Journal of Chemistry

Journal of Chemistry / 2004 / Article

Open Access

Volume 1 |Article ID 250809 | https://doi.org/10.1155/2004/250809

K. D. Patel, S. C. Panchani, "Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide", Journal of Chemistry, vol. 1, Article ID 250809, 6 pages, 2004. https://doi.org/10.1155/2004/250809

Coordination Polymers of 4,4'-(8-Quinolinolyl-5-methylenoxy) Diphenyl Sulfide

Received13 Mar 2004
Accepted01 May 2004

Abstract

Coordination polymers containing a novel bis(oxine) bidentate ligand, namely 4,4'-[(8-Quinolinolyl-5-methylenoxy) diphenyl sulfide H2L have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with 4,4'-dihydroxy diphenyl sulfide in the presence of a base catalyst. All of these coordination polymers and the parent ligand were characterized by elemental analyses, and IR spectral and diffuse reflectance spectral studies. The thermal stability and number-average molecular weights (Mn) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities

Copyright © 2004 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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