No. Rt Formula [M + HCOO]− (m /z ) [M-H]− (m /z ) Fragment ions (m /z ) CMP Compound name Reference 1 3.42 C42 H72 O15 861.4843 815.4784 653.4254, 491.2235, 463.0880 √ Notoginsenoside M [23 ] 2 3.62 C27 H30 O16 609.1816 300.0555 √ Rutin [24 ] 3 3.72 C8 H8 O5 183.0308 124.0211 √ Methyl gallate [25 ] 4 4.22 C48 H82 O19 1007.5439 961.5380 997.5126, 799.4825, 637.4305, 475.1966 √ Notoginsenoside R3/R6/20-O-Glucoginsenoside Rf [23 ] 5 4.28 C40 H70 O8 723.5082 677.5007 740.4865, 475.1963, 417.1550, 284.0329 Unknown 6 4.47 C43 H83 O12 836.5914 790.5905 853.5441 Unknown 7 4.55 C48 H82 O19 1007.5439 961.5406 997.5145, 799.4846, 637.4318, 475.3790 √ Notoginsenoside R3/R6/20-O-Glucoginsenoside Rf [23 ] 8 4.57 C32 H38 O15 707.2444 661.2957 1323.5775, 724.2191, 499.1783 Baohuoside A ∆ 9 4.61 C47 H80 O18 977.5385 931.5317 799.4850, 637.4321, 475.3785 √ Notoginsenoside R1 [26 ] 10 4.81 C48 H82 O18 991.5449 945.5477 799.4883, 637.4339, 619.4214, 475.3792 √ Ginsenoside Re [27 ] 11 4.85 C42 H72 O14 845.4936 799.4833 637.4339, 475.3792 √ Ginsenoside Rg1 [27 ] 12 5.24 C39 H50 O20 883.2853 837.2800 675.2280, 529.2005, 513.1791, 367.1183 Epimedin A1 ∆ 13 5.29 C15 H10 O7 301.0683 273.0429, 245.0488, 229.0532, 179.0065, 151.0179, 121.0346 Quercetin ∆ 14 5.31 C38 H48 O19 807.2960 645.2173, 513.1818, 366.1090 Epimedin B ∆ 15 5.38 C38 H50 O19 867.2896 821.2642 659.2647, 513.1761, 366.1201, 351.0912, 323.0849, 151.0094, 106.6611 Epimedin C ∆ 16 5.40 C38 H50 O19 867.3390 821.2833 659.2668, 366.1226 Epimedin A ∆ 17 5.53 C27 H30 O10 513.1833 367.1188, 351.0876, 323.0917, 151.0109, 145.0312 Isomer(47) ∆ 18 5.53 C33 H40 O15 721.2323 675.2302 529.1712, 513.1846, 367.1266 Icariin ∆ 19 5.64 C48 H82 O19 1007.5430 961.5372 799.4822, 637.3738 √ Notoginsenoside N/R6 [28 ] 20 5.67 C54 H92 O23 1153.6027 1107.5963 945.5418, 799.4827, 637.4309, 475.1394, Ginsenoside Re8 [29 ] 21 5.90 C59 H100 O27 1285.6840 1239.6516 1107.5920, 945.5372, 783.4835, 621.4189, 459.3343 √ Notoginsenoside Fa ∆ 22 6.09 C42 H72 O14 845.4875 799.4935 637.4294, 619.5074, 475.3772 √ Ginsenoside Rf [28 ] 23 6.11 C54 H92 O23 1153.6823 1107.6227 945.5391, 783.4855, 621.4235, 459.3650 √ Ginsenoside Rb1 [30 ] 24 6.21 C52 H86 O21 1091.5645 1045.7167 913.5291, 751.4626, 605.4065, 473.3609, √ Gypenoside XLIX ∆ 25 6.26 C53 H90 O22 1123.5693 1077.6210 945.5375, 783.4875 √ Ginsenoside Rc [30 ] 26 6.28 C41 H70 O13 815.4929 769.4709 637.4373, 619.4420, 475.3855 √ 20(S)-Notoginsenoside R2 ∆ 27 6.33 C41 H70 O13 815.4812 769.4928 637.4339, 475.3815 √ Notoginsenoside R2/F3/F5 [28 ] 28 6.40 C63 H106 O30 1341.5354 1209.6248, 1077.5825, 945.5411, 783.4882, 621.4359, 459.3843 √ Notoginsenoside Q [28 ] 29 6.41 C48 H76 O19 955.4913 793.4395, 569.3852 √ Ginsenoside rRo [31 ] 30 6.42 C53 H90 O22 1123.5911 1077.5951 945.5395, 783.4940, 621.4150, 459.3434 √ Ginsenoside Rb2 [28 ] 31 6.44 C53 H90 O22 1123.5911 1077.5911 945.5429, 783.4907, 459.3839 √ Ginsenoside Rb3 [28 ] 32 6.46 C42 H72 O13 829.5134 783.5062 637.4319, 619.4190, 475.3806 √ 20(S)-Ginsenoside Rg2 [30 ] 33 6.50 C41 H70 O13 815.4929 769.4709 637.4373, 619.4420, 475.3855 20(R)-Notoginsenoside R2 ∆ 34 6.56 C36 H62 O9 683.4399 637.4317 475.3788 20(S)-Ginsenoside Rh1/20(R)-Ginsenoside Rh1 [28 ] 35 6.56 C42 H72 O13 829.4958 783.4899 637.4317, 475.3788 √ 20(R)-Ginsenoside Rg2 [30 ] 36 6.59 C56 H94 O24 