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E-Journal of Chemistry
Volume 1 (2004), Issue 2, Pages 110-114
http://dx.doi.org/10.1155/2004/405086

Synthesis and Characterization of Some Trivalent and Tetravalent Derivatives of 2- Hydroxy-1-naphthoic Acid

Deepti Joshi1 and T. K. Joshi2

1Chemical Laboratories, DSB Campus, Kumaun University, Nainital-263002, Uttranchal, India
2Chemistry Department.CBS&H, G.B.Pant.University of Agriculture and Technology, Pantnagar, India

Received 22 February 2004; Accepted 10 March 2004

Copyright © 2004 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The trivalent derivatives (B, Al, As, Sb & Fe) and tetravalent derivatives (Si, Ti & Se) of 2-hydroxy-1-naphthoic acid have been prepared by the interaction of their corresponding isopropoxide with letter in different molar ratio viz. 1:3 &1:4 in benzene medium. The prepared compounds generally obtained as coloured solids and amongst them those containing isopropoxy groups were found to be hygroscopic. All these compound were characterized by azeotrope and elemental analysis as well as by IR, PMR and mass spectral measurements. These spectral data have facilitated in elucidating the mode of bonding of the said metals and non-metals in these compounds with 2-hydroxy-1-naphthoic acid.