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No. | Identity | Formula | Rt | Theoretical value | Actual value | Ppm | Main MS/MS fragments detected | Saponin type | Ref. |
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1 | Notoginsenoside N/M/R6/R3/20-glc-ginsenoside-Rf | C48H82O19 | 6.08 | 1007.5427 [M + HCOO]− | 1007.5358 [M + HCOO]− | −6.85 | 799.4779 [M-H-Glc]− 637.4254 [M-H-2Glc]− | PPT | [31] |
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2 | Ginsenoside Re1/Re2/Re3 | C48H82O19 | 6.10 | 1007.5427 [M + HCOO]− | 1007.5357 [M + HCOO]− | −6.95 | 799.4781 [M-H-Glc]− 637.4270 [M-H-2Glc]− | PPT | [31, 32] |
|
3 | Vina-ginsenoside R7 | C53H90O22 | 6.13 | 1123.5900 [M + HCOO]− | 1123.5768 [M + HCOO]− | −1.75 | 1077.5750 [M-H]− 945.5393 [M-H-Xyl]− 621.2886 [M-H-Xyl-2Glc]− | PPD | [31, 32] |
|
4 | Ginsenoside Rb3/ginsenoside Rc | C53H90O22 | 6.14 | 1123.5900 [M + HCOO]− | 1123.5845 [M + HCOO]− | −4.90 | 945.5501 [M-H-Xyl/Ara]− 783.4982 [M-H-Xyl/Ara-Glc]− 765.4770 [M-H-Xyl/Ara-Glc-H2O]− 621.3179 [M-H-Xyl/Ara-2Glc]− | PPD | [31] |
|
5 | Notoginsenoside R1/ginsenoside Re4/quinquenoside L17 | C47H80O18 | 6.23 | 977.5321 [M + HCOO]− | 977.5490 [M + HCOO]− | 17.29 | 931.5217 [M-H]− 799.4762 [M-H-Xyl]− 637.4242 [M-H-Xyl-Glc]− 475.3714 [M-H-Xyl-2Glc]− | PPT | [31] |
|
6 | Yesanchinoside B | C48H82O20 | 6.23 | 977.5321 [M-H]− | 977.5203 [M-H]− | −12.07 | 977.5415 [M-H]− 653.3294 [M-H-2Glc]− | OCO | [31, 32] |
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7 | Ginsenoside Re | C48H82O18 | 6.48 | 991.5478 [M + HCOO]− | 991.5399 [M + HCOO]− | −7.97 | 945.5347 [M-H]− 799.4775 [M-H-Rha]− 783.4836 [M-H-Glc]− 637.4283 [M-H-Rha-Glc]- 475.3784 [M-H-2Glc-Rha]− | PPT | [31, 32] |
|
8 | Notoginsenoside K | C48H82O18 | 6.50 | 991.5478 [M + HCOO]− | 991.5387 [M + HCOO]− | −9.18 | 945.5326 [M-H]− 783.4836 [M-H-Glc]− | PPD | [31, 32] |
|
9 | Ginsenoside Rg1 | C42H72O14 | 6.53 | 845.4899 [M + HCOO]− | 845.4824 [M + HCOO]− | −8.87 | 799.4767 [M-H]− 637.4272 [M-H-Glc]− 475.3758 [M-H-2Glc]− | PPT | [31, 32] |
|
10 | Majonoside R1 | C42H72O14 | 7.77 | 861.4848 [M + HCOO]− | 861.4969 [M + HCOO]− | 14.05 | 815.4773 [M-H]− 653.4257 [M-H-Glc]− 491.3711 [M-H-2Glc]− | OCO | [31, 32] |
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11 | Ginsenoside Rf | C42H72O14 | 8.15 | 845.4899 [M + HCOO]− | 845.4889 [M + HCOO]− | −1.18 | 799.4830 [M-H]− 637.4339 [M-H-Glc]− 475.3769 [M-H-2Glc]− | PPT | [31, 32] |
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12 | Tuberoside A | C48H76O19 | 8.23 | 955.4903 [M-H]− | 955.4896 [M-H]− | −0.73 | 793.4327 [M-H-Glc]− 569.3922 [M-H-CO2-H2O-2Glc]− | OLE | [31, 32] |
|
13 | Pseudoginsenoside F11 | C42H72O14 | 8.24 | 845.4899 [M + HCOO]− | 845.4893 [M + HCOO]− | −0.71 | 799.4825 [M-H]− 653.4245 [M-H-Rha]− | OCO | [32] |
|
