|
No. | Identity | Formula | Rt | Theoretical value | Actual value | Ppm | Main MS/MS fragments detected | Saponin type | Ref. |
|
1 | Ginsenoside Re | C48H82O18 | 6.47 | 991.5478 [M + HCOO]− | 991.5468 [M + HCOO]− | −1.01 | 945.5403 [M-H]− 799.4841 [M-H-Rha]− 783.4899 [M-H-Glc]− 637.4333 [M-H-Glc-Rha]− 475.3792 [M-H-2Glc-Rha]− | PPT | [28] |
|
2 | Gypenoside X VII | C48H82O18 | 6.50 | 991.5478 [M + HCOO]− | 991.5472 [M + HCOO]− | −0.61 | 945.5408 [M-H]− 783.4871 [M-H-Glc]− 621.4116 [M-H-2Glc]− 459.7427 [M-H-3Glc]− 161.0451 [Glc-H]− | PPD | [28] |
|
3 | Malonyl-ginsenoside Rc | C56H92O25 | 6.87 | 1209.5904 [M + HCOO]− | 1209.5897 [M + HCOO]− | −0.58 | 1119.4801 [M-H-CO2]− 1077.7046 [M-H-Mal]− 1077.7046 [M-H-Mal]− 783.4866 [M-H-Mal-Xyl-Glc]− | PPD | [28] |
|
4 | Ginsenoside Rg1 | C42H72O14 | 6.93 | 845.4899 [M + HCOO]− | 845.4886 [M + HCOO]− | −1.54 | 799.4836 [M-H]− 637.4357 [M-H-Glc]− 475.3795 [M-H-2Glc]− | PPT | [28] |
|
5 | Acetyl-ginsenoside Rg1 | C44H74O15 | 7.31 | 887.5004 [M + HCOO]− | 887.4990 [M + HCOO]− | −1.58 | 841.4931 [M-H]− 799.4761 [M-H-Ac]− 781.4734 [M-H-Ac-H2O]− 679.4437 [M-H-Glc]− 637.4263 [M-H-Ac-Glc]− 619.4208 [M-H-Ac-Glc-H2O]− 475.3736 [M-H-Ac-2Glc]− | PPT | [28, 31, 32] |
|
6 | Vina-ginsenoside R1 | C44H74O15 | 7.32 | 887.5004 [M + HCOO]− | 887.4999 [M + HCOO]− | −0.56 | 799.4686 [M-H-Ac]− 653.3508 [M-H-Ac-Rha]− 491.3585 [M-H-Ac-Rha-Glc]− | OCO | [28] |
|
7 | Pseudoginsenoside RC1 | C50H84O19 | 7.35 | 1033.5583 [M + HCOO]− | 1033.5575 [M + HCOO]− | −0.77 | 987.5534 [M-H]− 945.5455 [M-H-Ac]− 783.4812 [M-H-Ac-Glc]− 621.4262 [M-H-Ac-2Glc]− 459.1374 [M-H-Ac-Glc]− 161.0461 [Glc-H]− | PPD | [28] |
|
8 | Pseudoginsenoside RT2 | C41H70O14 | 8.13 | 831.4742 [M + HCOO]− | 831.4772 [M + HCOO]− | 3.61 | 785.4709 [M-H]− 653.4288 [M-H-Xyl]− | OCO | [28] |
|
9 | Majonoside R2 | C41H70O14 | 8.14 | 831.4742 [M + HCOO]− | 831.4769 [M + HCOO]− | 3.25 | 785.4690 [M-H]− 653.4274 [M-H-Xyl]− | OCO | [28] |
|
10 | Pseudoginsenoside F11 | C42H72O14 | 8.25 | 845.4899 [M + HCOO]− | 845.4912 [M + HCOO]− | 1.54 | 799.4871 [M-H]− 653.4296 [M-H-Rha]− 491.3707 [M-H-Rha-Glc]− 145.0475 [Rha-H]− | OCO | [28, 33, 34] |
|
11 | Malonyl-ginsenoside Rb1 | C57H94O26 | 8.39 | 1193.5955 [M-H]− | 1193.5978 [M-H]− | 1.93 | 1149.6088 [M-H-CO2]− 1107.5940 [M-H-Mal]− 945.5502 [M-H-Mal-Glc]− 783.4980 [M-H-Mal-2Glc]− 621.4172 [M-H-Mal-3Glc]− 459.3224 [M-H-Mal-4Glc]− | PPD | [28] |
|
