Journal of Chemistry

Journal of Chemistry / 2009 / Article

Open Access

Volume 6 |Article ID 953175 | https://doi.org/10.1155/2009/953175

Abdolkarim Zare, Alireza Hasaninejad, Esmael Rostami, Ahmad Reza Moosavi-Zare, Maria Merajoddin, Azam Arghoon, Nasrin Pishahang, Mohsen Shekouhy, "LiHSO4/SiO2 as a New, Efficient and Reusable Catalytic System for the Chemoselective Conversion of Aldehydes to Acylals under Solvent-Free Conditions", Journal of Chemistry, vol. 6, Article ID 953175, 7 pages, 2009. https://doi.org/10.1155/2009/953175

LiHSO4/SiO2 as a New, Efficient and Reusable Catalytic System for the Chemoselective Conversion of Aldehydes to Acylals under Solvent-Free Conditions

Received11 Feb 2009
Accepted05 Apr 2009

Abstract

A highly efficient, green and expeditious solvent-free method is described for the chemoselective conversion of aldehydes to the corresponding acylals in excellent yields, using acetic anhydride in the presence of catalytic amount (20 mol%) of silica-supported LiHSO4. Ketones does not react under these reaction conditions. LiHSO4/SiO2 can be recovered and reused without any significant loss of its catalytic activity.

Copyright © 2009 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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