14 | Ginsenoside Ro | C48H76O19 | 8.66 | 955.4903 [M-H]− | 955.4905 [M-H]− | 0.21 | 793.4402 [M-H-Glc]− 613.3748 [M-H-H2O-2Glc]− 569.3944 [M-H-2Glc-H2O-CO2]− 455.3560 [M-H-2Glc-GlcUA]− | OLE | [31, 32] |
|
15 | Hemsgiganoside B | C48H76O19 | 8.75 | 955.4903 [M-H]− | 955.4906 [M-H]− | 0.31 | 793.4359 [M-H-Glc]− 569.3929 [M-H-2Glc-H2O-CO2]− | OLE | [31, 32] |
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16 | Stipuleanoside R1/chikusetsusaponin Ib | C47H74O18 | 8.92 | 925.4797 [M-H]− | 925.4800 [M-H]− | 0.32 | 763.3628 [M-H-Glc]− 569.3837 [M-H-Glc-Ara-H2O-CO2]− | OLE | [31, 32] |
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17 | Pseudoginsenoside RT1 | C47H74O18 | 8.94 | 925.4797 [M-H]− | 925.4786 [M-H]− | −1.19 | 763.4263 [M-H-Glc]− 613.3727 [M-H-Glc-Xyl-H2O]− 569.3864 [M-H-Glc-Xyl-H2O-CO2]− | OLE | [31, 32] |
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18 | Chikusetsusaponin IV | C47H74O18 | 9.04 | 925.4797 [M-H]− | 925.4793 [M-H]− | −0.43 | 613.3701 [M-H-Glc-Ara-H2O]− 569.3853 [M-H-Glc-Ara-H2O-CO2]− | OLE | [31, 32] |
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19 | Zingibroside R1 | C42H66O14 | 9.28 | 793.4374 [M-H]− | 793.4355 [M-H]− | −2.39 | 793.4355 [M-H]− 631.3818 [M-H-Glc]− 569.3826 [M-H-Glc-CO2-H2O]− 455.3538 [M-H-Glc-GlcUA]− | OLE | [31, 32] |
|
20 | Ginsenoside Rd | C48H82O18 | 9.65 | 991.5478 [M + HCOO]− | 991.5479 [M + HCOO]− | 0.10 | 945.5435 [M-H]− 783.4866 [M-H-Glc]− 621.4390 [M-H-2Glc]− 459.3862 [M-H-3Glc]− 161.0467 [Glc-H]− | PPD | [31, 32] |
|
21 | Ginsenoside Rg3/ginsenoside F2 | C42H72O13 | 10.95 | 829.4949 [M + HCOO]− | 829.4946 [M + HCOO]− | −0.36 | 783.4850 [M-H]− 621.4301 [M-H-Glc]− 459.3812 [M-H-2Glc]− | PPD | [31, 32] |
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22 | Chikusetsusaponin IVa | C42H66O14 | 11.03 | 793.4374 [M-H]− | 793.4355 [M-H]− | −2.39 | 793.4348 [M-H]− 631.3970 [M-H-Glc]− 569.3805 [M-H-Glc-CO2-H2O]− | OLE | [31, 32] |
|
23 | Cynarasaponin C | C42H66O14 | 11.05 | 793.4374 [M-H]− | 793.4331 [M-H]− | −5.42 | 793.4328 [M-H]− 631.3818 [M-H-Glc]− 569.3826 [M-H-Glc-CO2-H2O]− | OLE | [31, 32] |
|
24 | Ginsenoside Rg5 | C42H70O12 | 11.61 | 811.4844 [M + HCOO]− | 811.4778 [M + HCOO]− | −8.13 | 765.4724 [M-H]− 603.4313 [M-H-Glc]− | PPD | [31, 32] |
|
25 | Pseudoginsenoside Rp1 | C41H64O13 | 11.77 | 763.4269 [M-H]− | 763.4222 [M-H]− | −6.16 | 613.3658 [M-H-Xyl-H2O]− 569.3800 [M-H-Xyl-H2O-CO2]− | OLE | [31, 32] |
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26 | Ginsenoside Rk1 | C42H70O12 | 11.81 | 811.4844 [M + HCOO]− | 811.4800 [M + HCOO]− | −5.42 | 765.4821 [M-H]− 603.4160 [M-H-Glc]− 161.0470 [Glc-H]− | PPD | [31, 32] |
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27 | Oleanolic acid-28-O-β-D-glucopyranose(PJS-1) | C36H58O8 | 12.62 | 663.4108 [M + HCOO]− | 663.4067 [M + HCOO]− | −6.18 | 617.4132 [M-H]− 455.3546 [M-H-Glc]− | OLE | [31, 32] |
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