Research Article

Electrodeposition of 4-Benzenesulfonic Acid onto a Graphite-Epoxy Composite Electrode for the Enhanced Voltammetric Determination of Caffeine in Beverages

Table 1

Charge transfer resistance and capacitance obtained by adjusting the spectra using equivalent circuit (Figure 3) for experiments carried out in absence and presence of caffeine at 2.0 mmol·L−1 for all electrodes.

OCP
Rct (Ω·cm2)Cdl (nF·cm−2)Rct (Ω·cm2)Cdl (nF·cm−2)

Bare104114.944325.1
42926.1381.029.4
EL141829.146426.2
41021.341032.3
EL294010.950520.3
39528.437030.3
EL380623.188119.3
83024.382920.5
EL437527.445326.8
38529.137135.6