Table of Contents Author Guidelines Submit a Manuscript
E-Journal of Chemistry
Volume 6 (2009), Issue 2, Pages 385-394
http://dx.doi.org/10.1155/2009/929816

Corrosion Inhibition of Mild Steel in Hydrochloric Acid by 2-Benzoylpyridine and Pyridoxolhydrochloride

A. O. James,1 N. C. Oforka,1 O. K. Abiola,1 and B. I. Ita2

1Department of Pure and Industrial Chemistry, University of Port Harcourt, P.M.B. 5323, Port Harcourt, Nigeria
2Chemistry Department, University of Calabar, Calabar, Nigeria

Received 1 July 2008; Revised 24 October 2008; Accepted 10 December 2008

Copyright © 2009 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The inhibition of corrosion of mild steel in hydrochloric acid solutions by 2-benzoylpyridine (2BP) and pyridoxolhydrochloride (PXO) at 303K, 313K and 323K has been investigated using weight loss and hydrogen evolution techniques. 2BP exhibited higher maximum inhibition efficiency (78.99%) than PXO (71.93%). Generally inhibition was found to increase with increasing inhibitor concentration and decreasing temperature. A first order type of mechanism has been deduced from the kinetic treatment of the results and the process of inhibition was attributed to physisorption. The difference in the inhibition behaviour of the two compounds has been explained on the basis of structure dependent electron donor properties of the inhibitors