Abdolkarim Zare, Alireza Hasaninejad, Esmael Rostami, Ahmad Reza Moosavi-Zare, Maria Merajoddin, Azam Arghoon, Nasrin Pishahang, Mohsen Shekouhy, "LiHSO4/SiO2 as a New, Efficient and Reusable Catalytic System for the Chemoselective Conversion of Aldehydes to Acylals under Solvent-Free Conditions", Journal of Chemistry, vol. 6, Article ID 953175, 7 pages, 2009. https://doi.org/10.1155/2009/953175
LiHSO4/SiO2 as a New, Efficient and Reusable Catalytic System for the Chemoselective Conversion of Aldehydes to Acylals under Solvent-Free Conditions
A highly efficient, green and expeditious solvent-free method is described for the chemoselective conversion of aldehydes to the corresponding acylals in excellent yields, using acetic anhydride in the presence of catalytic amount (20 mol%) of silica-supported LiHSO4. Ketones does not react under these reaction conditions. LiHSO4/SiO2 can be recovered and reused without any significant loss of its catalytic activity.
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