| Peak no. | tR (min) | Formula | MS | MS/MSc | Identification | Types of compounds | Reference | Measured | Theoretical | Error (ppm) |
| 1 | 15.330 | C16H22O10 | 409.0910a | 409.0907 | 0.7 | 193.0510, 373.1151, 167.0721, 149.0610, 89.0316, 211.0601, 161.0742, 179.0558, 123.0463, 409.0873, 143.0383 | Gardenoside | Iridoids | [30, 36, 37] | 2 | 17.542 | C16H24O11 | 391.1249b | 391.1246 | 0.8 | 391.1272, 185.0840, 167.0716, 229.0746, 119.0328, 89.0251, 211.0643, 149.0615, 179.0578, 123.0711 | Shanzhisided | Iridoids | | 427.1017a | 427.1013 | 1.0 | 391.1273, 89.0261, 167.0721, 185.0825, 229.0728 | |
| 3 | 18.098 | C16H22O10 | 409.0911a | 409.0907 | 1.0 | 373.1163, 149.0619, 211.0617, 167.0718, 123.0466, 119.0355, 409.0875, 89.0252, 193.0534 | Geniposidic acidd | Iridoids | | 4 | 19.248 | C17H24O11 | 439.1023a | 439.1013 | 2.4 | 439.1033, 241.0684, 101.0240 | DAAMEd | Iridoids | | 5 | 21.181 | C17H24O11 | 439.1023a | 439.1013 | 2.4 | 439.1088, 241.0733, 403.1295 | Gardenosided | Iridoids | | 6 | 21.668 | C16H26O8 | 345.1562b | 345.1555 | 2.1 | 165.0915, 89.0249, 119.0343, 101.0267 | Jasminoside D | Monocyclic monoterpenoids | [37] | 381.1333a | 381.1322 | 3.0 | 165.0935, 345.1577, 89.0264, 179.0570, 119.0368, 101.0260, 121.1039 |
| 7 | 22.668 | C16H24O9 | 395.1114a | 395.1114 | -0.1 | 359.1353, 197.0822 | Ixoroside | Iridoids | [37] | 8 | 23.743 | C17H24O11 | 439.1025a | 439.1013 | 2.8 | 439.1056, 403.1332, 241.0704 | SMEd | Iridoids | | 9 | 26.666 | C16H26O8 | 381.1332a | 381.1322 | 2.7 | 381.1332 | Jasminoside Bd | Monocyclic monoterpenoids | | 10 | 30.424 | C16H18O9 | 389.0648a | 389.0645 | 0.5 | 191.0564, 353.0885 | Chlorogenic acidd | Organic acids | | 11 | 31.971 | C23H34O15 | 585.1619a | 585.1592 | 4.7 | 585.1644, 225.0778, 549.1867, 123.0462, 101.0257, 207.0671 | Genipin gentiobiosided | Iridoids | | 12 | 36.838 | C17H24O10 | 423.1076a | 423.1063 | 3.0 | 423.1095, 225.0760, 387.1288 | Geniposided | Iridoids | | 13 | 42.163 | C16H26O7 | 365.1387a | 365.1373 | 4.0 | 365.1405 | Jasminoside A | Monocyclic monoterpenoids | [37] | 14 | 43.103 | C16H26O7 | 365.1386a | 365.1373 | 3.7 | 365.1385 | Jasminoside E | Monocyclic monoterpenoids | [37] | 15 | 53.572 | C27H30O16 | 609.1482b | 609.1461 | 3.4 | 609.1525, 301.0359 | Rutind | Flavonoids | | 645.1250a | 645.1228 | 3.4 | 609.1501, 301.0366 |
| 16 | 55.917 | C27H34O15 | 597.1855b | 597.1825 | 5.0 | 597.1923, 391.1285, 223.0633, 185.0825, 205.0521, 167.0717, 229.0734 | 6′-Trans-sinapoyl shanzhiside | Iridoids | | 633.1619a | 633.1592 | 4.3 | 597.1881, 391.1260, 205.0511 |
| 17 | 56.908 | C27H32O14 | 615.1511a | 615.1486 | 4.1 | 579.1770, 325.0927, 367.1043, 223.0612, 385.1151, 193.0505, 205.0506, 123.0451 | 6′-Trans-sinapoyl gardoside | Iridoids | [37] | 18 | 59.556 | C25H24O12 | 515.1215b | 515.1195 | 3.9 | 353.0910, 191.0579, 515.1277, 179.0348, 173.0443, 161.0227, 135.04738, 155.0361 | 3,4-Dicaffeoylquinic acid | Organic acids | [30, 37] | 19 | 61.039 | C32H40O17 | 695.2208b | 695.2193 | 2.2 | 695.2261, 469.1387, 163.0391, 145.0249, 123.0456, 367.1069, 225.0764, 663.2029,101.0252 | 6″-O-Trans-coumaroyl genipin gentiobioside | Iridoids | [36, 37] | 20 | 61.814 | C44H64O24 | 1011.3519a | 1011.3482 | 3.7 | 1011.3585, 651.2726, 327.1621, 975.3809, 283.1722 | Crocin Id | Crocins | | 21 | 63.359 | C31H32O16 | 659.1647b | 659.1618 | 4.5 | 497.1325, 659.1672, 335.0767, 191.0555, 353.0892, 161.0458 | 3,4-Di-O-caffeoyl-5-O-(3-hydroxy-3-methylglutaroyl) quinic acid | Organic acids | [30, 37] | 22 | 63.534 | C27H36O12 | 587.1926a | 587.1901 | 4.3 | 521.2075, 533.2077, 551.2697, 551.2697, 205.0517, 367.1050, 223.0621, 587.1956, 165.0928, 179.0727, 385.1160 | 6′-O-Trans-sinapoyl jasminoside L | Monocyclic monoterpenoids | [37] | 23 | 64.290 | C21H34O11 | 497.1810a | 497.1795 | 3.0 | 497.1855, 461.2069, 167.1092, 329.0637, 293.0889 | Jasminoside T | Monocyclic monoterpenoids | [37] | 24 | 64.985 | C28H34O14 | 593.1895b | 593.1876 | 3.2 | 593.1943, 205.0518, 223.0649, 225.0781, 367.1057, 207.0645, 123.0466, 101.0236 | 6′-O-Trans-sinapoyl geniposide | Iridoids | [36, 37] | 629.1668a | 629.1643 | 4.0 | 593.1936, 205.0511, 225.0773, 223.0627, 123.0457 | 25 | 65.278 | C38H54O19 | 849.2978a | 849.2953 | 2.9 | 327.1615, 283.1723, 651.2701, 239.1815, 849.3028, 489.2166 | Crocin IId | Crocins | | 26 | 71.292 | C27H36O11 | 571.1957a | 571.1952 | 0.9 | 535.2258, 325.0947, 265.0740, 223.0627, 205.0521, 385.1184, 221.0848 | 6′-O-Trans-sinapoyl jasminoside A | Monocyclic monoterpenoids | [37] | 27 | 75.160 | C44H64O24 | 1011.3509a | 1011.3482 | 2.7 | 1011.3556, 651.2711, 327.1611, 975.3767 | 13-cis-Crocin II | Crocins | [37] | 28 | 75.958 | C32H44O14 | 687.2437a | 687.2425 | 1.7 | 327.1608, 651.2707, 283.1704, 687.2467, 239.1814, 323.0971, 179.0566 | Crocin II | Crocins | [37] |
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