12 | Malonyl-ginsenoside Rb2 | C56H92O25 | 8.60 | 1163.5849 [M-H]− | 1163.5861 [M-H]− | 1.03 | 1119.4962 [M-H-CO2]− 1077.5817 [M-H-Mal]− 945.5414 [M-H-Mal-Xyl]− 783.4878 [M-H-Mal-Xyl-Glc]− 621.4401 [M-H-Mal-Xyl-2Glc]− 459.2655 [M-H-Mal-Xyl-3Glc]− | PPD | [28] |
|
13 | Ginsenoside Ro | C48H76O19 | 8.65 | 955.4903 [M-H]− | 955.4913 [M-H]− | 1.05 | 955.4924 [M-H]− 793.4407 [M-H-Glc]− 569.3823 [M-H-CO2-H2O-2Glc]− 455.3648 [M-H-2Glc-GlcUA]− | OLE | [28] |
|
14 | Malonyl-ginsenoside Rb3 | C56H92O25 | 8.85 | 1163.5849 [M-H]− | 1163.5825 [M-H]− | −2.06 | 1077.5806 [M-H-Mal]− 945.5403 [M-H-Mal-Xyl]− 783.4883 [M-H-Mal-Xyl-Glc]− 621.4357 [M-H-Mal-Xyl-2Glc]− 459.3861 [M-H-Mal-Xyl-3Glc]− | PPD | [28] |
|
15 | Zingibroside R1 | C42H66O14 | 9.25 | 793.4374 [M-H]− | 793.4337 [M-H]− | −4.66 | 793.4332 [M-H]− 631.3823 [M-H-Glc]− 569.3790 [M-H-Glc-CO2-H2O]− 455.3538 [M-H-Glc-GlcUA]− | OLE | [28] |
|
16 | Ginsenoside Rd | C48H82O18 | 9.52 | 991.5478 [M + HCOO]− | 991.5460 [M + HCOO]− | −1.82 | 945.5386 [M-H]− 783.4875 [M-H-Glc]− 621.4283 [M-H-2Glc]− 459.3574 [M-H-3Glc]− | PPD | [28] |
|
17 | Quinquefolium III | C50H84O19 | 10.04 | 1033.5583 [M + HCOO]− | 1033.5500 [M + HCOO]− | −8.03 | 945.5333 [M-H-Ac]− 783.4835 [M-H-Ac-Glc]− 621.4166 [M-H-Ac-2Glc]− 459.3737 [M-H-Ac-3Glc]− 161.0451 [Glc-H]− | PPD | [28] |
|
18 | Malonyl-ginsenoside Rd | C50H84O19 | 10.41 | 1033.5583 [M + HCOO]− | 1033.5500 [M + HCOO]− | −8.03 | 987.5585 [M-H]− 945.5641 [M-H-Ac]− 783.4999 [M-H-Ac-Glc]− 621.4255 [M-H-Ac-2Glc]− | PPD | [28] |
|
19 | Quinquefolium I | C52H86O19 | 10.70 | 1059.5740 [M + HCOO]− | 1059.5701 [M + HCOO]− | −3.68 | 945.5345 [M-H-C4H4O]− 783.4911 [M-H-C4H4O-Glc]− 621.4280 [M-H-C4H4O-2Glc]− 161.0440 [Glc-H]− | PPD | [28, 29] |
|
20 | Ginsenoside Rg5/ginsenoside Rg6/ginsenoside Rk1/ginsenoside Rg4 | C42H70O12 | 10.91 | 811.4844 [M + HCOO]− | 811.4832 [M + HCOO]− | −1.48 | 765.4765 [M-H]− 619.4148 [M-H-Rha]− 603.2623 [M-H-Glc]− 457.2162 [M-H-Rha-Glc]− 161.0476 [Glc-H]− | PPD | [28] |
|
21 | Ginsenoside Rg2 | C42H72O13 | 10.95 | 829.4949 [M + HCOO]− | 829.4896 [M + HCOO]− | −6.39 | 783.4891 [M-H]− 621.4318 [M-H-Glc]− 459.3699 [M-H-2Glc]− | PPT | [28] |
|
22 | Chikusetsusaponin IVa | C42H66O14 | 11.02 | 793.4374 [M-H]− | 793.4336 [M-H]− | −4.79 | 793.4336 [M-H]− 631.3883 [M-H-Glc]− 569.3820 [M-H-Glc-CO2-H2O]− 455.3252 [M-H-Glc-GlcUA]− | OLE | [28] |
|
23 | Ginsenoside Rg3/ginsenoside F2 | C42H72O13 | 11.62 | 829.4949 [M + HCOO]− | 829.4918 [M + HCOO]− | −3.74 | 783.4839 [M-H]− 637.6862 [M-H-Rha]− | PPD | [28] |
|