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E-Journal of Chemistry
Volume 7, Issue 1, Pages 239-245
http://dx.doi.org/10.1155/2010/235274

Copper(II) Extraction from Nitric Acid Solution with 1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone as a Cation Carrier by Liquid Membrane Emulsion

Baharuddin Hamzah,1 Noor Jalaluddin,2 Abdul Wahid Wahab,2 and Ambo Upe2

1Faculty of Teacher Training and Education, Universitas Tadulako Palu, Kampus Bumi Tadulako Tondo, 94223 Palu, Indonesia
2Faculty of Mathematics and Natural Science, Universitas Hasanuddin Makassar, Kampus Tamalanrea, 90245 Makassar, Indonesia

Received 19 March 2009; Accepted 15 May 2009

Copyright © 2010 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Copper(II) extraction from nitric acid solution with 1-phenyl-3-methyl-4-benzoil-5-pyrazolone (HPMBP) as a cation carrier by liquid membrane emulsion (LME) was investigated. The HPMBP initially was synthesized and the synthesis yield is a yellow crystal with melting point of 87-89 °C. The synthesis efficiency is 72.04% and generally the spectra of IR, 1H NMR and 13C NMR agree with HPMBP structure. The optimum condition for copper(II) extraction were found as follows: concentration of mixed surfactant (span 80+span 20) was 3%, volume ratio of membrane and internal phase was 1, concentration of HPMBP was 0.020 M, concentration of HCl was 1 M, volume ratio of emulsion and external phase was 0.143. By using these optimum conditions, 30 mL of LME can extract 1000 ppm of copper(II) within 210 mL of nitric acid solution with extraction percentage of 97.97%.