Journal of Chemistry

Journal of Chemistry / 2004 / Article

Open Access

Volume 1 |Article ID 385034 | https://doi.org/10.1155/2004/385034

K. G. Mallikarjun, "Thermal Decomposition Kinetics of Ni(II) Chelates of Substituted Chalcones", Journal of Chemistry, vol. 1, Article ID 385034, 5 pages, 2004. https://doi.org/10.1155/2004/385034

Thermal Decomposition Kinetics of Ni(II) Chelates of Substituted Chalcones

Received22 Feb 2004
Accepted10 Mar 2004

Abstract

The thermal decomposition of Ni(II) complexes of 3-(phenyl)-1-(2’-hydroxy-naphthyl)-2-propen-1-one (PHPO), 3-(4-chlorophenyl)-1-(2’-hydroxy-naphthyl)-2-propen-1-one(CPHPO), 3-(4-methoxyphenyl)-1-(2’-hydroxynapthyl)-2-propen-1-one (MPHPO), 3-(3,4-dimethoxyphenyl)-1-(2’-hydroxynaphthyl)-2-propen-1-one(DMPHPO) was studied by thermogravimetry. Mathematical analysis of the data has allowed us to determine various parameters using Freeman-Carroll equation, the integral method using the coats-Redfern equation and the approximation method using the Horowitz-Metzger equation. The trend of the kinetic parameters was found to be different from that of the thermal stability order. The low values of Z suggest the slow nature of the reaction.

Copyright © 2004 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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