Journal of Chemistry

Journal of Chemistry / 2009 / Article

Open Access

Volume 6 |Article ID 634346 | 13 pages | https://doi.org/10.1155/2009/634346

Study on Designing Sulfur Containing Bifunctional Building Block with Improved Refractive Index

Received31 Jul 2008
Revised28 Sep 2008
Accepted10 Nov 2008

Abstract

Sulfur and chlorine containing bifunctional diols with C-S bond has been prepared starting from chloroepoxy alkane and thioalcohol. The studies of FTIR, TLC, HPLC and NMR have been used to understand the reaction mechanism, as well as for optimization of the reaction parameters. The reaction is highly exothermic and the effect of temperature, rate of addition of reagents and reaction time are important factors affecting the formation of diol. Viscosity studies, HPLC, FTIR, NMR and acid number studies have shown that, these parameters could be used as process control parameters for the synthesis of diol. Refractive index of the synthesized diol is found to be higher than that of the reactants used.

Copyright © 2009 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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