Kodjo Charles Guillaume, Zabri Herve, Benie Anoubile, Estienne Jacques, "Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline", Journal of Chemistry, vol. 6, Article ID 473124, 6 pages, 2009. https://doi.org/10.1155/2009/473124
Preparation, Spectroscopy, Physicochemical Properties and X-ray Structure Analysis of 3,4,5-Trimethoxy N(2-hydroxybenzylidene) aniline
3,4,5-Trimethoxy N-(salicylidene) aniline was synthesized and characterized by IR spectroscopy, 1H NMR and x-ray single crystal analysis. UV-visible spectroscopy was used for physicochemical tests. X-ray data reveals that the crystalline network cohesion of this compound is essentially assured by CH/pi type hydrogen bounds. It crystallized in the orthorhombic Pbcn space group. Electronic spectroscopy shows that the title compound doesn't present photochromic property but thermochromic one. Intermolecular interactions analysis confirms for this compound a thermochromic structural predisposition.
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