1195.6116 1149.6077 1107.5959, 945.5424, 783.4896, 637.4297, 475.3786 √ Yesanchinoside F [32 ] 37 6.85 C48 H82 O18 991.5511 945.5786 783.4921, 621.4363, 459.3667 √ Ginsenoside Rd [28 ] 38 6.98 C51 H100 O30 1237.6125 1191.6177 1029.5610, 915.5285, 637.4301, 475.3689 Unknown 39 7.21 C52 H86 O21 943.5059 897.5676 765.4807, 751.4272, 681.4173, 619.3864, 487.3429 √ Gypenoside A ∆ 40 7.26 C55 H92 O23 1165.6019 1119.5986 783.4898, 621.4372, 459.3844 √ Ginsenoside Rs2 [28 ] 41 7.44 C27 H30 O11 575.3054 529.1713 1105.6187, 1059.6130, 367.1176 Icariside I 42 7.49 C47 H80 O17 961.5392 915.5334 783.4893, 621.4371 Notoginsenoside Fe/gynosaponin I/vinaginsenoside R16/R17 [28 ] 43 7.61 C60 H116 O36 1457.7361 1411.7128 1265.6560, 1133.6172, 987.5623, 841.4951, 475.3750 Unknown 44 7.62 C48 H82 O18 991.5460 945.5498 799.4841, 637.4338, 619.4188, 475.3750 Unknown 45 7.63 C51 H86 O21 1033.6028 987.5575 945.5498, 927.5349, 841.4951 √ Pseudoginsenoside Rc1 [28 ] 46 7.81 C55 H92 O23 1165.6125 1119.6310 1077.5851, 1059.5736, 945.5401, 927.5275, 765.4456, 621.3965, 459.2525 √ Ginsenoside Rs1 [28 ] 47 7.82 C27 H30 O10 513.1867 366.1149, 351.0916, 323.0886, 151.0092, 132.0236 Baohuoside I ∆ 48 7.82 C50 H98 O29 1207.6355 1161.6063 1175.6207, 1161.6063 Unknown 49 7.85 C41 H70 O14 831.4783 785.4698 653.4258 Notoginsenoside Rw2 [33 ] 50 7.89 C54 H86 O24 1163.6464 1117.6188 1057.5961, 971.5587, 929.5478 Hemsloside G2/ginsenoside ROA [34 ] 51 8.05 C42 H70 O12 811.4849 765.4782 619.4163, 457.2605 Ginsenoside Rg6 ∆ 52 8.14 C52 H104 O30 1253.6549 1207.6088 1207.6088, 1075.5676, 943.5283 Unknown 53 8.16 C42 H72 O13 829.4985 783.4911 637.4318, 475.3790 √ Ginsenoside Fc [28 ] 54 8.17 C51 H86 O21 1033.5596 987.5541 945.5425 927.5313, 783.4911, 765.4796, 621.4370, 459.3835 √ Quinquenoside III [28 ] 55 8.18 C42 H72 O14 845.4895 799.4831 637.4308, 619.4199, 475.3775 Isomer(22) [28 ] 56 8.42 C48 H82 O16 959.5573 913.5543 767.4940, 621.4166, 475.3465, 146.9997 Gynosaponin II [35 ] 57 8.50 C56 H94 O24 1149.6082 1107.7029, 945.5416, 927.5334, 783.4859, 765.3539, 621.4349, 459.3838 √ Quinquenoside R1 [28 ] 58 8.72 C42 H72 O13 829.4963 783.4920 767.4591, 621.4376, 459.3846 √ 20(S)-Ginsenoside Rg3 [23 ] 59 8.77 C42 H72 O13 829.4974 783.4915 765.4796, 621.4368, 459.3842 √ Isomer(58) [23 ] 60 8.86 C42 H72 O13 829.5020 783.4990 621.4348, 459.3762, 161.0500 √ 20(R)-Ginsenoside Rg3 [23 ] 61 9.39 C36 H62 O9 683.4375 637.4319 475.3790 20(S)-Ginsenoside Rh1/20(R)-Ginsenoside Rh1 [28 ] 62 9.54 C47 H80 O18 977.4802 931.5010 799.4818, 769.4988, 751.4977, 637.3975 Isomer(9) [28 ] 63 9.59 C49 H80 O18 1001.5699 955.5613 913.5525, 767.4947 Gylongiposide I [36 ] 64 9.60 C47 H80 O17 961.5573 915.5556 783.4860, 621.4335, 459.3809 Notoginsenoside Fe/gynosaponin I/vinaginsenoside R16/R17 [28 ] 65 10.22 C42 H70 O12 811.4861 765.4803 619.4220, 603.4269, 457.2275 Ginsenoside Rg6 [28 ] 66 10.26 C42 H72 O13 829.4875 783.4943 621.4368, 459.3837 √ Ginsenoside F2 [28 ] 67 10.36 C42 H70 O12 811.4857 765.4805 619.4229, 603.4269, 457.2340 Ginsenoside F4 [28 ] 68 10.38 C42 H70 O12 811.4849 765.4792 603.3373 Ginsenoside Rg5 [28 ] 69 10.40 C42 H70 O12 811.4850 765.4794 603.3384, 483.2727 Ginsenoside Rk1 [28 ] 70 15.05 C47 H80 O17 961.6223 915.5983 978.5970, 783.5145, 621.3875, 459.3448 √ Notoginsenoside Fe/gynosaponin I/vinaginsenoside R16/R17 [28 ]