Simultaneous Determination of Ternary Mixture of Carboxin, Chlorpyrifos, and Tebuconazole Residues in Cabbage Samples Using Three Spectrophotometric Methods

Table 6

Comparison of the published methods with the proposed methods for determination of carboxin, chlorpyrifos, and tebuconazole in real samples.

Analyte	Method	Linear range (μg/mL)	LOD (μg/mL)	LOQ (μg/mL)	%Recovery	%RSD	Application	Ref
CAR	GC	0.1–10	0.003–0.03	0.1	92–99	5–14	Fruits and vegetables	[5]
	DDRSD	1–30	0.178	0.541	90.70–94.53	2.47–5.28	Cabbage	This study
	SDRS	1–30	0.153–0.206	0.463–0.626	87.02–90.98	3.33–5.90	Cabbage	This study
	MCRS	1–30	0.260	0.790	88.76–92.45	2.18–5.91	Cabbage	This study
CHL	HPLC-DAD	15–60	0.5	1	Higher than 90	Less than 6	Mexican axolotl	[24]
	RSD	1–10	0.201	0.671	80–121	2.9–5.3	Water, soil	[13]
	GC-MS	0.5–50 (μg/kg)	0.01–0.2(μg/kg)	0.05–1(μg/kg)	80–105	0.1–13.37	Apple	[21]
	GC-MS/MS	2–2000 (μg/kg)	0.3 (μg/kg)	1 (μg/kg)	86.2–92.3	Less than 9.5	Duck muscle	[22]
	DDRSD	1–50	0.137–0.227	0.416–0.688	93.99–103.89	2.03–5.99	Cabbage	This study
	SDRS	1–50	0.228–0.272	0.691–0.824	92.32–108.53	1.44–5.98	Cabbage	This study
	MCRS	1–50	0.159	0.483	95.07–103.82	2.67–3.14	Cabbage	This study
TEB	GC-FID	1–1000	0.5	2	98.5–100.8	Less than 2	Formulation	[29]
	GC-MS	0.01–1	0.015	0.05	88.9–97.1	1.7–4.0	Gherkin fruits, soil	[30]
	GC-MS	0.01–1	0.003	0.01	88.2–105	1.52–7.65	Watermelon, soil	[31]
	DDRSD	1–45	0.109	0.332	88.95–93.59	3.32–5.53	Cabbage	This study
	SDRS	1–45	0.121–0.127	0.367–0.385	87.19–98.00	2.67–4.93	Cabbage	This study
	MCRS	1–45	0.205	0.621	91.10–96.95	1.57–2.36	Cabbage	This study

GC: gas chromatography. HPLC-DAD: high-performance liquid chromatography with diode array detection. RSD: ratio spectra derivative. GC-MS: gas chromatography-mass spectrometry. GC-MS/MS: gas chromatography tandem mass spectrometry. GC-FID: gas chromatography-flame ionization detector. DDRSD: double divisor-ratio spectra derivative. SDRS: successive derivative of ratio spectra. MCRS: mean centering of ratio spectra.