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E-Journal of Chemistry
Volume 5 (2008), S1, Pages S997-S1007
http://dx.doi.org/10.1155/2008/348037

Synthesis of Compounds Containing Fluorine, Vinylsulfone Groups and Transition Metal Complexes and their Applications to Textiles

E. Yildiz and N. Bozok

Department of Chemistry, Arts and Science Faculty, Cukurova University, Balcali-01330, Adana, Turkey

Received 24 December 2007; Revised 10 March 2008; Accepted 5 May 2008

Copyright © 2008 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A ligand which has reactive dye character and its transition metal complexes such as Cu(II), Co(II), Cr(III), Ni(II) containing vinylsulfone and fluorine groups were synthesized. The diazotation reaction has been studied at 0-5°C carefully. Completion of the reaction was monitored by the TLC method. FT-IR, UV, 1H-NMR, TGA and microanalysis methods were used for determination of the synthesized compounds. We assumed that copper complex indicated dimeric structure based on magnetic susceptibility result. All the synthesized compounds which have dye character were applied on cotton, polyamide and nylon fibers. Their dyeing and fastness properties were investigated according to international standards. These properties gave good results for all synthesized dyes except light fastnesses of chromium and nickel complex dyes.