 28.20 | 22.40 | 50.42 | 99.13 (0.96) | 28.00 | 56.05 | 96.30 (1.97) | 33.60 | 61.37 | 98.63 (2.49) |
| (5) GCA | 1.0 | 28.35 | 23.04 | 51.42 | 100.63 (0.66) | 28.80 | 56.53 | 97.90 (1.77) | 34.56 | 62.50 | 96.17 (0.96) |
| (6) GHDCA | 1.0 | 264.26 | 211.68 | 476.52 | 100.33 (0.90) | 264.60 | 523.14 | 97.87 (1.76) | 317.52 | 580.71 | 98.67 (2.30) |
| (7) TCDCA | 1.0 | 270.41 | 219.00 | 488.12 | 96.43 (1.99) | 273.75 | 544.43 | 102.15 (0.65) | 328.50 | 593.45 | 98.30 (1.99) |
| (8) HCA | 1.0 | 31.11 | 24.96 | 55.63 | 98.43 (1.12) | 31.20 | 62.12 | 97.10 (1.68) | 37.44 | 68.41 | 99.73 (2.21) |
| (9) CA | 1.0 | 28.71 | 22.88 | 51.34 | 97.10 (1.36) | 28.60 | 57.18 | 98.73 (1.57) | 34.32 | 62.56 | 100.97 (1.53) |
| (10) GCDCA | 1.0 | 651.34 | 520.08 | 1161.43 | 98.13 (1.48) | 650.10 | 1301.54 | 100.15 (1.45) | 780.12 | 1434.82 | 101.40 (1.08) |
| (11) HDCA | 1.0 | 21.62 | 16.72 | 38.43 | 96.33 (0.85) | 21.12 | 42.71 | 98.73 (1.42) | 24.64 | 46.08 | 99.17 (0.44) |
| (12) CDCA | 1.0 | 127.84 | 101.40 | 228.02 | 99.17 (0.78) | 126.75 | 253.71 | 97.60 (1.06) | 152.10 | 279.73 | 101.07 (1.50) |
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